MX2017000884A - Catalizadores. - Google Patents

Catalizadores.

Info

Publication number
MX2017000884A
MX2017000884A MX2017000884A MX2017000884A MX2017000884A MX 2017000884 A MX2017000884 A MX 2017000884A MX 2017000884 A MX2017000884 A MX 2017000884A MX 2017000884 A MX2017000884 A MX 2017000884A MX 2017000884 A MX2017000884 A MX 2017000884A
Authority
MX
Mexico
Prior art keywords
lll
epoxide
catalysts
lactide
lactone
Prior art date
Application number
MX2017000884A
Other languages
English (en)
Inventor
Kember Michael
chapman Andy
CHARTOIRE Anthony
ADRIAENNSENS Louis
Leeland James
Original Assignee
Econic Tech Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB201412990A external-priority patent/GB201412990D0/en
Priority claimed from GB201412992A external-priority patent/GB201412992D0/en
Priority claimed from GB201412986A external-priority patent/GB201412986D0/en
Application filed by Econic Tech Ltd filed Critical Econic Tech Ltd
Publication of MX2017000884A publication Critical patent/MX2017000884A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B01J31/1835—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/226—Sulfur, e.g. thiocarbamates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D257/00—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
    • C07D257/02—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/08—Bridged systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/785—Preparation processes characterised by the apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/22—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/23—Calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

La presente invención se refiere al campo de catalizadores de polimerización, y sistemas que comprenden tales catalizadores para polimerizar dióxido de carbono y un epóxido, un láctido y/o lactona, y/o un epóxido y un anhídrido. El catalizador es de la fórmula (I): (Ver Fórmula) En donde M1 y M2 están independientemente seleccionados de Zn(II), Cr(II), Co(II), Cu(II), Mn(II), Ni(II), Mg(II), Fe(II), Ti(II), V(II), Cr(III)-X, Co(III)-X, Ni(III)-X, Mn(III)-X, Fe(III)-X, Ca(II), Ge(II), Al(III)-X, Ti(III)-X, V(III)-X, Ge(IV)-(X)2 o Ti(IV)-(X)2. R3A es diferente de R3B; y/o al menos una ocurrencia de E3, E4, E5 y E6 es diferente a una ocurrencia restante de E3, E4, E5 y E6. También se describe un ligando, un proceso de sustitución N asimétrica de un ligando asimétrico y un proceso para la reacción de: (i) diáxido de carbono con un epóxido; (ii) un epóxido y un anhídrido; y/o (iii) un láctido y/o una lactona, en la presencia de un catalizador.
MX2017000884A 2014-07-22 2015-07-22 Catalizadores. MX2017000884A (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB201412990A GB201412990D0 (en) 2014-07-22 2014-07-22 Catalysts
GB201412992A GB201412992D0 (en) 2014-07-22 2014-07-22 Catalysts
GB201412986A GB201412986D0 (en) 2014-07-22 2014-07-22 Catalysts
PCT/GB2015/052114 WO2016012785A1 (en) 2014-07-22 2015-07-22 Catalysts

Publications (1)

Publication Number Publication Date
MX2017000884A true MX2017000884A (es) 2017-11-02

Family

ID=53776894

Family Applications (2)

Application Number Title Priority Date Filing Date
MX2017000884A MX2017000884A (es) 2014-07-22 2015-07-22 Catalizadores.
MX2017000880A MX2017000880A (es) 2014-07-22 2015-07-22 Catalizadores.

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX2017000880A MX2017000880A (es) 2014-07-22 2015-07-22 Catalizadores.

Country Status (15)

Country Link
US (4) US10030102B2 (es)
EP (2) EP3171975B1 (es)
JP (2) JP6730273B2 (es)
KR (2) KR102480993B1 (es)
CN (2) CN106536048B (es)
AU (2) AU2015293703B2 (es)
BR (2) BR112017001086B1 (es)
ES (1) ES2962669T3 (es)
MX (2) MX2017000884A (es)
MY (1) MY181918A (es)
PL (1) PL3171975T3 (es)
RU (2) RU2706004C2 (es)
SG (2) SG11201700229VA (es)
TW (2) TWI675700B (es)
WO (2) WO2016012786A1 (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0807607D0 (en) 2008-04-25 2008-06-04 Imp Innovations Ltd Catalyst
GB201308978D0 (en) 2013-05-17 2013-07-03 Imp Innovations Ltd Method for producing polymers and block copolymers
PL3171975T3 (pl) 2014-07-22 2024-01-22 Econic Technologies Ltd Katalizatory
GB201514506D0 (en) 2015-08-14 2015-09-30 Imp Innovations Ltd Multi-block copolymers
GB201515350D0 (en) * 2015-08-28 2015-10-14 Econic Technologies Ltd Method for preparing polyols
EP3538587B1 (en) 2016-11-11 2020-08-05 Dow Global Technologies LLC Semi-batch process for making polycarbonate polyols via copolymerization of carbon dioxide and an oxirane
GB201703323D0 (en) * 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polyols
GB201703324D0 (en) * 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polyether carbonates
GB201703384D0 (en) * 2017-03-02 2017-04-19 Econic Tech Ltd Process for the production of Tetraaminobiphenol macrocyclic ligands; and novel Tetraaminobiphenol macrocyclic ligands
GB201717459D0 (en) 2017-10-24 2017-12-06 Econic Tech Limited Methods for forming polycarbonate ether polyols and high molecular weight polyether carbonates
WO2019204553A1 (en) 2018-04-18 2019-10-24 Saudi Aramco Technologies Company End-group isomerization of poly(alkylene carbonate) polymers
US11180609B2 (en) 2018-08-02 2021-11-23 Saudi Aramco Technologies Company Sustainable polymer compositions and methods
US11634539B2 (en) 2018-09-24 2023-04-25 Saudi Aramco Technologies Company Polycarbonate block copolymers and methods thereof
CN113302224B (zh) 2019-01-31 2023-09-19 陶氏环球技术有限责任公司 聚醚-碳酸酯多元醇的纯化方法
GB201906214D0 (en) 2019-05-02 2019-06-19 Econic Tech Ltd A polyol block copolymer, compositions and processes therefor
GB201906210D0 (en) 2019-05-02 2019-06-19 Econic Tech Limited A polyol block copolymer, compositions and processes therefor
GB202003002D0 (en) 2020-03-02 2020-04-15 Crane Ltd Method of preparation of a polyol block copolymer
GB202003003D0 (en) 2020-03-02 2020-04-15 Econic Tech Ltd A polyol block copolymer
WO2021262845A1 (en) 2020-06-24 2021-12-30 Saudi Aramco Technologies Company Polyol compositions and methods
GB202017531D0 (en) 2020-11-05 2020-12-23 Econic Tech Limited (poly)ol block copolymer
EP4359460A1 (en) 2021-06-23 2024-05-01 Saudi Aramco Technologies Company Polyol compositions and methods
EP4384316A1 (en) 2021-08-11 2024-06-19 Econic Technologies Ltd Method for preparing surfactants by copolymerisation of epoxides and co2 using a mixture of a macrocyclic bimetal catalyst and a double metal cyanide catalyst
GB202115335D0 (en) 2021-10-25 2021-12-08 Econic Tech Ltd Surface-active agent

