MX2016007949A - Procedimiento de acilacion de glicol mejorado. - Google Patents

Procedimiento de acilacion de glicol mejorado.

Info

Publication number
MX2016007949A
MX2016007949A MX2016007949A MX2016007949A MX2016007949A MX 2016007949 A MX2016007949 A MX 2016007949A MX 2016007949 A MX2016007949 A MX 2016007949A MX 2016007949 A MX2016007949 A MX 2016007949A MX 2016007949 A MX2016007949 A MX 2016007949A
Authority
MX
Mexico
Prior art keywords
acylation
isohexide
water
acid
acylation process
Prior art date
Application number
MX2016007949A
Other languages
English (en)
Inventor
Howard Stephen
Stensrud Kenneth
Hagberg Erik
M Rockafellow Erin
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of MX2016007949A publication Critical patent/MX2016007949A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0209—Esters of carboxylic or carbonic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B01J31/0232—Halogen-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0228
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/49—Esterification or transesterification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/001—General concepts, e.g. reviews, relating to catalyst systems and methods of making them, the concept being defined by a common material or method/theory
    • B01J2531/002—Materials
    • B01J2531/004—Ligands

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Se describe un método para la acilación catalizada con ácido de una isohexida. El método puede permitir la acilación directa de alcoholes con ácidos carboxílicos. En particular, el método implica hacer reaccionar una isohexida y un exceso de ácido carboxílico, en presencia de un catalizador de ácido de Lewis tolerante a agua. Los catalizadores de ácido de Lewis tolerantes a agua pueden proporcionar rendimientos de diéster relativamente altos (p. ej., = 55%-60%) a cargas de catalizador inferiores. Esta característica, entre otras, es altamente deseable para el ahorro de costes, y puede mejorar la economía del procedimiento.
MX2016007949A 2013-12-19 2014-12-11 Procedimiento de acilacion de glicol mejorado. MX2016007949A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361918172P 2013-12-19 2013-12-19
PCT/US2014/069701 WO2015094895A1 (en) 2013-12-19 2014-12-11 An improved glycol acylation process

Publications (1)

Publication Number Publication Date
MX2016007949A true MX2016007949A (es) 2016-09-09

Family

ID=53403540

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016007949A MX2016007949A (es) 2013-12-19 2014-12-11 Procedimiento de acilacion de glicol mejorado.

Country Status (9)

Country Link
US (1) US20170008902A1 (es)
EP (1) EP3083637A4 (es)
JP (1) JP2017501138A (es)
KR (1) KR20160098489A (es)
CN (1) CN105829322A (es)
AU (1) AU2014366354A1 (es)
CA (1) CA2932349A1 (es)
MX (1) MX2016007949A (es)
WO (1) WO2015094895A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017100402A1 (en) * 2015-12-11 2017-06-15 Archer Daniels Midland Company One-pot synthesis of anhydropentitol esters from pentitols, catalyzed by water-tolerant lewis acids
CN112940065A (zh) * 2021-02-03 2021-06-11 山东大学 三氟甲磺酸盐在制备醋酸阿比特龙中的应用及合成方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6395810B1 (en) * 1998-03-04 2002-05-28 Ato B.V. Bicyclooctane derivatives as plasticizers
AU2270901A (en) * 1999-12-17 2001-06-25 E.I. Du Pont De Nemours And Company Continuous process for the preparation of polytrimethylene ether glycol
NL1015119C2 (nl) * 2000-05-04 2001-11-06 Inst Agrotechnologisch Onderzoek Ato Dlo Verbeterde synthese van anhydroglycitol-esters met verbeterde kleur.
US6608167B1 (en) * 2002-03-26 2003-08-19 E. I. Du Pont De Nemours And Company Bis(2-hydroxyethyl isosorbide); preparation, polymers derived therefrom, and enduses thereby
DE10353934A1 (de) * 2003-11-18 2005-06-23 Sasol Germany Gmbh Verfahren zur Herstellung von Metallsalzen der Trifluormethansulfonsäure und deren Verwendung als Veresterungskatalysatoren
FR2883877B1 (fr) * 2005-04-01 2008-10-10 Roquette Freres Procede de preparation de compositions de diester(s) de dianhydrohexitol
US7914700B2 (en) * 2006-03-31 2011-03-29 E. I. Du Pont De Nemours And Company Liquid crystal compositions and polymer networks derived therefrom
US20070282042A1 (en) * 2006-06-01 2007-12-06 Anthony East Esters of anhydrosugar alcohols as plasticizers
DE102007006442A1 (de) * 2007-02-05 2008-08-07 Evonik Oxeno Gmbh Gemisch von Diestern von Dianhydrohexitolderivaten mit Carbonsäuren der Summenformel C8H17COOH, Verfahren zur Herstellung dieser Diester und Verwendung dieser Gemische
DE102007028702A1 (de) * 2007-06-21 2008-12-24 Evonik Oxeno Gmbh Verfahren zur Herstellung von Dianhydrohexitol-Diestern
JP2013504336A (ja) * 2009-09-16 2013-02-07 ビーエーエスエフ ソシエタス・ヨーロピア 酵素により触媒されるモノアシル化ポリオールの調製方法
EP2388262A1 (en) * 2010-05-20 2011-11-23 Stichting Dutch Polymer Institute New biobased chiral compounds
CN104447779A (zh) * 2010-07-30 2015-03-25 阿彻丹尼尔斯米德兰德公司 微波辅助的脱水糖衍生物羟甲基糠醛、乙酰丙酸、无水糖醇、及其醚的合成
US9266898B2 (en) * 2010-12-17 2016-02-23 Cargill, Incorporated Reaction product from the co-dehydration of a sugar alcohol and a polyol
US20130019520A1 (en) * 2011-02-02 2013-01-24 Brown University Methods of Making Fatty Acids and Fatty Acid Alkyl Esters
WO2012123267A1 (en) * 2011-03-15 2012-09-20 Oce-Technologies B.V. Bio-based polyester latex
WO2013101999A1 (en) * 2011-12-28 2013-07-04 E. I. Du Pont De Nemours And Company Process for the production of furfural
MX2016007864A (es) * 2013-12-18 2016-09-07 Archer Daniels Midland Co Control de la formacion de cuerpos de color en la esterificacion de isohexida.

