MX2008001244A - Pelicula de poliestireno biaxialmente orientada conteniendo pequenas particulas de goma y bajo contenido de gel de particula de goma. - Google Patents

Pelicula de poliestireno biaxialmente orientada conteniendo pequenas particulas de goma y bajo contenido de gel de particula de goma.

Info

Publication number
MX2008001244A
MX2008001244A MX2008001244A MX2008001244A MX2008001244A MX 2008001244 A MX2008001244 A MX 2008001244A MX 2008001244 A MX2008001244 A MX 2008001244A MX 2008001244 A MX2008001244 A MX 2008001244A MX 2008001244 A MX2008001244 A MX 2008001244A
Authority
MX
Mexico
Prior art keywords
weight
percent
polymer composition
film
rubber particles
Prior art date
Application number
MX2008001244A
Other languages
English (en)
Inventor
Robert L Mcgee
Ludovic Harelle
Susan E Dollinger
Stephen J Skapik Iii
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of MX2008001244A publication Critical patent/MX2008001244A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/08Copolymers of styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2353/00Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2353/02Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24893Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254Polymeric or resinous material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Wrappers (AREA)

Abstract

Una pelicula biaxialmente orientada tiene una proporcion de orientacion de direccion de maquina (MDO) de mas de 1.2 y una proporcion de orientacion de direccion transversal (TDO) de 2.0 o menos, donde la proporcion de MDO es mayor que la proporcion de TDO, donde la pelicula contiene una composicion de polimero conteniendo un primer componente de poliestireno de alto impacto (HIPS) con un copolimero de bloque injertado a poliestireno, un contenido de dieno conjugado gomoso de uno a siete por ciento en peso con base en el peso del primer HIPS, menos de 10 por ciento en peso de concentracion de gel, un tamano de particula de goma promedio de entre uno y 0.01 micrometros, aproximadamente 40 hasta aproximadamente 90 por ciento en volumen de las particulas de goma tienen diametros de menos de aproximadamente 0.4 micras y desde aproximadamente 10 hasta aproximadamente 60 por ciento en volumen de las particulas de goma tienen diametros entre aproximadamente 0.4 y aproximadamente 2.5 micras, una mayoria de particulas de goma con una morfologia de nucleo/coraza y una concentracion que responde por 30 hasta 100 por ciento en peso del peso de composicion de polimero total y uno a cinco por ciento en peso de dieno gomoso basado en el peso de composicion de polimero total. La pelicula tambien puede contener hasta 70 por ciento en peso de un poliestireno de proposito general y hasta 20 por ciento en peso de un segundo componente de HIPS que es diferente del primer componente de HIPS, ambos basados en el peso de composicion de polimero total. La composicion de polimero responde por al menos 95 por ciento en peso de la pelicula con el balance del peso de pelicula siendo aditivos.
MX2008001244A 2005-07-28 2006-07-27 Pelicula de poliestireno biaxialmente orientada conteniendo pequenas particulas de goma y bajo contenido de gel de particula de goma. MX2008001244A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US70338505P 2005-07-28 2005-07-28
PCT/US2006/029492 WO2007016376A1 (en) 2005-07-28 2006-07-27 Biaxially oriented polystyrene film containing small rubber particles and low rubber particle gel content

Publications (1)

Publication Number Publication Date
MX2008001244A true MX2008001244A (es) 2008-03-24

Family

ID=37458912

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2008001244A MX2008001244A (es) 2005-07-28 2006-07-27 Pelicula de poliestireno biaxialmente orientada conteniendo pequenas particulas de goma y bajo contenido de gel de particula de goma.

Country Status (14)

Country Link
US (1) US20090130383A1 (es)
EP (1) EP1913079A1 (es)
JP (1) JP2009503200A (es)
KR (1) KR20080030626A (es)
CN (1) CN101233188A (es)
AR (1) AR057700A1 (es)
AU (1) AU2006275629A1 (es)
BR (1) BRPI0615537A2 (es)
CA (1) CA2616617A1 (es)
IL (1) IL188978A0 (es)
MX (1) MX2008001244A (es)
NO (1) NO20080292L (es)
TW (1) TW200710156A (es)
WO (1) WO2007016376A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010502770A (ja) 2006-07-27 2010-01-28 ダウ グローバル テクノロジーズ インコーポレイティド 小ゴム粒子及び低ゴム粒子ゲル含量を有し且つブロックコポリマーを含む配向ポリスチレンフィルムのシュリンクラベル
WO2009045737A1 (en) * 2007-10-02 2009-04-09 Dow Global Technologies Inc. Multilayer coextruded shrink labels of oriented polystyrene film containing small rubber particles and low rubber particle gel content and block copolymers
US20100130667A1 (en) * 2008-11-25 2010-05-27 Nichols Kevin L Rubber filled oriented polymer composition article

