MX2020008629A - Polimero de metacrilato de metilo-butadieno-estireno opaco de alto impacto para mejorar la resistencia al impacto del cloruro de polivinilo y procedimiento de preparacion del mismo. - Google Patents

Polimero de metacrilato de metilo-butadieno-estireno opaco de alto impacto para mejorar la resistencia al impacto del cloruro de polivinilo y procedimiento de preparacion del mismo.

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Publication number
MX2020008629A
MX2020008629A MX2020008629A MX2020008629A MX2020008629A MX 2020008629 A MX2020008629 A MX 2020008629A MX 2020008629 A MX2020008629 A MX 2020008629A MX 2020008629 A MX2020008629 A MX 2020008629A MX 2020008629 A MX2020008629 A MX 2020008629A
Authority
MX
Mexico
Prior art keywords
mbs
preparation
pvc
impact
present
Prior art date
Application number
MX2020008629A
Other languages
English (en)
Inventor
Xiaoquan Zhang
Tonggang Yi
Yongquan Xia
Honggang Zhao
Duo Xu
Boxiao Zou
Wen Liu
Xiaomin Ma
Original Assignee
Shandong Donglin New Mat Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Donglin New Mat Co Ltd filed Critical Shandong Donglin New Mat Co Ltd
Publication of MX2020008629A publication Critical patent/MX2020008629A/es

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/06—Vinyl aromatic monomers and methacrylates as the only monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08—Cellulose derivatives
    • C08L1/26—Cellulose ethers
    • C08L1/28—Alkyl ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L89/00—Compositions of proteins; Compositions of derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/262—Alkali metal carbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/324—Alkali metal phosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/53—Core-shell polymer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

La presente invención proporciona un polímero de metacrilato de metilobutadieno-estireno (MBS) opaco de alto impacto para mejorar la resistencia al impacto del cloruro de polivinilo (PVC) y un método de preparación del mismo, y pertenece al campo técnico de preparación de aditivos de PVC. El MBS proporcionado por la presente invención incluye los siguientes componentes en masa: 80-95% de la capa de núcleo, 4-20% de la capa de cubierta y 0,001-5% de coloide protector, donde la capa de núcleo es un polímero de butadieno (B) y estireno (S); la capa de cubierta es uno o un copolímero de dos o tres de S, acrilato y metil metacrilato (MMA); el coloide protector incluye uno o un compuesto de dos o tres de alcohol polivinílico (PVA), gelatina e hidroxipropilmetilcelulosa (HPMC). La presente invención resuelve los problemas de baja resistencia al impacto en el producto MBS existente y difícil coagulación o pulverización en el proceso posterior al tratamiento.
MX2020008629A 2019-02-14 2019-12-13 Polimero de metacrilato de metilo-butadieno-estireno opaco de alto impacto para mejorar la resistencia al impacto del cloruro de polivinilo y procedimiento de preparacion del mismo. MX2020008629A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201910113740.9A CN109929076A (zh) 2019-02-14 2019-02-14 一种pvc抗冲改性剂不透明高抗冲mbs及其制备方法
PCT/CN2019/125003 WO2020164301A1 (zh) 2019-02-14 2019-12-13 一种pvc抗冲改性剂不透明高抗冲mbs及其制备方法

Publications (1)

Publication Number Publication Date
MX2020008629A true MX2020008629A (es) 2020-09-21

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Family Applications (1)

Application Number Title Priority Date Filing Date
MX2020008629A MX2020008629A (es) 2019-02-14 2019-12-13 Polimero de metacrilato de metilo-butadieno-estireno opaco de alto impacto para mejorar la resistencia al impacto del cloruro de polivinilo y procedimiento de preparacion del mismo.

Country Status (6)

Country Link
US (1) US11479659B2 (es)
KR (1) KR102375494B1 (es)
CN (1) CN109929076A (es)
DE (1) DE112019000499B4 (es)
MX (1) MX2020008629A (es)
WO (1) WO2020164301A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109929076A (zh) 2019-02-14 2019-06-25 山东东临新材料股份有限公司 一种pvc抗冲改性剂不透明高抗冲mbs及其制备方法
KR102532948B1 (ko) * 2019-09-26 2023-05-16 주식회사 엘지화학 코어-쉘 공중합체 및 이를 포함하는 수지 조성물
CN111484581A (zh) * 2020-06-12 2020-08-04 江西岳峰集团高分子材料有限公司 一种抗冲型改性剂mbs的合成方法

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NL256962A (es) 1959-12-24
US3370105A (en) 1963-05-07 1968-02-20 Bell & Richardson Inc De Process for manufacture of impact polymers
GB1356926A (en) 1970-09-30 1974-06-19 Bp Chem Int Ltd Polymerisation process telephone intercommunication systems
FR2397431A1 (fr) 1977-07-12 1979-02-09 Ugine Kuhlmann Procede de fabrication de copolymeres greffes par polymerisation-greffage en emulsion-suspension
ES2122720T3 (es) * 1994-12-21 1998-12-16 Basf Ag Copolimeros de injerto de emulsion.
KR0179314B1 (ko) * 1996-02-28 1999-05-15 유현식 내충격성 및 광택성이 우수한 열가소성 수지 조성물의 제조방법
CN1053202C (zh) * 1997-01-06 2000-06-07 中国石油化工集团公司北京化工研究院 高透明耐冲击聚氯乙烯的制造方法
EP0985692B1 (en) * 1998-09-09 2005-01-19 Rohm And Haas Company Improved MBS impact modifier
DE102005022631A1 (de) 2005-05-11 2006-11-16 Basf Ag Kaltfahrweise für die Herstellung von Kautschuken und ihre Verwendung als Impact Modifier für Thermoplaste
DE102005027485A1 (de) * 2005-06-14 2006-12-28 Basf Ag Verstärkte thermoplastische Formmassen
CN101191002A (zh) * 2006-11-18 2008-06-04 沂源瑞丰高分子材料有限公司 具有优异冲击性能的mbs树脂组合物
CN106232712B (zh) * 2014-04-16 2019-05-17 阿科玛股份有限公司 高橡胶抗冲击改性剂在热塑性配制品中的用途
CN109929076A (zh) * 2019-02-14 2019-06-25 山东东临新材料股份有限公司 一种pvc抗冲改性剂不透明高抗冲mbs及其制备方法

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Publication number Publication date
US11479659B2 (en) 2022-10-25
CN109929076A (zh) 2019-06-25
WO2020164301A1 (zh) 2020-08-20
RU2020128115A3 (es) 2022-02-24
RU2020128115A (ru) 2022-02-24
KR102375494B1 (ko) 2022-03-17
DE112019000499T5 (de) 2020-10-29
KR20200106072A (ko) 2020-09-10
DE112019000499B4 (de) 2023-04-20
US20210221982A1 (en) 2021-07-22

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