MX2015015901A - Productos de eter-esteres acrilados multifuncionales, proceso de preparacion y composiciones reticulables relacionadas. - Google Patents

Productos de eter-esteres acrilados multifuncionales, proceso de preparacion y composiciones reticulables relacionadas.

Info

Publication number
MX2015015901A
MX2015015901A MX2015015901A MX2015015901A MX2015015901A MX 2015015901 A MX2015015901 A MX 2015015901A MX 2015015901 A MX2015015901 A MX 2015015901A MX 2015015901 A MX2015015901 A MX 2015015901A MX 2015015901 A MX2015015901 A MX 2015015901A
Authority
MX
Mexico
Prior art keywords
compositions
polyol
groups
product
michael addition
Prior art date
Application number
MX2015015901A
Other languages
English (en)
Inventor
Philippe Ciceron
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France filed Critical Arkema France
Publication of MX2015015901A publication Critical patent/MX2015015901A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/12—Esters of phenols or saturated alcohols
    • C08F222/20—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/31—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
    • C07C69/734—Ethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/104—Esters of polyhydric alcohols or polyhydric phenols of tetraalcohols, e.g. pentaerythritol tetra(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/106—Esters of polycondensation macromers
    • C08F222/1063—Esters of polycondensation macromers of alcohol terminated polyethers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Sealing Material Composition (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
  • Paints Or Removers (AREA)

Abstract

La presente invención se relaciona con un producto acrilado multifuncional de funcionalidad promedio, f, superior a 3 y una densidad en acrilatos que va de 4 a 12 mmol por g, el cual es el producto de reacción por esterificación y por eterificación por vía de la reacción de adición de Michael, entre por lo menos un poliol R(OH)m de funcionalidad m de por lo menos 3 y de ácido acrílico (R1OH), con los grupos carboxi del ácido acrílico que están en ausencia con relación a los grupos hidroxi del poliol y en donde el producto final comprende por lo menos 3 acrilatos definidos de acuerdo con la siguiente fórmula general (I) y que corresponde a n=0, n=l, n=2; (R1O) - [-R [OR1] m-2 O(C=O)-CH2-CH2-O-]n-R-(OR1)-m-1 (I) siendo R el radical acriloilo (-(C=O)-CH=CH2), R el radical residual del poliol (R(OH)m y n el número de unidades repetitivas éter-éster obtenidas por adición de Michael, de los OH residuales de los éster acrilatos hidroxilados formados por esterificación parcial del poliol (por adición de Michael) sobre los grupos acrilatos de los ésteres acrilatos. La invención se relaciona igualmente con un procedimiento de preparación del producto, de composiciones reticulables que lo comprenden y su uso en los recubrimientos, composiciones de sellado, de molienda, de compuesto o de centelleo químico. Una ventaja particular de estas composiciones es su baja retracción a pesar de su funcionalidad elevada.
MX2015015901A 2013-05-23 2014-05-20 Productos de eter-esteres acrilados multifuncionales, proceso de preparacion y composiciones reticulables relacionadas. MX2015015901A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1354651A FR3005953B1 (fr) 2013-05-23 2013-05-23 Produits ether-esters acryles multifonctionnels, procede de preparation et compositions reticulables liees.
PCT/FR2014/051174 WO2014188117A1 (fr) 2013-05-23 2014-05-20 Produits ether-esters acryles multifonctionnels, procédé de préparation et compositions réticulables liées

Publications (1)

Publication Number Publication Date
MX2015015901A true MX2015015901A (es) 2016-03-04

Family

ID=48874349

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015015901A MX2015015901A (es) 2013-05-23 2014-05-20 Productos de eter-esteres acrilados multifuncionales, proceso de preparacion y composiciones reticulables relacionadas.

Country Status (11)

Country Link
US (1) US9682916B2 (es)
EP (1) EP2999690B1 (es)
JP (1) JP2016526074A (es)
KR (1) KR101810311B1 (es)
CN (1) CN105283437A (es)
CA (1) CA2911208C (es)
ES (1) ES2715022T3 (es)
FR (1) FR3005953B1 (es)
MX (1) MX2015015901A (es)
TW (1) TWI537247B (es)
WO (1) WO2014188117A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016216641A (ja) * 2015-05-22 2016-12-22 日油株式会社 硬化性樹脂組成物
KR20180096997A (ko) * 2017-02-22 2018-08-30 동우 화인켐 주식회사 플렉시블 윈도우 적층체 및 이를 포함하는 화상 표시 장치
CA3097876A1 (en) * 2018-05-03 2019-11-07 Dow Global Technologies Llc Method for providing substrate coated with a cured damping coating and coated substrate so provided
US11236244B2 (en) 2018-09-10 2022-02-01 Sun Chemical Corporation Energy curable compositions comprising partially acrylated polyols
EP3898784A1 (en) 2018-12-17 2021-10-27 Arkema France Multi(meth)acrylate-functionalized resins as co-agents for crosslinking of thermoplastic polymers
US10807063B1 (en) 2019-12-31 2020-10-20 Industrial Technology Research Institute Device and method for continuously manufacturing acrylate compound
KR20220115421A (ko) 2021-02-10 2022-08-17 엘지전자 주식회사 모터 조립체

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5914017B2 (ja) * 1976-03-19 1984-04-02 株式会社日本触媒 多官能性アクリレ−トの製造方法
JPS54125610A (en) * 1978-03-20 1979-09-29 Toagosei Chem Ind Co Ltd Preparation of polymerizable polyacrylate
CA1182469A (en) * 1981-12-11 1985-02-12 William D. Emmons Esters of michael addition homopolymers of acrylic acid
US5243069A (en) * 1981-12-11 1993-09-07 Rohm And Haas Company Ester of Michael addition homopolymers of acrylic acid
JP5315829B2 (ja) * 2008-07-22 2013-10-16 東亞合成株式会社 硬化型ハードコート剤組成物
JP2013001871A (ja) * 2011-06-20 2013-01-07 Mitsubishi Rayon Co Ltd 金属表面用被覆材組成物及び積層樹脂成型品

Also Published As

Publication number Publication date
KR101810311B1 (ko) 2017-12-18
US9682916B2 (en) 2017-06-20
CA2911208C (fr) 2018-05-29
FR3005953B1 (fr) 2016-05-27
ES2715022T3 (es) 2019-05-31
EP2999690A1 (fr) 2016-03-30
WO2014188117A1 (fr) 2014-11-27
CA2911208A1 (fr) 2014-11-27
US20160090349A1 (en) 2016-03-31
TWI537247B (zh) 2016-06-11
JP2016526074A (ja) 2016-09-01
FR3005953A1 (fr) 2014-11-28
EP2999690B1 (fr) 2018-12-19
KR20160013982A (ko) 2016-02-05
TW201504212A (zh) 2015-02-01
CN105283437A (zh) 2016-01-27

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