MX2014000839A - Metodos para preparar sales de amonio de diacidos c4 por fermentacion y metodos integrados para fabricar derivados c4 de los mismos. - Google Patents

Metodos para preparar sales de amonio de diacidos c4 por fermentacion y metodos integrados para fabricar derivados c4 de los mismos.

Info

Publication number
MX2014000839A
MX2014000839A MX2014000839A MX2014000839A MX2014000839A MX 2014000839 A MX2014000839 A MX 2014000839A MX 2014000839 A MX2014000839 A MX 2014000839A MX 2014000839 A MX2014000839 A MX 2014000839A MX 2014000839 A MX2014000839 A MX 2014000839A
Authority
MX
Mexico
Prior art keywords
diacids
salts
methods
ammonium
divalent metal
Prior art date
Application number
MX2014000839A
Other languages
English (en)
Inventor
chi-cheng Ma
Todd Werpy
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of MX2014000839A publication Critical patent/MX2014000839A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
    • C07C51/493—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification whereby carboxylic acid esters are formed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/24—Oxygen or sulfur atoms
    • C07D207/26—2-Pyrrolidones
    • C07D207/263—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms
    • C07D207/267—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
    • C12P7/44—Polycarboxylic acids
    • C12P7/46—Dicarboxylic acids having four or less carbon atoms, e.g. fumaric acid, maleic acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Zoology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biotechnology (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Microbiology (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Se describen métodos para formar sales amónicas de diácidos C4 en un proceso de fermentación con la eliminación de sales carbonato de un metal divalente. El pH de los caldos de fermentación para la producción de diácidos C4 se controla añadiendo compuestos cálcicos o magnésicos que contienen oxígeno alcalinos, que forman sales de metales divalentes de los diácidos. Las sales de metales divalentes de los diácidos se remplazan por amonio mediante la introducción de sales amónicas a una temperatura y presión elevadas formando sales amónicas solubles de estos. Se añade simultáneamente CO2 o bicarbonato al medio de fermentación a la temperatura y la presión elevadas. La reducción de la temperatura y la presión forma sales carbonato de metales divalentes insolubles que se separan de las sales amónicas de los diácidos disueltas. Las sales carbonato recuperadas se pueden reciclar como materiales para controlar el pH en fermentaciones posteriores. Las sales amónicas de los diácidos disueltas pueden formar los derivados N-metil-2-pirrolidina (NMP), gamma-butirolactona (GBL) y 1,4-butanodiol (BDO) en reacciones en un único recipiente.
MX2014000839A 2011-07-21 2012-07-09 Metodos para preparar sales de amonio de diacidos c4 por fermentacion y metodos integrados para fabricar derivados c4 de los mismos. MX2014000839A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161510209P 2011-07-21 2011-07-21
US201161510204P 2011-07-21 2011-07-21
PCT/US2012/045937 WO2013012590A1 (en) 2011-07-21 2012-07-09 Methods for preparation of ammonium salts of c4 diacids by fermentation and integrated methods for making c4 derivatives thereof

Publications (1)

Publication Number Publication Date
MX2014000839A true MX2014000839A (es) 2014-09-22

Family

ID=47558393

Family Applications (2)

Application Number Title Priority Date Filing Date
MX2014000838A MX360202B (es) 2011-07-21 2012-07-09 Metodos para preparar sales de amonio de diácidos c4 por fermentación y métodos integrados para fabricar derivados c4 de los mismos.
MX2014000839A MX2014000839A (es) 2011-07-21 2012-07-09 Metodos para preparar sales de amonio de diacidos c4 por fermentacion y metodos integrados para fabricar derivados c4 de los mismos.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
MX2014000838A MX360202B (es) 2011-07-21 2012-07-09 Metodos para preparar sales de amonio de diácidos c4 por fermentación y métodos integrados para fabricar derivados c4 de los mismos.

Country Status (8)

Country Link
US (3) US20140127767A1 (es)
EP (2) EP2734509B1 (es)
CN (2) CN103827308B (es)
BR (2) BR112014001342A2 (es)
ES (1) ES2717873T3 (es)
MX (2) MX360202B (es)
TR (1) TR201904063T4 (es)
WO (2) WO2013012590A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130072714A1 (en) * 2011-09-16 2013-03-21 BioAmber International S.à.r.l. Biobased compositions of diammonium succinate, monoammonium succinate and/or succinic acid and derivatives thereof
WO2017073640A1 (ja) * 2015-10-28 2017-05-04 花王株式会社 Ｃ４ジカルボン酸の製造方法

