MX2015017533A - The synthesis of new anionic surfactants and their use as collectors in froth flotation of non-sulphidic ores. - Google Patents

The synthesis of new anionic surfactants and their use as collectors in froth flotation of non-sulphidic ores.

Info

Publication number
MX2015017533A
MX2015017533A MX2015017533A MX2015017533A MX2015017533A MX 2015017533 A MX2015017533 A MX 2015017533A MX 2015017533 A MX2015017533 A MX 2015017533A MX 2015017533 A MX2015017533 A MX 2015017533A MX 2015017533 A MX2015017533 A MX 2015017533A
Authority
MX
Mexico
Prior art keywords
froth flotation
salt
collectors
synthesis
ores
Prior art date
Application number
MX2015017533A
Other languages
Spanish (es)
Inventor
SMOLKO-SCHVARZMAYR Natalija
Klingberg Anders
Original Assignee
Akzo Nobel Chemicals Int Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo Nobel Chemicals Int Bv filed Critical Akzo Nobel Chemicals Int Bv
Publication of MX2015017533A publication Critical patent/MX2015017533A/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/016—Macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/02—Froth-flotation processes
    • B03D1/021—Froth-flotation processes for treatment of phosphate ores
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
    • C07C237/02—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C237/04—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C237/12—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated having the nitrogen atom of at least one of the carboxamide groups bound to an acyclic carbon atom of a hydrocarbon radical substituted by carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/685—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
    • C08G63/6852—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from hydroxy carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/10—Alpha-amino-carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/36—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino acids, polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/44—Polyester-amides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/02—Collectors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00—Specified materials treated by the flotation agents; specified applications
    • B03D2203/02—Ores
    • B03D2203/04—Non-sulfide ores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00—Specified materials treated by the flotation agents; specified applications
    • B03D2203/02—Ores
    • B03D2203/04—Non-sulfide ores
    • B03D2203/06—Phosphate ores

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Paper (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Peptides Or Proteins (AREA)

Abstract

The present invention relates to a compound obtainable by reacting an N-acyl neutral amino acid or a salt thereof, or an N-acyl neutral amino acid oligopeptide or a salt thereof with a monohydroxy monocarboxylic acid or a salt thereof. This compound is useful as a collector in a process for froth flotation of non-sulfidic ores, especially phosphate ores. The invention also relates to a method which comprises the steps of a) conditioning a pulped phoshate ore, wherein the phosphate ore comprises a calcium phosphate mineral or a mixture of such minerals, and gangue minerals, with an effective amount of a calcium phosphate mineral collector reagent, which is the above-mentioned compound, and optionally other flotation aids and b) performing a froth flotation process to recover the calcium phosphate mineral(s).
MX2015017533A 2013-07-05 2014-07-02 The synthesis of new anionic surfactants and their use as collectors in froth flotation of non-sulphidic ores. MX2015017533A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13175270 2013-07-05
PCT/EP2014/064014 WO2015000931A2 (en) 2013-07-05 2014-07-02 The synthesis of new anionic surfactants and their use as collectors in froth flotation of non-sulphidic ores

Publications (1)

Publication Number Publication Date
MX2015017533A true MX2015017533A (en) 2016-08-08

Family

ID=48740974

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015017533A MX2015017533A (en) 2013-07-05 2014-07-02 The synthesis of new anionic surfactants and their use as collectors in froth flotation of non-sulphidic ores.

Country Status (10)

