MX2020011091A - Complejos de fosfinimina amido-eter. - Google Patents
Complejos de fosfinimina amido-eter.Info
- Publication number
- MX2020011091A MX2020011091A MX2020011091A MX2020011091A MX2020011091A MX 2020011091 A MX2020011091 A MX 2020011091A MX 2020011091 A MX2020011091 A MX 2020011091A MX 2020011091 A MX2020011091 A MX 2020011091A MX 2020011091 A MX2020011091 A MX 2020011091A
- Authority
- MX
- Mexico
- Prior art keywords
- amido
- phosphinimine
- ligand
- ether complexes
- ether
- Prior art date
Links
- QLNAVQRIWDRPHA-UHFFFAOYSA-N iminophosphane Chemical compound P=N QLNAVQRIWDRPHA-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003446 ligand Substances 0.000 abstract 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 abstract 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 125000002524 organometallic group Chemical group 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/64082—Tridentate ligand
- C08F4/6411—Monoanionic ligand
- C08F4/64117—NNO
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/535—Organo-phosphoranes
- C07F9/5355—Phosphoranes containing the structure P=N-
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Una nueva familia de complejos organometálicos que contienen i) un átomo de metal seleccionado de Hf y Zr; ii) un ligando de fosfinimina; iii) un ligando de amido-éter y al menos otro ligando auxiliar. Se demuestra el uso de tal complejo, en combinación con un activador, como un catalizador de polimerización de olefinas. Los catalizadores son particularmente eficaces para la copolimerización de etileno con una alfa olefina (tal como el 1-buteno; 1-hexeno o 1-octeno) y permiten la producción de copolímeros de alto peso molecular (Mw superior a 25,000); con buena incorporación del comonómero a alta productividad.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201862662915P | 2018-04-26 | 2018-04-26 | |
| PCT/IB2019/053035 WO2019207401A1 (en) | 2018-04-26 | 2019-04-12 | Phosphinimine amido-ether complexes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2020011091A true MX2020011091A (es) | 2020-11-06 |
Family
ID=66630326
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2020011091A MX2020011091A (es) | 2018-04-26 | 2019-04-12 | Complejos de fosfinimina amido-eter. |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US10669355B2 (es) |
| EP (1) | EP3784679B1 (es) |
| JP (1) | JP2021521211A (es) |
| KR (1) | KR20210005594A (es) |
| CN (1) | CN111989334B (es) |
| AU (1) | AU2019259476A1 (es) |
| BR (1) | BR112020021822B1 (es) |
| CA (1) | CA3037503A1 (es) |
| ES (1) | ES2959547T3 (es) |
| MX (1) | MX2020011091A (es) |
| PE (1) | PE20210048A1 (es) |
| WO (1) | WO2019207401A1 (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7361239B1 (ja) | 2021-12-23 | 2023-10-13 | ポリプラスチックス株式会社 | 環状オレフィン共重合体の製造方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3248179A (en) | 1962-02-26 | 1966-04-26 | Phillips Petroleum Co | Method and apparatus for the production of solid polymers of olefins |
| NL135065C (es) | 1965-05-14 | |||
| US4242241A (en) | 1977-10-31 | 1980-12-30 | The Celotex Corporation | Method for making a slurry containing particulate matter and fibers for a preformed insulation product |
| US4528790A (en) | 1983-07-13 | 1985-07-16 | Owens-Corning Fiberglas Corporation | Roof insulation system |
| US4613484A (en) | 1984-11-30 | 1986-09-23 | Phillips Petroleum Company | Loop reactor settling leg system for separation of solid polymers and liquid diluent |
| US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
| US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| FI96216C (fi) | 1994-12-16 | 1996-05-27 | Borealis Polymers Oy | Prosessi polyeteenin valmistamiseksi |
| CA2201224C (en) | 1997-03-27 | 2004-12-07 | Annette Lynn Burke | Dual shear mixing element |
| CA2206944C (en) | 1997-05-30 | 2006-08-29 | Douglas W. Stephan | High temperature solution polymerization process |
| US6103657A (en) | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
| CA2243783C (en) * | 1998-07-21 | 2007-06-05 | Nova Chemicals Ltd. | Bis-phosphinimine catalyst |
| CA2243726C (en) * | 1998-07-21 | 2006-12-12 | Nova Chemicals Ltd. | Cyclopentadienyl/phosphinimine catalyst with one and only one activatable ligand |
| CA2243775C (en) | 1998-07-21 | 2007-06-12 | Nova Chemicals Ltd. | Phosphinimine/heteroatom catalyst component |
| US20020049288A1 (en) | 2000-04-04 | 2002-04-25 | Christopher Goh | Ether-amine based polymerization catalysts, compositions and processes using same |
| ES2869308T3 (es) * | 2013-12-19 | 2021-10-25 | Dow Global Technologies Llc | Complejo metal-ligando, catalizador de polimerización de olefina derivado del mismo y método de polimerización de olefina que utiliza el catalizador |
-
2019
- 2019-03-22 CA CA3037503A patent/CA3037503A1/en active Pending
- 2019-04-12 PE PE2020001643A patent/PE20210048A1/es unknown
- 2019-04-12 JP JP2020556285A patent/JP2021521211A/ja active Pending
- 2019-04-12 ES ES19725865T patent/ES2959547T3/es active Active
- 2019-04-12 CN CN201980027879.XA patent/CN111989334B/zh active Active
- 2019-04-12 KR KR1020207030067A patent/KR20210005594A/ko unknown
- 2019-04-12 BR BR112020021822-7A patent/BR112020021822B1/pt active IP Right Grant
- 2019-04-12 WO PCT/IB2019/053035 patent/WO2019207401A1/en active Application Filing
- 2019-04-12 AU AU2019259476A patent/AU2019259476A1/en not_active Abandoned
- 2019-04-12 EP EP19725865.0A patent/EP3784679B1/en active Active
- 2019-04-12 MX MX2020011091A patent/MX2020011091A/es unknown
- 2019-04-25 US US16/394,232 patent/US10669355B2/en active Active
-
2020
- 2020-04-28 US US16/860,461 patent/US11180581B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN111989334B (zh) | 2024-03-08 |
| WO2019207401A1 (en) | 2019-10-31 |
| US20190330387A1 (en) | 2019-10-31 |
| US20200255550A1 (en) | 2020-08-13 |
| BR112020021822B1 (pt) | 2023-12-19 |
| EP3784679A1 (en) | 2021-03-03 |
| PE20210048A1 (es) | 2021-01-08 |
| CA3037503A1 (en) | 2019-10-26 |
| ES2959547T3 (es) | 2024-02-26 |
| JP2021521211A (ja) | 2021-08-26 |
| KR20210005594A (ko) | 2021-01-14 |
| US11180581B2 (en) | 2021-11-23 |
| AU2019259476A1 (en) | 2020-09-17 |
| EP3784679B1 (en) | 2023-07-19 |
| EP3784679C0 (en) | 2023-07-19 |
| US10669355B2 (en) | 2020-06-02 |
| CN111989334A (zh) | 2020-11-24 |
| BR112020021822A2 (pt) | 2021-02-23 |
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