GB827151A - Removing hydrogen sulphide from gases - Google Patents

Removing hydrogen sulphide from gases

Info

Publication number
GB827151A
GB827151A GB607855A GB607855A GB827151A GB 827151 A GB827151 A GB 827151A GB 607855 A GB607855 A GB 607855A GB 607855 A GB607855 A GB 607855A GB 827151 A GB827151 A GB 827151A
Authority
GB
United Kingdom
Prior art keywords
solution
methylene blue
base
dye
gases
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB607855A
Inventor
John Eric Mills
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gas Council
Original Assignee
Gas Council
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gas Council filed Critical Gas Council
Priority to GB607855A priority Critical patent/GB827151A/en
Priority to FR1142205D priority patent/FR1142205A/en
Priority to DEG19117A priority patent/DE1051451B/en
Publication of GB827151A publication Critical patent/GB827151A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/52Hydrogen sulfide
    • B01D53/523Mixtures of hydrogen sulfide and sulfur oxides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/16Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

827,151. Purifying gases. GAS COUNCIL. Feb. 29, 1956 [March 1, 1955], No. 6078/55. Class 55 (2). In a process for removing H 2 S from gases such as coal gas the gas is washed with a solution of an organic dye base which will yield a readily oxidizable reduction product with H 2 S, the solution being regenerated by oxidation with air or oxygen. The dye base may be derived from a dye salt of the azine, triazine, oxazine or tri-phenylmethane classes, e.g. from methylene blue chloride. Methylene blue base may be made as follows :-To 100 c.c. of a 4% solution of methylene blue chloride in aniline, 0.5 c.c. concentrated ammonia solution is added. The solution is then reduced with H 2 S and extracted with an equal volume of water containing 5 c.c. concentrated ammonia solution followed by a second extraction, and if necessary further extractions, to remove all chloride ions. The solution is then aerated or oxygenated to yield a solution of methylene blue base. If during the process dye salts of sulphur oxy-acids are formed they may be converted back to the dye base by a treatment similar to the method of preparation described. Specification 827,152, [Group III], is referred to.
GB607855A 1955-03-01 1955-03-01 Removing hydrogen sulphide from gases Expired GB827151A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB607855A GB827151A (en) 1955-03-01 1955-03-01 Removing hydrogen sulphide from gases
FR1142205D FR1142205A (en) 1955-03-01 1956-02-29 Process for the removal of hydrogen sulphide contained in a gas
DEG19117A DE1051451B (en) 1955-03-01 1956-03-01 Process for removing hydrogen sulfide from gases

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB607855A GB827151A (en) 1955-03-01 1955-03-01 Removing hydrogen sulphide from gases

Publications (1)

Publication Number Publication Date
GB827151A true GB827151A (en) 1960-02-03

Family

ID=9807979

Family Applications (1)

Application Number Title Priority Date Filing Date
GB607855A Expired GB827151A (en) 1955-03-01 1955-03-01 Removing hydrogen sulphide from gases

Country Status (3)

Country Link
DE (1) DE1051451B (en)
FR (1) FR1142205A (en)
GB (1) GB827151A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10787614B2 (en) * 2018-10-15 2020-09-29 Merichem Company Hydrogen sulfide removal process

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE620932C (en) * 1934-02-02 1935-10-30 I G Farbenindustrie Akt Ges Process for removing weak gaseous acids from gases

Also Published As

Publication number Publication date
DE1051451B (en) 1959-02-26
FR1142205A (en) 1957-09-16

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