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2816923A (en) * 1956-03-13 1957-12-17 California Research Corp Conversion of maleic acid to fumaric acid
US3117991A (en) * 1960-07-29 1964-01-14 Halcon International Inc Preparation of fumaric acid by heating malic acid with maleic anhydride
US3113138A (en) * 1961-12-20 1963-12-03 Fmc Corp Preparation of butyrolactone
US3923597A (en) * 1974-08-01 1975-12-02 Gen Electric Mercury concentration by the use of microorganisms
US4059513A (en) * 1975-08-04 1977-11-22 Zadera Karel V Treatment of water to remove certain ions therefrom
US4048013A (en) * 1976-06-10 1977-09-13 Gesellschaft Fur Molekularbiologische Forschung Mbh Process for producing single-cell protein from methanol using methylomonas sp. DSM 580
US5008468A (en) * 1986-04-16 1991-04-16 Catalytica, Inc. Acid catalyzed process
GB8707595D0 (en) * 1987-03-31 1987-05-07 British Petroleum Co Plc Chemical process
DE4018242A1 (de) * 1990-06-07 1991-12-12 Basf Ag Verfahren zur herstellung von n-substituierten pyrrolidonen
US5766439A (en) * 1996-10-10 1998-06-16 A. E. Staley Manufacturing Co. Production and recovery of organic acids
US5969164A (en) * 1996-12-20 1999-10-19 The Standard Oil Company Catalysts for the hydrogenation of maleic acid to 1,4-butanediol
US6071728A (en) * 1997-01-09 2000-06-06 Amylum Belgium, N.V. Process for the production of crystalline aspartic acid
US5958744A (en) * 1997-08-18 1999-09-28 Applied Carbochemicals Succinic acid production and purification
US6603021B2 (en) 2001-06-18 2003-08-05 Battelle Memorial Institute Methods of making pyrrolidones
US7199250B2 (en) * 2002-12-20 2007-04-03 Battelle Memorial Institute Process for producing cyclic compounds
BRPI0416274A (pt) * 2003-11-07 2007-01-09 Mitsubishi Chemical Corp E Aji método para produzir solução de amÈnio de ácido orgánico
JP2005295998A (ja) * 2003-11-07 2005-10-27 Mitsubishi Chemicals Corp 有機酸アンモニウム溶液の製造方法
CN1878868A (zh) * 2003-11-07 2006-12-13 三菱化学株式会社 制造有机酸铵溶液的方法
WO2006066839A2 (de) * 2004-12-21 2006-06-29 Basf Aktiengesellschaft Verfahren zur herstellung von pyrrolidonen aus succinaten aus fermentationsbrühen
EP2157185B1 (en) * 2007-05-18 2014-05-14 Ajinomoto Co., Inc. Process for production of succinic acid, and process for production of ammonium succinate solution
KR101575912B1 (ko) 2007-08-17 2015-12-08 바스프 에스이 파스테우렐라세애의 카복실산 생산 구성원
DK2215213T3 (da) * 2007-11-01 2013-07-22 Oberon Fmr Inc Slambaseret tilsætningsstof til dyrfoder og fremgangsmåde til fremstilling heraf
CA2625511A1 (en) * 2008-03-13 2009-09-13 Dilum Dunuwila Process for the direct production of esters of carboxylic acids from fermentation broths
FR2933978B1 (fr) * 2008-07-18 2012-12-21 Arkema France Fabrication d'anhydride maleique a partir de matieres renouvelables, anhydride maleique obtenu et utilisations
KR101767034B1 (ko) * 2008-12-02 2017-08-10 푸락 바이오켐 비.브이. １가 숙신산 염의 제조방법
CN101475477A (zh) * 2009-01-23 2009-07-08 上海化学试剂研究所 反丁烯二酸二甲酯的制备方法
EP3505619A1 (en) 2009-02-16 2019-07-03 Basf Se Novel microbial succinic acid producers and purification of succinic acid
US8431372B2 (en) 2009-06-19 2013-04-30 Mbi International Fermentation method using a magnesium compound containing oxygen
BRPI1013955A2 (pt) * 2009-07-01 2015-08-25 Novozymes North America Inc Processo para separar e recuperar o ácido dicarboxílixo c4
CN102918017B (zh) * 2010-03-26 2014-12-17 生物琥珀酸有限公司 从含有琥珀酸二铵、琥珀酸一铵和/或琥珀酸的发酵液制备琥珀酸一铵的方法及琥珀酸一铵到琥珀酸的转化
US8399687B2 (en) * 2010-04-01 2013-03-19 Bioamber International S.A.R.L. Processes for the production of hydrogenated products
US8466300B2 (en) * 2010-04-01 2013-06-18 Bioamber International S.A.R.L. Processes for the production of hydrogenated products
CN102947259A (zh) * 2010-04-01 2013-02-27 生物琥珀酸国际责任有限公司 从琥珀酸盐制备四氢呋喃、γ-丁内酯和/或丁二醇的方法
JP2013528604A (ja) * 2010-05-19 2013-07-11 ビオアンブ，ソシエテ パ アクシオンス シンプリフィエ ピロリドンの製造方法
JP2013528605A (ja) * 2010-05-19 2013-07-11 ビオアンブ，ソシエテ パ アクシオンス シンプリフィエ ピロリドン類の製造方法

Also Published As

Publication number Publication date
MX360202B (es) 2018-10-25
US20170029353A1 (en) 2017-02-02
CN103827308B (zh) 2016-08-24
EP2734509B1 (en) 2018-12-26
BR112014001382B1 (pt) 2020-11-10
WO2013012589A1 (en) 2013-01-24
ES2717873T3 (es) 2019-06-26
EP2734629A4 (en) 2015-02-25
WO2013012590A1 (en) 2013-01-24
TR201904063T4 (tr) 2019-04-22
US20140162326A1 (en) 2014-06-12
EP2734629A1 (en) 2014-05-28
US20140127767A1 (en) 2014-05-08
BR112014001342A2 (pt) 2017-10-03
EP2734509A4 (en) 2015-03-04
MX2014000838A (es) 2015-04-08
CN103797003B (zh) 2016-10-26
EP2734509A1 (en) 2014-05-28
BR112014001382A2 (pt) 2017-04-25
CN103797003A (zh) 2014-05-14
CN103827308A (zh) 2014-05-28

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