MX2007003663A - Fenoles sulfonados con nitrofenoles como inhibidores de polimerizacion. - Google Patents

Fenoles sulfonados con nitrofenoles como inhibidores de polimerizacion.

Info

Publication number
MX2007003663A
MX2007003663A MX2007003663A MX2007003663A MX2007003663A MX 2007003663 A MX2007003663 A MX 2007003663A MX 2007003663 A MX2007003663 A MX 2007003663A MX 2007003663 A MX2007003663 A MX 2007003663A MX 2007003663 A MX2007003663 A MX 2007003663A
Authority
MX
Mexico
Prior art keywords
sub
nitrophenols
group
inhibitor
polymerization inhibitors
Prior art date
Application number
MX2007003663A
Other languages
English (en)
Inventor
Brigitte Benage
Vilen Kosover
Jesus R Fabian
Istvan Lippai
Gerald J Abruscato
Original Assignee
Chemtura Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemtura Corp filed Critical Chemtura Corp
Publication of MX2007003663A publication Critical patent/MX2007003663A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/41—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton
    • C07C309/42—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton having the sulfo groups bound to carbon atoms of non-condensed six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • C08K5/375—Thiols containing six-membered aromatic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)

Abstract

Se describe en la presente un metodo para inhibir la polimerizacion prematura y el crecimiento de polimero de monomeros etilenicamente no saturados comprendiendo agregar a dichos monomeros una cantidad efectiva de una combinacion de (A) al menos un inhibidor que es un fenol sulfonado de la formula (1): en donde (1) R2 se selecciona del grupo que consiste de hidrogeno e hidrocarbilo; y (2) R1 y -R3 se seleccionan independientemente del grupo que consiste de hidrogeno y S03H, siempre que al menos uno de Rl y R3 sea S03H; (B) al menos un inhibidor que es un nitrofenol; y, opcionalmente, (C) un inhibidor seleccionado del grupo que consiste de compuestos nitroxil y nitrosoanilinas; y (D) una amina.
MX2007003663A 2004-09-28 2005-07-20 Fenoles sulfonados con nitrofenoles como inhibidores de polimerizacion. MX2007003663A (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US61437804P 2004-09-28 2004-09-28
US63124104P 2004-11-29 2004-11-29
US11/172,517 US20060069219A1 (en) 2004-09-28 2005-06-29 Sulfonated phenols with nitrophenols as polymerization inhibitors
PCT/US2005/026016 WO2006036274A1 (en) 2004-09-28 2005-07-20 Sulfonated phenols with nitrophenols as polymerization inhibitors

Publications (1)

Publication Number Publication Date
MX2007003663A true MX2007003663A (es) 2007-06-13

Family

ID=35385340

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2007003663A MX2007003663A (es) 2004-09-28 2005-07-20 Fenoles sulfonados con nitrofenoles como inhibidores de polimerizacion.

Country Status (16)

Country Link
US (1) US20060069219A1 (es)
EP (1) EP1794106B1 (es)
JP (1) JP5175550B2 (es)
KR (1) KR101181599B1 (es)
CN (1) CN102766009A (es)
AR (1) AR050962A1 (es)
AT (1) ATE463473T1 (es)
BR (1) BRPI0515540A (es)
CA (1) CA2581526C (es)
DE (1) DE602005020473D1 (es)
ES (1) ES2343071T3 (es)
MX (1) MX2007003663A (es)
MY (1) MY146410A (es)
PL (1) PL1794106T3 (es)
TW (1) TWI374131B (es)
WO (1) WO2006036274A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0606801A2 (pt) 2005-02-04 2015-06-16 Chemtura Corp Método para inibir polimerização prematura de monômeros estirênicos, composição
US9206268B2 (en) * 2011-09-16 2015-12-08 General Electric Company Methods and compositions for inhibiting polystyrene formation during styrene production
ES2547893T3 (es) * 2011-12-26 2015-10-09 Dorf Ketal Chemicals (India) Private Limited Composición de aditivo mejorada a base de amina para el control y la inhibición de la polimerización de monómeros aromáticos de vinilo, y procedimiento para su uso