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3123655A (en) * 1964-03-03 Process for extruding high impact thermoplastic
US4409369A (en) * 1980-03-03 1983-10-11 The Dow Chemical Company Transparent impact resin and process for the preparation thereof
DE3035570A1 (de) * 1980-09-20 1982-05-06 Basf Ag, 6700 Ludwigshafen Schlagfeste thermoplastische formmasse
US4572819A (en) * 1983-08-24 1986-02-25 The Dow Chemical Company Apparatus for anionic polymerization wherein the molecular weight of the polymer is closely controlled
US4585825A (en) * 1983-09-30 1986-04-29 The Dow Chemical Company Monovinylidene aromatic polymer resins having added amounts of high molecular weight polymer
US4608284A (en) * 1985-01-22 1986-08-26 Cellu-Craft Inc. Heat shrinkable label and related container
US4666987A (en) * 1985-02-22 1987-05-19 The Dow Chemical Company In-mold polymerization of vinyl aromatic compound
JPH03227327A (ja) * 1990-02-01 1991-10-08 Idemitsu Petrochem Co Ltd 二軸延伸スチレン系樹脂フイルム
JP3329838B2 (ja) * 1991-07-11 2002-09-30 電気化学工業株式会社 スチレン系樹脂二軸延伸シート
US5322664A (en) * 1993-02-02 1994-06-21 Owens-Illinois Labels Inc. Clear film extrusion from an annular die
US5428106A (en) * 1993-09-02 1995-06-27 The Dow Chemical Company Rubber modified polystyrene
US5643664A (en) * 1994-08-23 1997-07-01 Packaging Corporation Of America Biaxially oriented polystyrene film
US6011117A (en) * 1997-02-11 2000-01-04 Basf Corporation High gloss, high impact polystyrene composition
ES2189250T3 (es) * 1997-10-31 2003-07-01 Dow Global Technologies Inc Mezclas de polimeros nonoviniliden-aromaticos modificados con caucho.
US6248807B1 (en) * 1999-03-15 2001-06-19 Fina Technology, Inc. Method for the preparation of core-shell morphologies from polybutadiene-polystyrene graft copolymers
US6649259B1 (en) * 2000-02-29 2003-11-18 National Starch And Chemical Investment Holding Corporation Adhesives for thermally shrinkable films or labels
EP1174444B1 (en) * 2000-07-19 2008-05-21 Kuraray Co., Ltd., Kurashiki Plant Dispersion stablizer for suspension polymerization of vinyl compound
AU2001291155A1 (en) * 2000-10-11 2002-04-22 Dow Global Technologies Inc. Rubber modified monovinylidene aromatic polymer blends with improved transparency
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US6841261B2 (en) * 2000-11-10 2005-01-11 Denki Kagaku Kogyo Kabushiki Kaisha Block copolymer, composition thereof, and film made thereof
US7211623B2 (en) * 2001-04-13 2007-05-01 Er Ming Yan Synthetic plastic material and a method of making thereof
CN1537125A (zh) * 2001-08-02 2004-10-13 基于高线性高分子量聚丁二烯烃橡胶的单亚乙烯基芳族聚合物及其制法
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Also Published As

Publication number Publication date
US20090130383A1 (en) 2009-05-21
BRPI0615537A2 (pt) 2011-05-17
EP1913079A1 (en) 2008-04-23
KR20080030626A (ko) 2008-04-04
AR057700A1 (es) 2007-12-12
IL188978A0 (en) 2008-08-07
NO20080292L (no) 2008-02-20
CN101233188A (zh) 2008-07-30
AU2006275629A1 (en) 2007-02-08
JP2009503200A (ja) 2009-01-29
CA2616617A1 (en) 2007-02-08
WO2007016376A1 (en) 2007-02-08
TW200710156A (en) 2007-03-16

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