MX2015006496A - Sistemas cataliticos ziegler-natta de alto desempeño, procesos para producir catalizadores basados en mgc12 y uso de los mismos. - Google Patents

Sistemas cataliticos ziegler-natta de alto desempeño, procesos para producir catalizadores basados en mgc12 y uso de los mismos.

Info

Publication number
MX2015006496A
MX2015006496A MX2015006496A MX2015006496A MX2015006496A MX 2015006496 A MX2015006496 A MX 2015006496A MX 2015006496 A MX2015006496 A MX 2015006496A MX 2015006496 A MX2015006496 A MX 2015006496A MX 2015006496 A MX2015006496 A MX 2015006496A
Authority
MX
Mexico
Prior art keywords
ziegler
natta catalyst
catalyst
improved
producing
Prior art date
Application number
MX2015006496A
Other languages
English (en)
Other versions
MX363582B (es
Inventor
Yvonne Denkwitz
Oliver Schuster
Andreas Winter
Original Assignee
Lummus Novolen Technology Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lummus Novolen Technology Gmbh filed Critical Lummus Novolen Technology Gmbh
Publication of MX2015006496A publication Critical patent/MX2015006496A/es
Publication of MX363582B publication Critical patent/MX363582B/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/06Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/10Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Se describen catalizadores Ziegler-Natta mejorados y métodos para fabricar el catalizador mejorado. El catalizador Ziegler-Natta se forma usando un soporte de MgC12-xROH esférico, donde R es una unidad de hidrocarburo lineal, cíclica o ramificada con 1-10 átomos de carbono y donde ROH es un alcohol o una mezcla de al menos dos alcoholes diferentes y donde x tiene un intervalo de aproximadamente 1.5 a 6.0, de manera preferente aproximadamente 2.5 a 4, de manera más preferente aproximadamente 2.9 a 3.4, y de manera aún más preferente 2.95 a 3.35. El catalizador Ziegler-Natta incluye un metal de transición del Grupo 4-8 y un donador interno que comprende un compuesto de diéter. El catalizador tiene actividad mejorada en las reacciones de copolimerización de olefina así como buena estereoregularidad y sensibilidad de hidrógeno, y puede ser útil en la producción de polímeros de propileno sin ftalato que tienen una distribución de peso molecular (PI (GPC)) en el intervalo de aproximadamente 5.75 a aproximadamente 9.
MX2015006496A 2012-11-26 2013-11-22 SISTEMAS CATALITICOS ZIEGLER-NATTA DE ALTO DESEMPEÑO, PROCESOS PARA PRODUCIR CATALIZADORES BASADOS EN MgC12 Y USO DE LOS MISMOS. MX363582B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261729895P 2012-11-26 2012-11-26
PCT/EP2013/074465 WO2014079969A1 (en) 2012-11-26 2013-11-22 HIGH PERFORMANCE ZIEGLER-NATTA CATALYST SYSTEMS, PROCESS FOR PRODUCING SUCH MgCl2 BASED CATALYSTS AND USE THEREOF

Publications (2)

Publication Number Publication Date
MX2015006496A true MX2015006496A (es) 2015-10-29
MX363582B MX363582B (es) 2019-03-27

Family

ID=49726703

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015006496A MX363582B (es) 2012-11-26 2013-11-22 SISTEMAS CATALITICOS ZIEGLER-NATTA DE ALTO DESEMPEÑO, PROCESOS PARA PRODUCIR CATALIZADORES BASADOS EN MgC12 Y USO DE LOS MISMOS.

Country Status (11)