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63280086A (ja) 1987-05-12 1988-11-17 Hiroyoshi Shirai 複核錯体またはその塩体およびラングミュア・ブロジェット膜
JP2007238601A (ja) 2006-02-08 2007-09-20 Sumitomo Chemical Co Ltd 多核金属錯体変性物及びその用途
US20090062110A1 (en) 2006-02-08 2009-03-05 Sumitomo Chemical Company Limited Metal complex and use thereof
KR20090127419A (ko) * 2007-03-09 2009-12-11 내셔날 인스티튜트 오브 어드밴스드 인더스트리얼 사이언스 앤드 테크놀로지 연료 전지용 전극 촉매
GB0807607D0 (en) 2008-04-25 2008-06-04 Imp Innovations Ltd Catalyst
US9284406B2 (en) * 2010-09-14 2016-03-15 Novomer, Inc. Catalysts and methods for polymer synthesis
EP2721032A4 (en) * 2011-06-16 2014-11-05 Univ South Florida POLYHEDRIC CAGE WITH METAL OPORPHYRENE EQUIPMENT, METHOD FOR THE PRODUCTION THEREOF AND METHOD FOR THEIR USE
GB201111928D0 (en) * 2011-07-12 2011-08-24 Norner As Process
GB201115565D0 (en) 2011-09-08 2011-10-26 Imp Innovations Ltd Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent
PL3171975T3 (pl) 2014-07-22 2024-01-22 Econic Technologies Ltd Katalizatory

Also Published As

Publication number Publication date
US10030102B2 (en) 2018-07-24
US10774180B2 (en) 2020-09-15
KR20170035999A (ko) 2017-03-31
KR102480993B1 (ko) 2022-12-23
MY181918A (en) 2021-01-14
RU2017105139A3 (es) 2018-12-28
RU2696272C2 (ru) 2019-08-01
TW201609259A (zh) 2016-03-16
KR102523483B1 (ko) 2023-04-20
CN106536048A (zh) 2017-03-22
EP3171975C0 (en) 2023-10-04
AU2015293703A1 (en) 2017-02-02
BR112017001086A2 (pt) 2017-11-21
AU2015293702B2 (en) 2018-11-01
AU2015293703B2 (en) 2019-06-13
RU2017105138A (ru) 2018-08-28
CN106536047B (zh) 2020-10-30
CN106536048B (zh) 2020-05-05
JP6728162B2 (ja) 2020-07-22
EP3171975A1 (en) 2017-05-31
TWI675700B (zh) 2019-11-01
RU2706004C2 (ru) 2019-11-13
BR112017001081A2 (pt) 2017-11-21
US10556988B2 (en) 2020-02-11
KR20170034417A (ko) 2017-03-28
RU2017105139A (ru) 2018-08-28
TW201609258A (zh) 2016-03-16
TWI660778B (zh) 2019-06-01
US20190055352A1 (en) 2019-02-21
ES2962669T3 (es) 2024-03-20
SG11201700229VA (en) 2017-02-27
JP6730273B2 (ja) 2020-07-29
JP2017524064A (ja) 2017-08-24
PL3171975T3 (pl) 2024-01-22
MX2017000880A (es) 2017-08-18
EP3180121A1 (en) 2017-06-21
EP3171975B1 (en) 2023-10-04
JP2017524800A (ja) 2017-08-31
WO2016012786A1 (en) 2016-01-28
EP3180121B1 (en) 2024-06-05
SG11201700233XA (en) 2017-02-27
AU2015293702A1 (en) 2017-02-02
CN106536047A (zh) 2017-03-22
US20200140610A1 (en) 2020-05-07
BR112017001081B1 (pt) 2020-12-29
US20170204221A1 (en) 2017-07-20
US20170210848A1 (en) 2017-07-27
RU2017105138A3 (es) 2018-12-29
WO2016012785A1 (en) 2016-01-28
BR112017001086B1 (pt) 2020-12-15

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