MX2012005136A - Proceso integrado para produccion de fluoro-olefina. - Google Patents
Proceso integrado para produccion de fluoro-olefina.Info
- Publication number
- MX2012005136A MX2012005136A MX2012005136A MX2012005136A MX2012005136A MX 2012005136 A MX2012005136 A MX 2012005136A MX 2012005136 A MX2012005136 A MX 2012005136A MX 2012005136 A MX2012005136 A MX 2012005136A MX 2012005136 A MX2012005136 A MX 2012005136A
- Authority
- MX
- Mexico
- Prior art keywords
- hydrofluorination
- hcfc
- vapor phase
- liquid phase
- tcp
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/07—Purification ; Separation
- C01B7/0706—Purification ; Separation of hydrogen chloride
- C01B7/0718—Purification ; Separation of hydrogen chloride by adsorption
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/07—Purification ; Separation
- C01B7/0706—Purification ; Separation of hydrogen chloride
- C01B7/0731—Purification ; Separation of hydrogen chloride by extraction
- C01B7/0737—Purification ; Separation of hydrogen chloride by extraction hydrogen chloride being extracted
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/19—Fluorine; Hydrogen fluoride
- C01B7/191—Hydrogen fluoride
- C01B7/195—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
- C07C17/087—Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Se describe un proceso para la manufactura de HFO1234yf de TCP en tres pasos integrados que incluyen hidrofluoración de TCP (tetracloropropeno) a HCF-1233xf en la fase de vapor seguido por hidrofluoración de HCFC-1233xf a HCFC-244bb en la fase líquida que se sigue después por deshidrocloración en fase líquida o de vapor para producir HFO-1234yf. La hidrofluoración en fase de vapor se lleva a cabo a una presión superior que la hidrofluoración en fase líquida, eliminando así la necesidad de compresión y/o recuperación intermedia. También, cualquier HC1 generado de esta reacción se alimenta a la sección de hidrofluoración en fase líquida para promover agitación y mezclado. Esto da como resultado un proceso más económico de un capital inicial y costo de operación contra la conducción de los 3 pasos secuencialmente.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/611,288 US8618340B2 (en) | 2009-11-03 | 2009-11-03 | Integrated process for fluoro-olefin production |
PCT/US2010/053486 WO2011056441A2 (en) | 2009-11-03 | 2010-10-21 | Integrated process for fluoro-olefin production |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2012005136A true MX2012005136A (es) | 2012-05-23 |
Family
ID=43926113
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2012005136A MX2012005136A (es) | 2009-11-03 | 2010-10-21 | Proceso integrado para produccion de fluoro-olefina. |
Country Status (7)
Country | Link |
---|---|
US (1) | US8618340B2 (es) |
EP (1) | EP2496541B1 (es) |
JP (1) | JP5732062B2 (es) |
CN (1) | CN102656132B (es) |
ES (1) | ES2509640T3 (es) |
MX (1) | MX2012005136A (es) |
WO (1) | WO2011056441A2 (es) |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9024092B2 (en) * | 2006-01-03 | 2015-05-05 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
US8952208B2 (en) * | 2006-01-03 | 2015-02-10 | Honeywell International Inc. | Method for prolonging a catalyst's life during hydrofluorination |
US20170253545A1 (en) | 2007-01-03 | 2017-09-07 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
US9670117B2 (en) | 2007-01-03 | 2017-06-06 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
US8563789B2 (en) * | 2007-06-27 | 2013-10-22 | Arkema Inc. | Process for the manufacture of hydrofluoroolefins |
US8846990B2 (en) | 2007-07-06 | 2014-09-30 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
US9493384B2 (en) | 2007-07-06 | 2016-11-15 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
US9890096B2 (en) | 2011-01-19 | 2018-02-13 | Honeywell International Inc. | Methods of making 2,3,3,3-tetrafluoro-2-propene |