Country Link
US (2) US9522968B2 (es)
EP (2) EP2935350A1 (es)
JP (1) JP6127149B2 (es)
KR (1) KR101748056B1 (es)
CN (1) CN104981486B (es)
BR (1) BR112015012078A8 (es)
MX (1) MX363582B (es)
SG (2) SG10201704438XA (es)
TW (1) TWI519553B (es)
WO (1) WO2014079969A1 (es)
ZA (1) ZA201503545B (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MY153117A (en) 2008-12-31 2014-12-31 Grace W R & Co Procatalyst composition with substituted 1,2-phenylene aromatic diester internal donor and method
US9826757B2 (en) * 2013-03-15 2017-11-28 Advance International Inc. Automated method and system for recovering protein powder meal, pure omega 3 oil and purified distilled water from animal tissue
JP6537118B2 (ja) * 2013-08-07 2019-07-03 東洋合成工業株式会社 化学増幅フォトレジスト組成物及び装置の製造方法
EP3309183A1 (en) 2016-10-14 2018-04-18 SABIC Global Technologies B.V. Polypropylene for use in bopp applications
EP3606986A4 (en) 2017-04-04 2021-01-20 Braskem America, Inc. HIGH ETHYLENE RANDOM COPOLYMER CONTAINING NON-MIGRANT OLIGOMERS
US20220380496A1 (en) * 2019-10-04 2022-12-01 Borealis Ag Ziegler-natta catalysts for olefin polymerization
EP4389784A1 (en) 2022-12-23 2024-06-26 Lummus Novolen Technology Gmbh Novel polymer blends comprising recycled polymers with enhanced properties
EP4389810A1 (en) 2022-12-23 2024-06-26 Lummus Novolen Technology Gmbh Polymer blends comprising recycled polymers with enhanced properties
US20240209197A1 (en) 2022-12-23 2024-06-27 Lummus Novolen Technology Gmbh Polymer blends comprising recycled polymers with enhanced properties
EP4424723A1 (en) 2023-02-28 2024-09-04 Lummus Novolen Technology Gmbh Polypropylene production using a propylene stream comprising propane

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1098272B (it) * 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
FI80055C (fi) 1986-06-09 1990-04-10 Neste Oy Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner.
IT1227258B (it) 1988-09-30 1991-03-28 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1230134B (it) * 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
FI90247C (fi) 1991-05-31 1994-01-10 Borealis As Menetelmä polymerointikatalyytin aktiivisten ja tasakokoisten kantajahiukkasten valmistamiseksi
FI90248C (fi) 1991-11-29 1994-01-10 Borealis As Menetelmä hiukkasmaisen kantajan valmistamiseksi olefiinipolymerointikatalyyttiä varten
JP3280477B2 (ja) * 1992-08-31 2002-05-13 三井化学株式会社 オレフィン重合用固体状チタン触媒成分の調製方法
CA2121721C (en) * 1993-04-29 2004-11-23 Giampiero Morini Crystalline propylene polymers having high melt flow rate values and a narrow molecular weight distribution
TW400342B (en) 1994-09-06 2000-08-01 Chisso Corp A process for producing a solid catalyst component for olefin polymerization and a process for producing an olefin polymer
US7049377B1 (en) * 1995-02-21 2006-05-23 Basell Poliolefine Italia S.R.L. 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers
IL117114A (en) 1995-02-21 2000-02-17 Montell North America Inc Components and catalysts for the polymerization ofolefins
IT1282691B1 (it) * 1996-02-27 1998-03-31 Montell North America Inc Processo per la preparazione di copolimeri random del propilene e prodotti cosi' ottenuti
JPH10310605A (ja) 1997-05-13 1998-11-24 Mitsui Chem Inc α−オレフィンの重合方法
AU777683B2 (en) 1999-04-15 2004-10-28 Basell Technology Company B.V. Components and catalysts for the polymerization of olefins
MXPA02000431A (es) * 2001-01-12 2005-06-06 Fina Technology Produccion de resinas de polipropileno de flujo de fundicion ultra rapido.
ES2418804T3 (es) 2001-06-13 2013-08-16 Basell Poliolefine Italia S.P.A. Componentes y catalizadores para la (co)polimerización de olefinas
RU2325404C2 (ru) 2002-08-01 2008-05-27 Базелль Полиолефин Италия С.П.А. Высокостереорегулярный полипропилен с улучшенными свойствами
RU2005128272A (ru) * 2003-02-24 2006-08-10 Чайна Петролеум Энд Кемикал Корпорейшн (Cn) Комплексный носитель катализаторов полимеризации пропилена, каталитический компонент и катализатор, включающий указанный компонент
HUE025490T2 (en) 2005-01-19 2016-04-28 Mitsui Chemicals Inc Process for the production of olefin polymer
CN101107275B (zh) 2005-01-19 2011-06-22 三井化学株式会社 烯烃聚合物的制备方法及固体状钛催化剂成分
DK2013249T3 (en) 2006-04-24 2015-09-07 Total Res & Technology Feluy Using a Ziegler-Natta catalyst to produce a polypropylene homopolymer or a random copolymer having a high melt index
IL187637A (en) 2007-11-26 2014-11-30 Israel Aerospace Ind Ltd A system and method for detecting proximity to the target
MY161075A (en) * 2008-06-11 2017-04-14 Lummus Novolen Technology Gmbh High activity ziegler-natta catalysts, process for producing catalyst and use thereof
JP5689232B2 (ja) 2009-03-24 2015-03-25 三井化学株式会社 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法
CN102040690A (zh) 2009-10-20 2011-05-04 中国石油化工股份有限公司 一种低灰分聚丙烯的制备方法

