MX2017004670A - Composicion plastificante que comprende cicloalquilesteres de acidos dicarboxilicos saturados y esteres 1,2-ciclohexandicarboxil icos. - Google Patents

Composicion plastificante que comprende cicloalquilesteres de acidos dicarboxilicos saturados y esteres 1,2-ciclohexandicarboxil icos.

Info

Publication number
MX2017004670A
MX2017004670A MX2017004670A MX2017004670A MX2017004670A MX 2017004670 A MX2017004670 A MX 2017004670A MX 2017004670 A MX2017004670 A MX 2017004670A MX 2017004670 A MX2017004670 A MX 2017004670A MX 2017004670 A MX2017004670 A MX 2017004670A
Authority
MX
Mexico
Prior art keywords
esters
plasticizer composition
cyclohexanedicarboxylic
saturated dicarboxylic
dicarboxylic acids
Prior art date
Application number
MX2017004670A
Other languages
English (en)
Inventor
Breitscheidel Boris
Pfeiffer Matthias
Grimm Axel
Morgenstern Herbert
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2017004670A publication Critical patent/MX2017004670A/es

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016Plasticisers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/11Esters; Ether-esters of acyclic polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/12Esters; Ether-esters of cyclic polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/06Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente invención se refiere a una composición plastificante que comprende al menos un cicloalquil éster de ácidos dicarboxílicos saturados y al menos un éster 1,2-ciclohexandicarbo xílico, a composiciones de moldeo que comprenden un polímero termoplástico o un alastómero y esta composición plastificante, y al uso de estas composiciones plastificantes y composiciones de moldeo.
MX2017004670A 2014-10-09 2015-10-08 Composicion plastificante que comprende cicloalquilesteres de acidos dicarboxilicos saturados y esteres 1,2-ciclohexandicarboxil icos. MX2017004670A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP14188352 2014-10-09
PCT/EP2015/073267 WO2016055573A1 (en) 2014-10-09 2015-10-08 Plasticizer composition which comprises cycloalkyl esters of saturated dicarboxylic acids and 1,2-cyclohexanedicarboxylic esters

Publications (1)

Publication Number Publication Date
MX2017004670A true MX2017004670A (es) 2017-10-18

Family

ID=51743280

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017004670A MX2017004670A (es) 2014-10-09 2015-10-08 Composicion plastificante que comprende cicloalquilesteres de acidos dicarboxilicos saturados y esteres 1,2-ciclohexandicarboxil icos.

Country Status (15)