US9000240B2 (en) | 2011-05-19 | 2015-04-07 | Honeywell International Inc. | Integrated process for the production of 1-chloro-3,3,3-trifluoropropene |
MX2020001859A (es) * | 2011-09-15 | 2021-12-14 | Daikin Ind Ltd | Método para purificar hidrocarburos clorados. |
EP2760812A4 (en) * | 2011-09-30 | 2015-08-05 | Honeywell Int Inc | PROCESS FOR THE PREPARATION OF 2,3,3,3-TETRAFLUOROPROPES |
CN103946197B (zh) * | 2011-09-30 | 2017-02-22 | 霍尼韦尔国际公司 | 制造2,3,3,3‑四氟丙烯的方法 |
JP2014534177A (ja) * | 2011-09-30 | 2014-12-18 | ハネウェル・インターナショナル・インコーポレーテッド | 2,3,3,3−テトラフルオロプロペンの製造方法 |
US8796493B2 (en) * | 2011-09-30 | 2014-08-05 | Honeywell International Inc. | Methods to separate halogentated olefins from 2-chloro-1,1,1,2-tetrafluoropropane using a solid adsorbent |
ES2856227T3 (es) * | 2011-10-14 | 2021-09-27 | Honeywell Int Inc | Proceso para producir 2,3,3,3-tetrafluoropropeno |
MX357840B (es) * | 2011-11-04 | 2018-07-26 | Bektesevic Selma | Proceso para producir 2,3,3,3-tetrafluoropropeno. |
CN104284874A (zh) * | 2011-11-04 | 2015-01-14 | 汪海有 | 用于产生2,3,3,3-四氟丙烯的方法 |
MX344116B (es) * | 2011-11-10 | 2016-12-06 | Joseph Nappa Mario | Proceso de fluoracion catalitica de fabricacion de hidrohaloalcanos. |
US20130158250A1 (en) * | 2011-12-16 | 2013-06-20 | Honeywell International, Inc. | Method of deacidifying cellulose based materials |
CN104781219B (zh) * | 2012-02-10 | 2018-08-17 | 汪海有 | 用于制造2,3,3,3-四氟丙烯的改进的方法 |
EP4098644A1 (en) * | 2012-02-29 | 2022-12-07 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
US9162945B2 (en) * | 2012-03-22 | 2015-10-20 | Daikin Industries, Ltd. | Process for preparing 2-chloro-3,3,3-trifluoropropene |
US9018428B2 (en) | 2012-09-06 | 2015-04-28 | Honeywell International Inc. | Reactor and agitator useful in a process for making 1-chloro-3,3,3-trifluoropropene |
ES2709201T3 (es) | 2013-03-12 | 2019-04-15 | Honeywell Int Inc | Un método de mitigar la formación de HCF-245cb durante la hidrofluoración de HCFO-1233xf en HCFC-244bb |
MX2015011156A (es) * | 2013-03-13 | 2015-11-09 | Honeywell Int Inc | Procedimiento de fluoracion escalonado y sistema de reactores. |
US9272968B2 (en) | 2013-03-14 | 2016-03-01 | Honeywell International Inc. | Process to suppress the formation of 3,3,3-trifluoropropyne in fluorocarbon manufacture |
US9353029B2 (en) * | 2013-03-14 | 2016-05-31 | Honeywell International, Inc. | Fluorination process and reactor |
CN107827707A (zh) * | 2013-03-15 | 2018-03-23 | 霍尼韦尔国际公司 | 制备2‑氯‑1,1,1,2‑四氟丙烷(HCFC‑244bb)的方法 |
US20140275651A1 (en) * | 2013-03-15 | 2014-09-18 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
US9233895B2 (en) | 2013-03-15 | 2016-01-12 | Honeywell International, Inc. | Process to manufacture 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) |
US9334206B2 (en) * | 2013-03-15 | 2016-05-10 | Honeywell International Inc. | Integrated process to produce 2,3,3,3-tetrafluoropropene |
FR3003565B1 (fr) * | 2013-03-20 | 2018-06-29 | Arkema France | Composition comprenant hf et 2,3,3,3-tetrafluoropropene |
WO2014172592A1 (en) * | 2013-04-18 | 2014-10-23 | Honeywell International Inc. | Reaction system and process to produce fluorinated organics |
JP5825299B2 (ja) | 2013-07-12 | 2015-12-02 | ダイキン工業株式会社 | 2,3,3,3−テトラフルオロプロペンの製造方法 |
CN105960277A (zh) * | 2014-02-10 | 2016-09-21 | 霍尼韦尔国际公司 | 用于液相氟化的反应器设计 |
JP6210073B2 (ja) | 2015-01-21 | 2017-10-11 | ダイキン工業株式会社 | フルオロプロペンの製造方法 |
CN113527036A (zh) | 2015-05-21 | 2021-10-22 | 科慕埃弗西有限公司 | 通过SbF5进行的1233xf至244bb的氢氟化 |
US9790151B2 (en) | 2015-11-12 | 2017-10-17 | Honeywell International Inc. | Process for making 2,3,3,3-tetrafluoropropene and/or vinylidine fluoride |
US9856193B2 (en) | 2015-11-12 | 2018-01-02 | Honeywell International Inc. | Process for the production of fluorinated cyclobutane |
US10005705B2 (en) | 2015-11-12 | 2018-06-26 | Honeywell International Inc. | Process for the production of fluorinated cyclobutane |