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US3163677A (en) * 1961-08-07 1964-12-29 American Cyanamid Co Process for preparing n, n, o-trisubstituted hydroxyl amines and n, n-disubstituted nitroxides and products
GB983134A (en) * 1962-06-13 1965-02-10 American Cyanamid Co Cyclic nitroxides and process for preparing same
US3502692A (en) * 1962-06-13 1970-03-24 American Cyanamid Co Cyclic nitroxides and process for preparing same
US3422144A (en) * 1965-04-27 1969-01-14 American Cyanamid Co Stable free radical nitroxides
US3372182A (en) * 1965-04-27 1968-03-05 American Cyanamid Co Process for preparation of stable, free radical nitroxides
FR1501769A (fr) * 1966-07-04 1967-11-18 Commissariat Energie Atomique Radicaux libres du type nitroxyde
US3873564A (en) * 1971-03-03 1975-03-25 Synvar Ass 2-Imidazolinyl-3-oxide-1-oxypropionic acid
GB1354420A (en) * 1971-05-17 1974-06-05 Volgogradsky Politekh Inst Isoprene treatment
US4086147A (en) * 1976-12-10 1978-04-25 Cosden Technology, Inc. Polymerization inhibitor for vinyl aromatic compounds
US4468343A (en) * 1983-04-11 1984-08-28 Cosden Technology, Inc. Polymerization co-inhibitors for vinyl aromatic compounds
US4665185A (en) * 1984-03-22 1987-05-12 Ciba-Geigy Corporation Process for preparing nitroxyls of sterically hindered amines
US4664845A (en) * 1986-01-09 1987-05-12 Uniroyal Chemical Company, Inc. Phenylenediamine solubilizer for dinitrophenol in aromatic solvent
US4670131A (en) * 1986-01-13 1987-06-02 Exxon Chemical Patents Inc. Method for controlling fouling of hydrocarbon compositions containing olefinic compounds
US5290888A (en) * 1990-07-20 1994-03-01 Ciba-Geigy Corporation Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions
US5212272A (en) * 1990-10-31 1993-05-18 Peach State Labs, Inc. Polyacrylic acid compositions for textile processing
US5157175A (en) * 1991-09-09 1992-10-20 Nalco Chemical Company Composition and method for inhibition of styrene polymerization
JP2914075B2 (ja) * 1992-04-30 1999-06-28 大日本インキ化学工業株式会社 （メタ）アクリル酸エステルの製造法
US5254760A (en) * 1992-07-29 1993-10-19 Ciba-Geigy Corporation Inhibiting polymerization of vinyl aromatic monomers
JPH06234700A (ja) * 1993-02-12 1994-08-23 Dainippon Ink & Chem Inc （メタ）アクリル酸エステル類の製造方法
US5446220A (en) * 1994-08-24 1995-08-29 Betz Laboratories, Inc. Methods for inhibiting vinyl aromatic monomer polymerization
US5545786C1 (en) * 1994-11-28 2001-10-16 Ciba Geigy Corp Method for inhibiting premature polymerization of vinyl aromatic monomers
JPH08217726A (ja) * 1995-02-15 1996-08-27 Dainippon Ink & Chem Inc ペンタエリスリトール（メタ）アクリルエステルの製造方法
JP3401018B2 (ja) * 1996-06-05 2003-04-28 ビーエーエスエフ アクチェンゲゼルシャフト モノマー及び安定剤を含有する混合物
US5932735A (en) * 1997-06-13 1999-08-03 Ciba Specialty Chemicals Corporation Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers
US6200461B1 (en) * 1998-11-05 2001-03-13 Betzdearborn Inc. Method for inhibiting polymerization of ethylenically unsaturated hydrocarbons
US6403850B1 (en) * 2000-01-18 2002-06-11 Uniroyal Chemical Company, Inc. Inhibition of polymerization of unsaturated monomers
EP1332196A1 (en) * 2000-10-16 2003-08-06 Uniroyal Chemical Company, Inc. Blends of quinone alkide and nitroxyl compounds as polymerization inhibitors
JP3788950B2 (ja) * 2001-04-25 2006-06-21 伯東株式会社 芳香族ビニル化合物の重合抑制方法
US7125475B2 (en) * 2002-02-15 2006-10-24 Crompton Corporation Nitrosophenols and C-nitrosoanilines as polymerization inhibitors
US7691952B2 (en) * 2004-09-28 2010-04-06 Chemtura Corporation Sulfonated nitrophenols as polymerization inhibitors

Also Published As

Publication number Publication date
TW200616938A (en) 2006-06-01
CA2581526A1 (en) 2006-04-06
MY146410A (en) 2012-08-15
KR101181599B1 (ko) 2012-09-13
ES2343071T3 (es) 2010-07-22
JP2008514598A (ja) 2008-05-08
EP1794106A1 (en) 2007-06-13
BRPI0515540A (pt) 2008-07-29
CA2581526C (en) 2013-02-12
KR20070058528A (ko) 2007-06-08
AR050962A1 (es) 2006-12-06
WO2006036274A1 (en) 2006-04-06
ATE463473T1 (de) 2010-04-15
PL1794106T3 (pl) 2010-09-30
CN102766009A (zh) 2012-11-07
TWI374131B (en) 2012-10-11
JP5175550B2 (ja) 2013-04-03
US20060069219A1 (en) 2006-03-30
EP1794106B1 (en) 2010-04-07
DE602005020473D1 (de) 2010-05-20

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