Country Link
US (1) US10329402B2 (es)
EP (1) EP3204448B1 (es)
JP (1) JP2017531717A (es)
KR (1) KR20170066547A (es)
CN (1) CN107108958B (es)
BR (1) BR112017007022A2 (es)
CA (1) CA2963769A1 (es)
CL (1) CL2017000856A1 (es)
ES (1) ES2704245T3 (es)
MX (1) MX2017004670A (es)
PL (1) PL3204448T3 (es)
RU (1) RU2698691C2 (es)
SG (1) SG11201702275PA (es)
TW (1) TW201619119A (es)
WO (1) WO2016055573A1 (es)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201619120A (zh) * 2014-10-09 2016-06-01 巴斯夫歐洲公司 包含飽和二羧酸之環烷基酯及對苯二甲酯之塑化劑組成物
RU2729055C2 (ru) 2016-01-20 2020-08-04 Басф Се Пластифицирующая композиция, которая содержит алифатический сложный эфир дикарбоновой кислоты и сложный диэфир, выбранный из сложных эфиров 1,2-циклогександикарбоновой кислоты и сложных эфиров терефталевой кислоты
CN109153813B (zh) 2016-12-12 2020-07-03 株式会社Lg化学 增塑剂组合物和包含其的树脂组合物
GB2569608B (en) 2017-12-21 2022-10-26 Altro Ltd Plasticiser composition
JP7307719B2 (ja) * 2018-04-27 2023-07-12 株式会社パイロットコーポレーション 筆記板用油性インキ組成物及びそれを内蔵したマーキングペン
KR102260896B1 (ko) * 2018-06-11 2021-06-07 주식회사 엘지화학 가소제 조성물 및 이를 포함하는 수지 조성물
KR102260893B1 (ko) * 2018-06-11 2021-06-07 주식회사 엘지화학 가소제 조성물 및 이를 포함하는 수지 조성물
KR102294862B1 (ko) * 2018-06-12 2021-08-30 주식회사 엘지화학 가소제 조성물 및 이를 포함하는 수지 조성물
KR102260895B1 (ko) * 2018-06-12 2021-06-07 주식회사 엘지화학 가소제 조성물 및 이를 포함하는 수지 조성물
KR102093026B1 (ko) * 2018-06-27 2020-03-24 최하영 가소제를 포함하고 있는 폴리케톤 조성물
JP7095216B2 (ja) * 2018-08-27 2022-07-05 エルジー・ケム・リミテッド 可塑剤組成物及びこれを含む樹脂組成物
JP6988044B2 (ja) 2018-12-14 2022-01-05 エルジー・ケム・リミテッド 可塑剤組成物及びこれを含む樹脂組成物
CN110128761A (zh) * 2019-05-05 2019-08-16 江苏大海塑料股份有限公司 一种环保高性能改性pvc造粒的制备方法
CN110187026B (zh) * 2019-05-30 2022-10-25 扬子石化-巴斯夫有限责任公司 一种2-丙基庚醇及其杂质的分析方法
KR102528325B1 (ko) * 2019-08-28 2023-05-02 한화솔루션 주식회사 수성 난연 접착제 조성물 및 그 제조방법
KR102506279B1 (ko) * 2020-07-01 2023-03-03 한화솔루션 주식회사 가소제 조성물, 및 이를 포함하는 염화비닐 수지 조성물
KR102648321B1 (ko) 2020-12-29 2024-03-14 한화솔루션 주식회사 수성 난연 접착제 조성물 및 그 제조방법
CN114956998B (zh) * 2022-04-29 2023-09-26 江南大学 一种用于pla和pvc的环己酯封端的戊二酸低聚乳酸酯增塑剂的制备方法
CN116640361B (zh) * 2023-06-15 2023-12-22 益丰新材料股份有限公司 一种离型剂组合物及其应用