ES2890532T3 (es) | 2016-11-08 | 2022-01-20 | Honeywell Int Inc | Un procedimiento para la producción de ciclobutano fluorado |
WO2018231764A1 (en) * | 2017-06-12 | 2018-12-20 | Honeywell International Inc. | Method to produce hfo-1234yf from tcp by suppressing the bubble/dew point |
KR20210008102A (ko) | 2018-06-06 | 2021-01-20 | 허니웰 인터내셔날 인코포레이티드 | HFO-1234yf를 제조하기 위한 HCFC-244bb의 탈염화수소화 방법 |
MX2021002098A (es) | 2018-08-24 | 2021-04-28 | Honeywell Int Inc | Procesos para producir trifluoroyodometano y yoduro de trifluoroacetilo. |
WO2020132307A1 (en) | 2018-12-21 | 2020-06-25 | Honeywell International Inc. | Azeotrope or azeotrope-like compositions of 1,2,2-trifluoro-1-trifluoromethylcyclobutane (tfmcb) and applications thereof |
CN109534951B (zh) * | 2018-12-30 | 2021-09-28 | 山东华安新材料有限公司 | 一种2,3,3,3-四氟丙烯混合物的分离装置及分离方法 |
US11554956B2 (en) | 2019-04-16 | 2023-01-17 | Honeywell International Inc. | Integrated process and catalysts for manufacturing hydrogen iodide from hydrogen and iodine |
US20220234890A1 (en) * | 2019-08-30 | 2022-07-28 | Showa Denko K.K. | Method for producing fluorine gas |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005108332A1 (en) * | 2004-04-29 | 2005-11-17 | Honeywell International, Inc. | Processes for synthesis of 1,3,3,3-tetrafluoropropene |
US8058486B2 (en) * | 2004-04-29 | 2011-11-15 | Honeywell International Inc. | Integrated process to produce 2,3,3,3-tetrafluoropropene |
US8084653B2 (en) * | 2004-04-29 | 2011-12-27 | Honeywell International, Inc. | Method for producing fluorinated organic compounds |
EP2546225B1 (en) * | 2006-01-03 | 2017-12-20 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
US8071825B2 (en) * | 2006-01-03 | 2011-12-06 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
WO2008054778A2 (en) | 2006-10-31 | 2008-05-08 | E. I. Du Pont De Nemours And Company | Processes for producing 2,3,3,3-tetrafluoropropene, a process for producing 1-chloro-2,2,3,3,3-pentafluoropropane and azeotropic compositions of 1-chloro-2,3,3,3-tetrafluoropropene with hf |
US8318992B2 (en) | 2006-10-31 | 2012-11-27 | E I Du Pont De Nemours And Company | Processes for the production of fluoropropanes and halopropenes |
TW200837036A (en) | 2006-11-15 | 2008-09-16 | Du Pont | Process for producing 2,3,3,3-tetrafluoropropene |
US9040759B2 (en) * | 2007-07-06 | 2015-05-26 | Honeywell International Inc. | Preparation of fluorinated olefins via catalytic dehydrohalogenation of halogenated hydrocarbons |
US7795480B2 (en) * | 2007-07-25 | 2010-09-14 | Honeywell International Inc. | Method for producing 2-chloro-3,3,3,-trifluoropropene (HCFC-1233xf) |
WO2009035130A2 (en) | 2007-09-11 | 2009-03-19 | Daikin Industries, Ltd. | Process for producing 2,3,3,3-tetrafluoropropene |
US9079818B2 (en) * | 2007-10-15 | 2015-07-14 | Honeywell International Inc. | Process for synthesis of fluorinated olefins |
-
2009
- 2009-11-03 US US12/611,288 patent/US8618340B2/en active Active
-
2010
- 2010-10-21 JP JP2012537902A patent/JP5732062B2/ja active Active
- 2010-10-21 CN CN201080049776.2A patent/CN102656132B/zh active Active
- 2010-10-21 WO PCT/US2010/053486 patent/WO2011056441A2/en active Application Filing
- 2010-10-21 ES ES10828789.7T patent/ES2509640T3/es active Active
- 2010-10-21 MX MX2012005136A patent/MX2012005136A/es active IP Right Grant
- 2010-10-21 EP EP10828789.7A patent/EP2496541B1/en not_active Not-in-force
Also Published As
Publication number | Publication date |
---|---|
CN102656132A (zh) | 2012-09-05 |
JP2013510148A (ja) | 2013-03-21 |
EP2496541A2 (en) | 2012-09-12 |
CN102656132B (zh) | 2014-11-26 |
US20110105807A1 (en) | 2011-05-05 |
WO2011056441A3 (en) | 2011-09-15 |
EP2496541A4 (en) | 2013-03-13 |
ES2509640T3 (es) | 2014-10-17 |
WO2011056441A2 (en) | 2011-05-12 |
EP2496541B1 (en) | 2014-08-06 |
US8618340B2 (en) | 2013-12-31 |
JP5732062B2 (ja) | 2015-06-10 |
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