Also Published As

Publication number Publication date
US20170008902A1 (en) 2017-01-12
EP3083637A4 (en) 2017-05-31
KR20160098489A (ko) 2016-08-18
WO2015094895A1 (en) 2015-06-25
CN105829322A (zh) 2016-08-03
EP3083637A1 (en) 2016-10-26
AU2014366354A1 (en) 2016-06-16
CA2932349A1 (en) 2015-06-25
JP2017501138A (ja) 2017-01-12

Similar Documents

Publication Publication Date Title
CO7170148A2 (es) Enzimas car novedosas y producción mejorada de alcoholes grasos
EP2561928A4 (en) COPPER-BASED CATALYST IN NANOMETER SIZE, MANUFACTURING METHOD AND ALCOHOL MANUFACTURING METHOD THUS BY DIRECT HYDROGENATION OF CARBOXYLIC ACID
AR094464A1 (es) PRODUCCIÓN DE ÁCIDOS w-AMINO GRASOS
EA201590026A1 (ru) Выработка длинноцепочечных полиненасыщенных жирных кислот в растительных клетках
SG11201602744RA (en) Method for producing unsaturated carboxylic acid and supported catalyst
SG11201405023VA (en) Catalyst and process for the production of acetic acid and dimetyhl ether
MY161190A (en) Process for the conversion of a carbohydrate-containing feedstock
IN2015DN02292A (es)
GB201208589D0 (en) Improvements in or relating to organic compounds
PH12015500327A1 (en) Hydrogen catalyst and process for production thereof by the use of uncalcined starting material
IN2014DN08545A (es)
MY180404A (en) Production method for ?,?-unsaturated alcohols
MY179954A (en) Method for producing olefin
MX2016007949A (es) Procedimiento de acilacion de glicol mejorado.
IN2014KN00748A (es)
CL2011003163A1 (es) Celula huesped microbiana oleaginosa recombinante para la produccion mejorada de al menos un acido graso poliinsaturado de cadena larga que codifica un polipeptido con actividad acilcoa: lisofosfolipido; metodo para elaborar aceite que comprende acido eicosapentaenoico y/o acido docosahexaenoico.
MY166636A (en) Method for the production of carboxylic acid esters during a transport
IN2015DN00531A (es)
MX2013005745A (es) Metodo in vitro para determinar la presencia de piretroides tipo ii.
BR112015014106A2 (pt) politióis como catalisadores de isomerização cis/trans para compostos insaturados
BR112015014163A2 (pt) processo para a produção de um produto de hidrogenação
IN2015DN01264A (es)
PH12015501453A1 (en) Method for producing olefin
MY171325A (en) Method for preparing and isolating carboxylic esters
MY175686A (en) A process for production of a silica-supported alkali metal catalyst