MX2015006496A - Sistemas cataliticos ziegler-natta de alto desempeño, procesos para producir catalizadores basados en mgc12 y uso de los mismos. - Google Patents
Sistemas cataliticos ziegler-natta de alto desempeño, procesos para producir catalizadores basados en mgc12 y uso de los mismos.Info
- Publication number
- MX2015006496A MX2015006496A MX2015006496A MX2015006496A MX2015006496A MX 2015006496 A MX2015006496 A MX 2015006496A MX 2015006496 A MX2015006496 A MX 2015006496A MX 2015006496 A MX2015006496 A MX 2015006496A MX 2015006496 A MX2015006496 A MX 2015006496A
- Authority
- MX
- Mexico
- Prior art keywords
- ziegler
- natta catalyst
- catalyst
- improved
- producing
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/10—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Se describen catalizadores Ziegler-Natta mejorados y métodos para fabricar el catalizador mejorado. El catalizador Ziegler-Natta se forma usando un soporte de MgC12-xROH esférico, donde R es una unidad de hidrocarburo lineal, cíclica o ramificada con 1-10 átomos de carbono y donde ROH es un alcohol o una mezcla de al menos dos alcoholes diferentes y donde x tiene un intervalo de aproximadamente 1.5 a 6.0, de manera preferente aproximadamente 2.5 a 4, de manera más preferente aproximadamente 2.9 a 3.4, y de manera aún más preferente 2.95 a 3.35. El catalizador Ziegler-Natta incluye un metal de transición del Grupo 4-8 y un donador interno que comprende un compuesto de diéter. El catalizador tiene actividad mejorada en las reacciones de copolimerización de olefina así como buena estereoregularidad y sensibilidad de hidrógeno, y puede ser útil en la producción de polímeros de propileno sin ftalato que tienen una distribución de peso molecular (PI (GPC)) en el intervalo de aproximadamente 5.75 a aproximadamente 9.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261729895P | 2012-11-26 | 2012-11-26 | |
PCT/EP2013/074465 WO2014079969A1 (en) | 2012-11-26 | 2013-11-22 | HIGH PERFORMANCE ZIEGLER-NATTA CATALYST SYSTEMS, PROCESS FOR PRODUCING SUCH MgCl2 BASED CATALYSTS AND USE THEREOF |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2015006496A true MX2015006496A (es) | 2015-10-29 |
MX363582B MX363582B (es) | 2019-03-27 |
Family
ID=49726703
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2015006496A MX363582B (es) | 2012-11-26 | 2013-11-22 | SISTEMAS CATALITICOS ZIEGLER-NATTA DE ALTO DESEMPEÑO, PROCESOS PARA PRODUCIR CATALIZADORES BASADOS EN MgC12 Y USO DE LOS MISMOS. |
Country Status (11)
Country | Link |
---|---|
US (2) | US9522968B2 (es) |
EP (2) | EP2935350A1 (es) |
JP (1) | JP6127149B2 (es) |
KR (1) | KR101748056B1 (es) |
CN (1) | CN104981486B (es) |
BR (1) | BR112015012078A8 (es) |
MX (1) | MX363582B (es) |
SG (2) | SG10201704438XA (es) |
TW (1) | TWI519553B (es) |
WO (1) | WO2014079969A1 (es) |
ZA (1) | ZA201503545B (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MY153117A (en) | 2008-12-31 | 2014-12-31 | Grace W R & Co | Procatalyst composition with substituted 1,2-phenylene aromatic diester internal donor and method |
US9826757B2 (en) * | 2013-03-15 | 2017-11-28 | Advance International Inc. | Automated method and system for recovering protein powder meal, pure omega 3 oil and purified distilled water from animal tissue |
JP6537118B2 (ja) * | 2013-08-07 | 2019-07-03 | 東洋合成工業株式会社 | 化学増幅フォトレジスト組成物及び装置の製造方法 |
EP3309183A1 (en) | 2016-10-14 | 2018-04-18 | SABIC Global Technologies B.V. | Polypropylene for use in bopp applications |
EP3606986A4 (en) | 2017-04-04 | 2021-01-20 | Braskem America, Inc. | HIGH ETHYLENE RANDOM COPOLYMER CONTAINING NON-MIGRANT OLIGOMERS |
US20220380496A1 (en) * | 2019-10-04 | 2022-12-01 | Borealis Ag | Ziegler-natta catalysts for olefin polymerization |
EP4389784A1 (en) | 2022-12-23 | 2024-06-26 | Lummus Novolen Technology Gmbh | Novel polymer blends comprising recycled polymers with enhanced properties |