Country Link
US (1) US10543493B2 (en)
EP (1) EP3016746A2 (en)
AU (1) AU2014286223B2 (en)
BR (1) BR112015031783A2 (en)
CA (1) CA2914544A1 (en)
CL (1) CL2015003716A1 (en)
EA (1) EA033476B1 (en)
MA (1) MA38716B1 (en)
MX (1) MX2015017533A (en)
WO (1) WO2015000931A2 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EA033037B9 (en) 2014-09-18 2020-02-19 Норион Кемикалз Интернэшнл Б.В. Use of branched fatty alcohol alkoxylates as secondary collectors for froth flotation
CA3016794C (en) * 2016-03-22 2023-11-07 Akzo Nobel Chemicals International B.V. Use of emulsifier in collector composition
CN106076653B (en) * 2016-06-28 2018-08-24 武汉工程大学 A kind of preparation method of modified fat acid type Collophane anti-floatation collector
CN106179764A (en) * 2016-07-26 2016-12-07 武汉工程大学 The preparation method of vegetable fatty acid soap tartaric acid hydrocarbyl carbonate Compositional type phosphorite flotation collector
CN106269286B (en) * 2016-08-24 2019-12-06 武汉工程大学 Preparation method of sulfonated fatty acid phosphate reverse flotation collector
CN106391322B (en) * 2016-11-03 2019-07-23 武汉工程大学 A kind of low grade collophanite direct flotation collecting agent and preparation method thereof
AU2017381628B2 (en) 2016-12-23 2020-01-02 Akzo Nobel Chemicals International B.V. Process to treat phosphate ores
CN107029894A (en) * 2017-03-28 2017-08-11 常州大学 A kind of preparation method of low temperature resistant mid-low grade collophanite ore flotation collector
BR112019027877B1 (en) 2017-07-04 2023-03-21 Nouryon Chemicals International B.V PROCESS FOR TREATMENT OF SILICIOUS NON-SULFURIC OREES WITH A COLLECTOR COMPOSITION, COLLECTOR COMPOSITION AND SLUSH
CA3068881C (en) 2017-07-04 2024-03-19 Nouryon Chemicals International B.V. Process to treat carbonatitic non-sulfidic ores and collector composition therefor
CN108745652A (en) * 2018-04-28 2018-11-06 昆明理工大学 A kind of combination medicament and its application method for zinc oxide ore flotation
CN108722680A (en) * 2018-04-28 2018-11-02 昆明理工大学 A kind of phosphate rock floating combination medicament and its application method for high-silicon high magnesium
CN108722679A (en) * 2018-04-28 2018-11-02 昆明理工大学 A kind of combination medicament and its application method for middle low temperature phosphate rock floating
WO2020007971A1 (en) 2018-07-06 2020-01-09 Nouryon Chemicals International B.V. Process for froth flotation
CN112934477B (en) * 2021-02-22 2023-08-25 郑州大学 Bauxite treatment method
EP4364852A1 (en) 2022-11-04 2024-05-08 Nouryon Chemicals International B.V. Collector composition and flotation method