Family Cites Families (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2921089A (en) 1957-11-27 1960-01-12 Eastman Kodak Co 2-propylheptanol and its esters
US3418351A (en) 1965-05-17 1968-12-24 Shell Oil Co Recovery of hydroformylation cobalt-carbonyl-hydrocarbyl-tert-phosphine catalyst complex
DE1945359B2 (de) 1969-09-08 1973-05-10 Verfahren zur gewinnung von estern
DE2139630C3 (de) 1971-08-07 1979-03-22 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von vorwiegend geradkettigen Aldehyden
DE2244373A1 (de) 1972-09-09 1974-04-04 Basf Ag Verfahren zur kontinuierlichen herstellung von waessrigen loesungen von kobaltcarbonylen
DE2404855C3 (de) 1974-02-01 1981-01-22 Basf Ag, 6700 Ludwigshafen Verfahren zur Verhinderung von Emulsionsbildung bei der Aufbereitung von Butyraldehyden und Kobalt enthaltenden Reaktionsgemischen
US4009124A (en) 1975-09-15 1977-02-22 Basf Aktiengesellschaft Basic mixed carbonate of copper and aluminum and process for manufacturing a copper-containing catalyst
DE2445303C3 (de) 1974-09-21 1979-04-05 Basf Ag, 6700 Ludwigshafen Basisches, zur Herstellung eines Kupfer enthaltenden Katalysators geeignetes Carbonat
US4148830A (en) 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
DE2612355C3 (de) 1976-03-24 1983-11-17 Basf Ag, 6700 Ludwigshafen Verfahren zur Abtrennung von Katalysatoren aus rohen Weichmacherestern
DE2628987C3 (de) 1976-06-28 1981-10-22 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von C↓3↓-C↓5↓-Alkanolen
US4426524A (en) 1980-09-02 1984-01-17 Fmc Corporation Heterocyclic substituted benzyl alcohol, insecticidal ester derivatives, and intermediates
DE3228881C2 (de) 1982-08-03 1985-06-13 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von C↓3↓-C↓5↓-Alkoholen
US4969953A (en) 1988-10-25 1990-11-13 Mitsubishi Kasei Corporation Alcohol mixture for plasticizer and method for producing the same
SU1796640A1 (ru) * 1989-12-28 1993-02-23 Gni Pi Azotnoj Promy Produktov ПЛАСТИФИЦИРУЮЩАЯ СМЕСЬ ДЛЯ ПОЛИВИНИЛХЛОРИДНЫХ композиций
GB9207756D0 (en) 1992-04-07 1992-05-27 Davy Mckee London Process
US5288918A (en) 1992-09-29 1994-02-22 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
US5281647A (en) * 1992-11-10 1994-01-25 Miles Inc. Polymeric plasticizers and a process for preparing the same
RU2057115C1 (ru) 1993-03-05 1996-03-27 АООТ "Научно-исследовательский институт пластических масс им.Г.С.Петрова с опытным московским заводом пластмасс" Способ получения пластификатора на основе сложных эфиров смеси дикарбоновых кислот с числом углеродных атомов 4 - 6
DE4339713A1 (de) 1993-11-22 1995-05-24 Basf Ag Verfahren zur Oligomerisierung von Olefinen zu hochlinearen Oligomeren und Katalysatoren dafür
JPH07206768A (ja) * 1994-01-12 1995-08-08 Nippon Oil Co Ltd 光学活性コハク酸又はその誘導体の製造法
DE4427428A1 (de) 1994-08-03 1996-02-29 Basf Ag Verfahren zur Herstellung von Aldehyden
DE19605435A1 (de) 1996-02-14 1997-08-21 Basf Ag Verfahren zur Herstellung von Aldehyden durch Hydroformylierung mit einem Rhodiumkatalysator und Wiedergewinnung des Rhodiumkatalysators durch Extraktion
FR2749582B1 (fr) 1996-06-07 1998-07-17 Rhone Poulenc Fibres Procede d'hydroxycarbonylation des acides pentenoiques
WO1998023566A1 (en) 1996-11-26 1998-06-04 Shell Internationale Research Maatschappij B.V. Highly branched primary alcohol compositions, and biodegradable detergents made therefrom
DE19721347B9 (de) 1997-05-22 2005-09-29 Celanese Chemicals Europe Gmbh Verfahren zur Herstellung von Esterweichmachern
MY129474A (en) 1997-12-19 2007-04-30 Basf Ag Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores
DE19801437A1 (de) 1998-01-16 1999-07-22 Basf Ag Verfahren zur Herstellung von Aldehyden
DE59908919D1 (de) 1999-04-21 2004-04-22 Basf Ag Gemisch von diestern der adipin- oder phthalsäure mit isomeren nonanolen
