MX2007003681A - Agentes quelantes para la eliminacion de metales pesados. - Google Patents

Agentes quelantes para la eliminacion de metales pesados.

Info

Publication number
MX2007003681A
MX2007003681A MX2007003681A MX2007003681A MX2007003681A MX 2007003681 A MX2007003681 A MX 2007003681A MX 2007003681 A MX2007003681 A MX 2007003681A MX 2007003681 A MX2007003681 A MX 2007003681A MX 2007003681 A MX2007003681 A MX 2007003681A
Authority
MX
Mexico
Prior art keywords
troika
metal removal
acid
macroporous
resin
Prior art date
Application number
MX2007003681A
Other languages
English (en)
Inventor
Charles E Mckenna
Boris A Kashemirov
Isabelle Favier
Thomas D Wolfe
Original Assignee
Univ Southern California
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Southern California filed Critical Univ Southern California
Publication of MX2007003681A publication Critical patent/MX2007003681A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/40—Introducing phosphorus atoms or phosphorus-containing groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S210/00—Liquid purification or separation
    • Y10S210/902—Materials removed
    • Y10S210/911—Cumulative poison
    • Y10S210/912—Heavy metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Water Treatment By Sorption (AREA)
  • Removal Of Specific Substances (AREA)
  • Processing Of Solid Wastes (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La presente invencion proporciona acidos Troika unidos a una resina macroporosa y metodos para la preparacion de los mismos, que incluye la union directa de un acido Troika, y la union de un precursor de acido Troika seguido por la generacion del acido Troika in si tu. Tambien se describen los metodos de funcionalizacion de una resina para facilitar la union. Se describen los acidos Troika multiples, que comprenden un par de acidos Troika unidos juntos. Se han disenan y validado las rutas de sintesis para ambas resinas microporosas y macroporosas modificadas por la introduccion de un acido tipo Troika adecuado. En una modalidad preferida, una resina Troika macroporosa elimina Cu2+ y Ni2+ de una solucion acuosa con alta afinidad, y es selectivo contra Mg2+ o Ca2+. Los materiales de la presente invencion tienen ventajas para la remocion o eliminacion de metales a partir de agua de desecho de plantas de energia.
MX2007003681A 2004-09-30 2005-09-23 Agentes quelantes para la eliminacion de metales pesados. MX2007003681A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/957,553 US7527733B2 (en) 2004-09-30 2004-09-30 Chelating agents for heavy metal removal
PCT/US2005/034420 WO2006039235A2 (en) 2004-09-30 2005-09-23 Chelating agents for heavy metal removal

Publications (1)

Publication Number Publication Date
MX2007003681A true MX2007003681A (es) 2007-05-21

Family

ID=36097816

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2007003681A MX2007003681A (es) 2004-09-30 2005-09-23 Agentes quelantes para la eliminacion de metales pesados.

Country Status (12)