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE257398C (en)
US1453695A (en) 1922-02-18 1923-05-01 William H Miner Antifriction side bearing
US2744825A (en) 1951-12-12 1956-05-08 Patterson Co C Acyl lactylic acid products
US3074980A (en) 1958-12-18 1963-01-22 Procter & Gamble Process for making acyl amides of amino acid salts
DE1162305B (en) 1959-07-04 1964-02-06 Kloeckner Humboldt Deutz Ag Process for the flotation of minerals
US3425549A (en) * 1966-03-04 1969-02-04 Petrolite Corp Flotation process
GB1197672A (en) 1968-01-26 1970-07-08 Colgate Palmolive Co Process for Preparing Fatty Acyl Derivatives of Amino Acids.
US3985722A (en) 1973-12-12 1976-10-12 Ajinomoto Co., Inc. Process for preparing N-higher aliphatic acyl derivatives of amino acids, peptides or proteins
DE3238060A1 (en) 1982-10-14 1984-04-19 Henkel KGaA, 4000 Düsseldorf FLOTATION AGENTS AND METHOD FOR FLOTATION OF NON-SULFIDIC MINERALS
US4732667A (en) 1985-02-20 1988-03-22 Berol Kemi Ab Process and composition for the froth flotation beneficiation of iron minerals from iron ores
US4720339A (en) * 1985-03-15 1988-01-19 American Cyanamid Company Flotation beneficiation process for non-sulfide minerals
DE3517154A1 (en) 1985-05-11 1986-11-13 Henkel KGaA, 4000 Düsseldorf USE OF SURFACTANT MIXTURES AS AUXILIARIES FOR THE FLOTATION OF NON-SULFIDIC ORES
DD257398A1 (en) * 1987-02-05 1988-06-15 Akad Wissenschaften Ddr PROCESS FOR FLOTATION OF ANHYDRITE / GIPS
RU1453695C (en) * 1987-02-27 1994-11-30 НПТ "Протеин. ПАВ" Method of phosphate ore flotation
RU1751901C (en) * 1989-08-30 1994-03-30 НПТ "Протеин. ПАВ" Method of producing flotation agent
DE4105384A1 (en) 1990-02-28 1991-08-29 Hoechst Ag Selective flotation of phosphorus minerals - by using an N-acylated protein, peptide or penicillin hydrolysate as collector
DE4010279A1 (en) 1990-03-30 1991-10-02 Henkel Kgaa METHOD FOR OBTAINING MINERALS FROM NON-SULFIDIC ORNAMENTS BY FLOTATION
DE4016792A1 (en) 1990-05-25 1991-11-28 Henkel Kgaa METHOD FOR OBTAINING MINERALS FROM NON-SULFIDIC ORES BY FLOTATION
DE4117671A1 (en) 1991-05-29 1992-12-03 Henkel Kgaa METHOD FOR OBTAINING MINERALS FROM NON-SULFIDIC ORES BY FLOTATION
DE4133063A1 (en) 1991-10-04 1993-04-08 Henkel Kgaa PROCESS FOR PRODUCING IRON ORE CONCENTRATES BY FLOTATION
RU2083558C1 (en) 1993-08-06 1997-07-10 Научно-производственное товарищество "Протеин ПАВ" Process for preparing n-acylamino acid and salts thereof having surface active and flotation properties
US5646317A (en) 1993-10-25 1997-07-08 Kao Corporation Processes for the preparation of N-(long-chain acyl)amino acid and salt thereof, and intermediate amidonitrile and process for the preparation thereof
US5744062A (en) 1996-08-29 1998-04-28 R.I.T.A. Corporation Balanced emulsifier blends for oil-in-water emulsions
TW502011B (en) 1997-02-05 2002-09-11 Ajinomoto Kk Process for producing n-long-chain acyl acidic amino acids or salts thereof
AU2002950185A0 (en) 2002-07-12 2002-09-12 The Australian National University Enzyme inhibitors
CN100448968C (en) 2003-10-03 2009-01-07 味之素株式会社 Detergent compositions and processes for the production thereof
DE102006038853A1 (en) 2006-08-18 2008-02-21 Clariant International Limited Process for the preparation of acylglycinates by direct oxidation
DE102007055265A1 (en) 2007-11-20 2009-05-28 Clariant International Ltd. Process for the preparation of acylglycinates
DE102008003825A1 (en) 2008-01-10 2009-07-16 Clariant International Ltd. Process for the preparation of acylglycinates by direct oxidation
DE102011107503A1 (en) 2011-07-15 2012-03-01 Clariant International Ltd. Preparing acylglycinate compound useful in a composition, which is used as a surfactant in a cosmetic preparation, comprises reacting glycine with fatty acid chloride in water and in the presence of a basic alkali metal compound
US8822711B2 (en) 2011-07-28 2014-09-02 Conopco, Inc. Method for preparing fatty acyl amido carboxylic acid based surfactants
WO2013047458A1 (en) 2011-09-27 2013-04-04 互応化学工業株式会社 Gelling agent and gelled composition

Also Published As

Publication number Publication date
EP3016746A2 (en) 2016-05-11
MA38716B1 (en) 2018-12-31
CA2914544A1 (en) 2015-01-08
US10543493B2 (en) 2020-01-28
EA201690109A1 (en) 2016-08-31
WO2015000931A3 (en) 2019-06-06
AU2014286223A1 (en) 2015-12-24
AU2014286223B2 (en) 2017-12-21
CL2015003716A1 (en) 2016-08-19
US20160129456A1 (en) 2016-05-12
BR112015031783A2 (en) 2017-07-25
MA38716A1 (en) 2018-04-30
WO2015000931A2 (en) 2015-01-08
EA033476B1 (en) 2019-10-31

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