EP4389810A1 (en) | 2022-12-23 | 2024-06-26 | Lummus Novolen Technology Gmbh | Polymer blends comprising recycled polymers with enhanced properties |
US20240209197A1 (en) | 2022-12-23 | 2024-06-27 | Lummus Novolen Technology Gmbh | Polymer blends comprising recycled polymers with enhanced properties |
EP4424723A1 (en) | 2023-02-28 | 2024-09-04 | Lummus Novolen Technology Gmbh | Polypropylene production using a propylene stream comprising propane |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
FI80055C (fi) | 1986-06-09 | 1990-04-10 | Neste Oy | Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner. |
IT1227258B (it) | 1988-09-30 | 1991-03-28 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
IT1230134B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
FI90247C (fi) | 1991-05-31 | 1994-01-10 | Borealis As | Menetelmä polymerointikatalyytin aktiivisten ja tasakokoisten kantajahiukkasten valmistamiseksi |
FI90248C (fi) | 1991-11-29 | 1994-01-10 | Borealis As | Menetelmä hiukkasmaisen kantajan valmistamiseksi olefiinipolymerointikatalyyttiä varten |
JP3280477B2 (ja) * | 1992-08-31 | 2002-05-13 | 三井化学株式会社 | オレフィン重合用固体状チタン触媒成分の調製方法 |
CA2121721C (en) * | 1993-04-29 | 2004-11-23 | Giampiero Morini | Crystalline propylene polymers having high melt flow rate values and a narrow molecular weight distribution |
TW400342B (en) | 1994-09-06 | 2000-08-01 | Chisso Corp | A process for producing a solid catalyst component for olefin polymerization and a process for producing an olefin polymer |
US7049377B1 (en) * | 1995-02-21 | 2006-05-23 | Basell Poliolefine Italia S.R.L. | 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers |
IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
IT1282691B1 (it) * | 1996-02-27 | 1998-03-31 | Montell North America Inc | Processo per la preparazione di copolimeri random del propilene e prodotti cosi' ottenuti |
JPH10310605A (ja) | 1997-05-13 | 1998-11-24 | Mitsui Chem Inc | α−オレフィンの重合方法 |
AU777683B2 (en) | 1999-04-15 | 2004-10-28 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
MXPA02000431A (es) * | 2001-01-12 | 2005-06-06 | Fina Technology | Produccion de resinas de polipropileno de flujo de fundicion ultra rapido. |
ES2418804T3 (es) | 2001-06-13 | 2013-08-16 | Basell Poliolefine Italia S.P.A. | Componentes y catalizadores para la (co)polimerización de olefinas |
RU2325404C2 (ru) | 2002-08-01 | 2008-05-27 | Базелль Полиолефин Италия С.П.А. | Высокостереорегулярный полипропилен с улучшенными свойствами |
RU2005128272A (ru) * | 2003-02-24 | 2006-08-10 | Чайна Петролеум Энд Кемикал Корпорейшн (Cn) | Комплексный носитель катализаторов полимеризации пропилена, каталитический компонент и катализатор, включающий указанный компонент |
HUE025490T2 (en) | 2005-01-19 | 2016-04-28 | Mitsui Chemicals Inc | Process for the production of olefin polymer |
CN101107275B (zh) | 2005-01-19 | 2011-06-22 | 三井化学株式会社 | 烯烃聚合物的制备方法及固体状钛催化剂成分 |
DK2013249T3 (en) | 2006-04-24 | 2015-09-07 | Total Res & Technology Feluy | Using a Ziegler-Natta catalyst to produce a polypropylene homopolymer or a random copolymer having a high melt index |
IL187637A (en) | 2007-11-26 | 2014-11-30 | Israel Aerospace Ind Ltd | A system and method for detecting proximity to the target |
MY161075A (en) * | 2008-06-11 | 2017-04-14 | Lummus Novolen Technology Gmbh | High activity ziegler-natta catalysts, process for producing catalyst and use thereof |
JP5689232B2 (ja) | 2009-03-24 | 2015-03-25 | 三井化学株式会社 | 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 |
CN102040690A (zh) | 2009-10-20 | 2011-05-04 | 中国石油化工股份有限公司 | 一种低灰分聚丙烯的制备方法 |
-
2013
- 2013-11-18 US US14/082,595 patent/US9522968B2/en active Active
- 2013-11-19 TW TW102142053A patent/TWI519553B/zh active
- 2013-11-22 EP EP13802264.5A patent/EP2935350A1/en not_active Ceased
- 2013-11-22 JP JP2015543437A patent/JP6127149B2/ja active Active
- 2013-11-22 MX MX2015006496A patent/MX363582B/es unknown
