MX2015012415A - Procedimiento para rescatar metales alcalinos y azufre a parir de sulfuros y polisulfuros de metal alcalino. - Google Patents

Procedimiento para rescatar metales alcalinos y azufre a parir de sulfuros y polisulfuros de metal alcalino.

Info

Publication number
MX2015012415A
MX2015012415A MX2015012415A MX2015012415A MX2015012415A MX 2015012415 A MX2015012415 A MX 2015012415A MX 2015012415 A MX2015012415 A MX 2015012415A MX 2015012415 A MX2015012415 A MX 2015012415A MX 2015012415 A MX2015012415 A MX 2015012415A
Authority
MX
Mexico
Prior art keywords
alkali
sulfur
alkali metal
polysulfides
metal sulfides
Prior art date
Application number
MX2015012415A
Other languages
English (en)
Other versions
MX368152B (es
Inventor
John Howard Gordon
Javier Alvare
Original Assignee
Ceramatec Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ceramatec Inc filed Critical Ceramatec Inc
Publication of MX2015012415A publication Critical patent/MX2015012415A/es
Publication of MX368152B publication Critical patent/MX368152B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G15/00—Cracking of hydrocarbon oils by electric means, electromagnetic or mechanical vibrations, by particle radiation or with gases superheated in electric arcs
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G32/00—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G32/00—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms
    • C10G32/02—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms by electric or magnetic means
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/02—Electrolytic production, recovery or refining of metals by electrolysis of solutions of light metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Metallurgy (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Mechanical Engineering (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

Se pueden recuperar metales alcalinos (126) y azufre (128) un partir de monosulfuros y polisulfuros alcalinos (122) mediante un procedimiento electrolítico que utiliza una celda electrolítica (120) que tiene una membrana conductiva de ión de metal alcalino. Una solución de anolito incluye un monosulfuro de metal alcalino, un polisulfuro de metal alcalino, o una mezcla de éstos, y un solvente que disuelve azufre elemental. Un catolito incluye metal alcalino derretido. Si se aplica una corriente se oxidan el sulfuro y el polisulfuro se oxidan en el compartimiento del anolito, se mueven los iones del metal alcalino al pasar a través de la membrana conductiva del ion de metal alcalino al compartimiento del catolito, y se reducen los iones de metal alcalino en el compartimiento del catolito. El azufre líquido se separa de la solución de anolito y puede ser recuperado. La celda electrolítica es operada a una temperatura a la cual son derretidos el metal alcalino y el azufre que se han formado.
MX2015012415A 2013-03-14 2014-03-14 Procedimiento para rescatar metales alcalinos y azufre a parir de sulfuros y polisulfuros de metal alcalino. MX368152B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361781557P 2013-03-14 2013-03-14
PCT/US2014/027292 WO2014152393A1 (en) 2013-03-14 2014-03-14 Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides

Publications (2)

Publication Number Publication Date
MX2015012415A true MX2015012415A (es) 2016-07-26
MX368152B MX368152B (es) 2019-09-20

Family

ID=51581207

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015012415A MX368152B (es) 2013-03-14 2014-03-14 Procedimiento para rescatar metales alcalinos y azufre a parir de sulfuros y polisulfuros de metal alcalino.

Country Status (11)

Country Link
EP (1) EP2970780B1 (es)
JP (1) JP6230690B2 (es)
KR (1) KR102258315B1 (es)
CN (2) CN106757146B (es)
CA (1) CA2906000C (es)
ES (1) ES2674092T3 (es)
HK (1) HK1220476A1 (es)
MX (1) MX368152B (es)
MY (1) MY171961A (es)
SG (1) SG11201507505VA (es)
WO (1) WO2014152393A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10538847B2 (en) 2015-12-29 2020-01-21 Enlighten Innovations Inc. Method and apparatus for recovering metals and sulfur from feed streams containing metal sulfides and polysulfides
ES2862916T3 (es) * 2015-12-29 2021-10-08 Enlighten Innovations Inc Método y aparato para recuperar metales y azufre de corrientes de alimentación que contienen sulfuros y polisulfuros metálicos
CN108360025B (zh) * 2018-05-02 2019-05-07 东北大学 一种水溶液电解固态金属硫化物制备金属的方法
CN110565120B (zh) * 2019-10-18 2021-09-07 东北大学 一种在含铜铁液中脱除并回收铜的方法
US11486046B2 (en) 2020-03-04 2022-11-01 Enlighten Innovations Inc. Production of sodium metal by dual temperature electrolysis processes
JP7451247B2 (ja) 2020-03-17 2024-03-18 本田技研工業株式会社 リチウムイオンの回収方法
CN111564602B (zh) * 2020-05-23 2023-03-07 江西理工大学 一种电位控制直接制备锂硫电池液态正极的方法
KR20230087600A (ko) * 2020-10-19 2023-06-16 차이나 페트로리움 앤드 케미컬 코포레이션 연료유 생산 방법, 시스템 및 그 응용, 연료유 및 그 응용
AU2022210740A1 (en) * 2021-01-21 2023-08-10 Li-Metal Corp. Electrowinning cell for the production of a metal product and method of using same
US11976375B1 (en) 2022-11-11 2024-05-07 Li-Metal Corp. Fracture resistant mounting for ceramic piping

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6132590A (en) * 1998-01-09 2000-10-17 Huron Tech Corp Electrolytic process for treating aqueous waste streams
US7897028B2 (en) * 2004-01-26 2011-03-01 Ceramatec, Inc. Process for the recovery of materials from a desulfurization reaction
US7998341B2 (en) * 2004-11-08 2011-08-16 Intevep, S.A. Process for treating hydrocarbon feeds with electrolytic hydrogen
MX2009009166A (es) * 2007-02-26 2009-11-26 Trans Ionics Corp Desulfurizacion de corrientes del petroleo utilizando sodio metalico.
US8088270B2 (en) * 2007-11-27 2012-01-03 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
US8486251B2 (en) * 2008-08-05 2013-07-16 Exxonmobil Research And Engineering Company Process for regenerating alkali metal hydroxides by electrochemical means
CA2890794A1 (en) * 2008-10-09 2010-04-15 John Gordon Apparatus and method for reducing an alkali metal electrochemically at a temperature below the metal's melting temperature
WO2013019596A1 (en) * 2011-07-29 2013-02-07 Saudi Arabian Oil Company Process for in-situ electrochemical oxidative generation and conversion of organosulfur compounds

Also Published As

Publication number Publication date
EP2970780A1 (en) 2016-01-20
MX368152B (es) 2019-09-20
MY171961A (en) 2019-11-08
WO2014152393A1 (en) 2014-09-25
ES2674092T3 (es) 2018-06-27
HK1220476A1 (zh) 2017-05-05
SG11201507505VA (en) 2015-10-29
CA2906000C (en) 2021-05-04
JP6230690B2 (ja) 2017-11-15
EP2970780B1 (en) 2018-05-30
CA2906000A1 (en) 2014-09-25
JP2016519712A (ja) 2016-07-07
CN106757146B (zh) 2018-10-23
EP2970780A4 (en) 2016-11-02
KR102258315B1 (ko) 2021-06-01
CN105189706A (zh) 2015-12-23
KR20150127640A (ko) 2015-11-17
CN106757146A (zh) 2017-05-31

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