Country Link
US (1) US7527733B2 (es)
EP (1) EP1794092A4 (es)
JP (1) JP2008514419A (es)
KR (1) KR20070085280A (es)
CN (1) CN101065330A (es)
AU (1) AU2005292337A1 (es)
BR (1) BRPI0516862A (es)
CA (1) CA2581913A1 (es)
MX (1) MX2007003681A (es)
RU (1) RU2007116105A (es)
WO (1) WO2006039235A2 (es)
ZA (1) ZA200702660B (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7678281B2 (en) * 2003-07-18 2010-03-16 Bj Services Company Method of reclaiming brine solutions using an organic chelant
US7674384B2 (en) * 2003-07-18 2010-03-09 Bj Services Company Method of reclaiming brine solutions using an organic chelant
US8874145B2 (en) * 2006-08-02 2014-10-28 Telecommunication Systems, Inc. Personal location code broker
BRPI0811377A2 (pt) * 2007-05-31 2014-12-09 Dow Italia S R L "processo para a remoção e recuperação de pelo menos um metal pesado"
US7947130B2 (en) * 2009-10-24 2011-05-24 Wai Mun Lee Troika acid semiconductor cleaning compositions and methods of use
EP2542248A4 (en) 2010-03-02 2013-04-17 Univ Kansas POLYAMINE-DIHYDROXYBENZOIC ACID CONJUGATE HYDROGELES AS IRON-CHELATOR
US8702975B2 (en) * 2010-09-16 2014-04-22 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
US8663460B2 (en) 2010-09-16 2014-03-04 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
US8728304B2 (en) 2010-09-16 2014-05-20 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
US8673133B2 (en) 2010-09-16 2014-03-18 Chevron U.S.A. Inc. Process, method, and system for removing heavy metals from fluids
US8975340B2 (en) 2010-12-15 2015-03-10 Electric Power Research Institute, Inc. Synthesis of sequestration resins for water treatment in light water reactors
US9214248B2 (en) 2010-12-15 2015-12-15 Electric Power Research Institute, Inc. Capture and removal of radioactive species from an aqueous solution
US9589690B2 (en) 2010-12-15 2017-03-07 Electric Power Research Institute, Inc. Light water reactor primary coolant activity cleanup
CN103157445A (zh) * 2013-02-25 2013-06-19 武汉纺织大学 一种聚合物负载的金属盐配位萃取剂及其制备与应用
CN108531563A (zh) * 2018-02-05 2018-09-14 深圳市尚维高科有限公司 多孔微球的用途及裂解液以及裂解液的使用方法
CN109502873B (zh) * 2018-11-16 2021-11-16 西北矿冶研究院 一种处理废水中重金属离子的装置及方法
CN110693076A (zh) * 2019-08-07 2020-01-17 常德华馥生物技术有限公司 降低烟草浸膏中Pb和As含量的方法
CN110372081A (zh) * 2019-08-16 2019-10-25 重庆工程职业技术学院 工业废水重金属处理池

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1004398A1 (ru) * 1981-09-18 1983-03-15 Московский ордена Ленина и ордена Трудового Красного Знамени химико-технологический институт им.Д.И.Менделеева 0,0-Дибутилоксиминоцианметилфосфонат в качестве экстрагента переходных металлов и способ его получени
US4952321A (en) * 1988-10-07 1990-08-28 Brigham Young University Process of removing and concentrating desired ions from solutions
US5182251A (en) * 1991-10-10 1993-01-26 Brigham Young University Aminoalkylphosphonic acid containing ligands attached to solid supports for removal of metal ions
JP3518112B2 (ja) * 1995-12-06 2004-04-12 東京瓦斯株式会社 燃料電池の水処理装置
US5948931A (en) * 1996-07-12 1999-09-07 University Of Southern California Preparation and use of α-(hydroxyimino) phosphonoacetic acids
US5804606A (en) * 1997-04-21 1998-09-08 Rohm & Haas Company Chelating resins
US6232265B1 (en) * 1999-06-11 2001-05-15 Ibc Advanced Technologies, Inc. Particulate solid supports functionalized with polyhydroxypyridinone ligands
AU780950B2 (en) 1999-09-27 2005-04-28 Ibc Advanced Technologies, Inc. Polyamide-containing ligands covalently bonded to supports, polyamide-containing resins, and methods for removing metals from solutions
GB0025502D0 (en) * 2000-10-18 2000-11-29 Johnson Matthey Plc Metal scavenging
JP2004000874A (ja) * 2002-04-05 2004-01-08 Toyobo Co Ltd 溶液中の金属イオン濾過装置

Also Published As

Publication number Publication date
CA2581913A1 (en) 2006-04-13
RU2007116105A (ru) 2008-11-10
WO2006039235A3 (en) 2006-08-31
US7527733B2 (en) 2009-05-05
EP1794092A2 (en) 2007-06-13
CN101065330A (zh) 2007-10-31
JP2008514419A (ja) 2008-05-08
WO2006039235A2 (en) 2006-04-13
KR20070085280A (ko) 2007-08-27
AU2005292337A1 (en) 2006-04-13
BRPI0516862A (pt) 2008-09-23
EP1794092A4 (en) 2011-08-10
ZA200702660B (en) 2008-08-27
US20060065604A1 (en) 2006-03-30

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