DE19927978A1 (de) 1999-06-18 2000-12-21 Basf Ag Ausgewählte Cyclohexan-1,3- und 1,4-dicarbonsäureester
DE19939491A1 (de) 1999-08-20 2001-02-22 Basf Ag Kontinuierliches Verfahren zur Hydroformylierung von Olefinen mit 6 bis 20 Kohlenstoffatomen
DE10024542A1 (de) 2000-05-18 2001-11-22 Basf Ag Verfahren zur Herstellung von gesättigten C3-C20-Alkoholen
DE10056179A1 (de) 2000-11-13 2002-05-29 Basf Ag Verfahren zur Herstellung von Estern mehrbasiger Säuren
US7173138B2 (en) 2001-03-29 2007-02-06 Basf Aktiengesellschaft Ligands for pnicogen chelate complexes with a metal of subgroup VIII and use of the complexes as catalysts for hydroformylation, carbonylation, hydrocyanation or hydrogenation
CN102002200B (zh) * 2001-09-25 2014-01-15 埃克森美孚化学专利公司 增塑聚氯乙烯
DE10217186A1 (de) 2002-04-18 2003-11-13 Oxeno Olefinchemie Gmbh Benzoesäureisononylester und deren Verwendung
DE10301675A1 (de) * 2003-01-17 2004-07-29 Crompton Vinyl Additives Gmbh Stabilisatorsystem zur PVC-Stabilisierung
DE10336150A1 (de) * 2003-08-07 2005-03-10 Oxeno Olefinchemie Gmbh Schäumbare Kompositionen, die Benzoesäureisononylester aufweisen
GB0322247D0 (en) 2003-09-23 2003-10-22 Exxonmobil Chem Patents Inc Improvement in or relating to an isobutylene containing stream
RU2401847C2 (ru) * 2005-01-18 2010-10-20 Эксонмобил Кемикэл Пейтентс Инк. Усовершенствования, касающиеся пластификаторных композиций
DE102006003913A1 (de) * 2006-01-27 2007-08-02 Benecke-Kaliko Ag PVC-Zusammensetzung und deren Verwendung
FR2922548B1 (fr) 2007-10-22 2012-11-30 Rhodia Operations Diesters d'acides dicarboxyliques,procedes de preparation et utilisations
DE102008006400A1 (de) 2008-01-28 2009-07-30 Evonik Oxeno Gmbh Gemische von Diisononylestern der Terephthalsäure, Verfahren zu deren Herstellung und deren Verwendung
JP5121589B2 (ja) * 2008-06-11 2013-01-16 株式会社ブリヂストン ランフラットタイヤ
KR20100029978A (ko) * 2008-09-09 2010-03-18 에스케이에너지 주식회사 가소제 및 이를 포함한 폴리염화비닐 수지 조성물
EP2512658A2 (de) 2009-12-15 2012-10-24 Basf Se Katalysator und verfahren zur hydrierung von aromaten
US7973194B1 (en) * 2010-03-18 2011-07-05 Eastman Chemical Company High solvating cyclohexane dicarboxylate diesters plasticizers
DE102010061871A1 (de) 2010-11-24 2012-05-24 Evonik Oxeno Gmbh Polymer-Zusammensetzung enthaltend DINT als Weichmacher
EP2631267A1 (de) 2012-02-24 2013-08-28 Lanxess Deutschland GmbH Bernsteinsäurealkylester-Mischungen als Weichmacher
DE102012224300A1 (de) * 2012-12-21 2014-06-26 Hilti Aktiengesellschaft Dämmschichtbildende Zusammensetzung und deren Verwendung
EP2789652A1 (fr) * 2013-04-10 2014-10-15 Rhodia Opérations Composition plastifiante
CN103319439A (zh) * 2013-04-12 2013-09-25 常州南京大学高新技术研究院 一种制备环氧脂肪酸环己酯的方法
PL3077453T3 (pl) 2013-12-06 2018-10-31 Basf Se Kompozycja plastyfikatora zawierająca pochodne tetrahydrofuranu i estry kwasu 1,2-cykloheksanodikarboksylowego
PL3092266T3 (pl) 2014-01-09 2018-12-31 Basf Se Kompozycja plastyfikatora zawierająca pochodną furanu i ester kwasu 1,2-cykloheksanodikarboksylowego
MX2016013988A (es) 2014-04-24 2017-01-11 Basf Se Composicion plastificante que contiene derivados de furano y esteres dialquilicos de acido tereftalico.
TW201605945A (zh) 2014-07-08 2016-02-16 巴斯夫歐洲公司 包含二羧酸的酯及1,2-環己烷二羧酸的酯之模製化合物

Also Published As

Publication number Publication date
KR20170066547A (ko) 2017-06-14
CN107108958B (zh) 2019-06-14
US10329402B2 (en) 2019-06-25
ES2704245T3 (es) 2019-03-15
EP3204448B1 (en) 2018-10-03
CN107108958A (zh) 2017-08-29
PL3204448T3 (pl) 2019-03-29
RU2017116048A (ru) 2018-11-12
EP3204448A1 (en) 2017-08-16
CL2017000856A1 (es) 2017-10-20
JP2017531717A (ja) 2017-10-26
BR112017007022A2 (pt) 2018-01-16
CA2963769A1 (en) 2016-04-14
SG11201702275PA (en) 2017-04-27
US20170313850A1 (en) 2017-11-02
RU2017116048A3 (es) 2019-03-01
RU2698691C2 (ru) 2019-08-28
TW201619119A (zh) 2016-06-01
WO2016055573A1 (en) 2016-04-14

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