Also Published As

Publication number Publication date
JP6127149B2 (ja) 2017-05-10
BR112015012078A2 (pt) 2017-07-11
US20170022304A1 (en) 2017-01-26
EP3904399A1 (en) 2021-11-03
US10066034B2 (en) 2018-09-04
US9522968B2 (en) 2016-12-20
BR112015012078A8 (pt) 2019-10-01
EP2935350A1 (en) 2015-10-28
TW201420621A (zh) 2014-06-01
JP2015535540A (ja) 2015-12-14
ZA201503545B (en) 2016-10-26
KR20150091326A (ko) 2015-08-10
US20140148566A1 (en) 2014-05-29
TWI519553B (zh) 2016-02-01
SG11201504141VA (en) 2015-07-30
SG10201704438XA (en) 2017-06-29
CN104981486A (zh) 2015-10-14
KR101748056B1 (ko) 2017-06-27
CN104981486B (zh) 2018-04-20
MX363582B (es) 2019-03-27
WO2014079969A1 (en) 2014-05-30

Similar Documents

Publication Publication Date Title
MX363582B (es) SISTEMAS CATALITICOS ZIEGLER-NATTA DE ALTO DESEMPEÑO, PROCESOS PARA PRODUCIR CATALIZADORES BASADOS EN MgC12 Y USO DE LOS MISMOS.
MY161075A (en) High activity ziegler-natta catalysts, process for producing catalyst and use thereof
MX2015006495A (es) Sistemas cataliticos ziegler-natta de alto desempeño, proceso para producir tales catalizadores soportados y el uso de los mismos.
MY181149A (en) Amide ester internal electron donor and process
MX2016008016A (es) Sistema catalizador para polimerizacion de una olefina.
WO2012004676A3 (en) Process for producing high molecular weight polyethylene
MX2013007354A (es) Proceso para producir una composicion de procatalizador con donador de electrones interno de alcoxialquilester y producto.
ATE551395T1 (de) Hochreine heterophasige propylencopolymere
BRPI0916095A8 (pt) Composição de procatalisador, composição catalítica e processo para produzir um polímero a base de olefinas
MX2016015770A (es) Procatalizador para la polimerizacion de olefinas que comprende un monoester y donante interno de amidobenzoato.
CN101824106B (zh) 烯烃聚合用催化组分及其催化剂
WO2012004680A3 (en) Process for producing high molecular weight polyethylene
WO2012064630A3 (en) Solution polymerization process and procatalyst carrier systems useful therein
DE602007001805D1 (de) Verfahren zur herstellung von propylenpolymeren mit geringem aschegehalt
WO2010123775A4 (en) Procatalyst composition with adamantane and method
WO2012134719A8 (en) Novel catalysts and methods of use thereof to produce vinyl terminated polymers
BR112015005338A2 (pt) métodos para produzir um componente catalisador sólido para polimerização de olefina e para produzir um polímero de olefina, e, catalisador de polimerização de olefina
EA201300546A1 (ru) Способ получения полимеров пропилена со сверхвысокой скоростью течения расплава
MX2012012073A (es) Formacion de catalizador de ziegler-natta usando componentes no mezclados.
BR112016002597A2 (pt) método para produzir um polímero à base de etileno em um processo de polimerização usando um agente autolimitante
EA038511B9 (ru) Прокатализатор для полимеризации олефинов
CN101824108B (zh) 一种齐格勒-纳塔催化剂
WO2011081460A3 (ko) 올레핀 중합용 지글러-나타 촉매
CN101831016B (zh) 一种烯烃聚合催化组分及其催化剂
MX2012011914A (es) Metodo para hacer catalizadores tipo ziegler-natta.