- 2013-11-22 WO PCT/EP2013/074465 patent/WO2014079969A1/en active Application Filing
- 2013-11-22 EP EP21175760.4A patent/EP3904399A1/en active Pending
- 2013-11-22 SG SG10201704438XA patent/SG10201704438XA/en unknown
- 2013-11-22 CN CN201380065805.8A patent/CN104981486B/zh active Active
- 2013-11-22 KR KR1020157015313A patent/KR101748056B1/ko active IP Right Grant
- 2013-11-22 BR BR112015012078A patent/BR112015012078A8/pt not_active Application Discontinuation
- 2013-11-22 SG SG11201504141VA patent/SG11201504141VA/en unknown
-
2015
- 2015-05-20 ZA ZA2015/03545A patent/ZA201503545B/en unknown
-
2016
- 2016-10-06 US US15/286,971 patent/US10066034B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
JP6127149B2 (ja) | 2017-05-10 |
BR112015012078A2 (pt) | 2017-07-11 |
US20170022304A1 (en) | 2017-01-26 |
EP3904399A1 (en) | 2021-11-03 |
US10066034B2 (en) | 2018-09-04 |
US9522968B2 (en) | 2016-12-20 |
BR112015012078A8 (pt) | 2019-10-01 |
EP2935350A1 (en) | 2015-10-28 |
TW201420621A (zh) | 2014-06-01 |
JP2015535540A (ja) | 2015-12-14 |
ZA201503545B (en) | 2016-10-26 |
KR20150091326A (ko) | 2015-08-10 |
US20140148566A1 (en) | 2014-05-29 |
TWI519553B (zh) | 2016-02-01 |
SG11201504141VA (en) | 2015-07-30 |
SG10201704438XA (en) | 2017-06-29 |
CN104981486A (zh) | 2015-10-14 |
KR101748056B1 (ko) | 2017-06-27 |
CN104981486B (zh) | 2018-04-20 |
MX363582B (es) | 2019-03-27 |
WO2014079969A1 (en) | 2014-05-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
MX363582B (es) | SISTEMAS CATALITICOS ZIEGLER-NATTA DE ALTO DESEMPEÑO, PROCESOS PARA PRODUCIR CATALIZADORES BASADOS EN MgC12 Y USO DE LOS MISMOS. | |
MY161075A (en) | High activity ziegler-natta catalysts, process for producing catalyst and use thereof | |
MX2015006495A (es) | Sistemas cataliticos ziegler-natta de alto desempeño, proceso para producir tales catalizadores soportados y el uso de los mismos. | |
MY181149A (en) | Amide ester internal electron donor and process | |
MX2016008016A (es) | Sistema catalizador para polimerizacion de una olefina. | |
WO2012004676A3 (en) | Process for producing high molecular weight polyethylene | |
MX2013007354A (es) | Proceso para producir una composicion de procatalizador con donador de electrones interno de alcoxialquilester y producto. | |
ATE551395T1 (de) | Hochreine heterophasige propylencopolymere | |
BRPI0916095A8 (pt) | Composição de procatalisador, composição catalítica e processo para produzir um polímero a base de olefinas | |
MX2016015770A (es) | Procatalizador para la polimerizacion de olefinas que comprende un monoester y donante interno de amidobenzoato. | |
CN101824106B (zh) | 烯烃聚合用催化组分及其催化剂 | |
WO2012004680A3 (en) | Process for producing high molecular weight polyethylene | |
WO2012064630A3 (en) | Solution polymerization process and procatalyst carrier systems useful therein | |
DE602007001805D1 (de) | Verfahren zur herstellung von propylenpolymeren mit geringem aschegehalt | |
WO2010123775A4 (en) | Procatalyst composition with adamantane and method | |
WO2012134719A8 (en) | Novel catalysts and methods of use thereof to produce vinyl terminated polymers | |
BR112015005338A2 (pt) | métodos para produzir um componente catalisador sólido para polimerização de olefina e para produzir um polímero de olefina, e, catalisador de polimerização de olefina | |
EA201300546A1 (ru) | Способ получения полимеров пропилена со сверхвысокой скоростью течения расплава | |
MX2012012073A (es) | Formacion de catalizador de ziegler-natta usando componentes no mezclados. | |
BR112016002597A2 (pt) | método para produzir um polímero à base de etileno em um processo de polimerização usando um agente autolimitante | |
EA038511B9 (ru) | Прокатализатор для полимеризации олефинов | |
CN101824108B (zh) | 一种齐格勒-纳塔催化剂 | |
WO2011081460A3 (ko) | 올레핀 중합용 지글러-나타 촉매 | |
CN101831016B (zh) | 一种烯烃聚合催化组分及其催化剂 | |
MX2012011914A (es) | Metodo para hacer catalizadores tipo ziegler-natta. |