MX165875B - Procedimiento para la preparacion de 1,1,1-triflurodicloroetano y/o 1,1,1,2-tetrafluorocloroetano - Google Patents

Procedimiento para la preparacion de 1,1,1-triflurodicloroetano y/o 1,1,1,2-tetrafluorocloroetano

Info

Publication number
MX165875B
MX165875B MX013518A MX1351888A MX165875B MX 165875 B MX165875 B MX 165875B MX 013518 A MX013518 A MX 013518A MX 1351888 A MX1351888 A MX 1351888A MX 165875 B MX165875 B MX 165875B
Authority
MX
Mexico
Prior art keywords
trifluorodichloroethane
tetrafluorochloroethane
preparation
triflurodicloroethane
tetrafluorocloroethane
Prior art date
Application number
MX013518A
Other languages
English (en)
Inventor
William Henry Gumprecht
Leo Ernest Manzer
Velliyur Nott Mallikarjuna Rao
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of MX165875B publication Critical patent/MX165875B/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C19/00—Acyclic saturated compounds containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
    • C07C17/087—Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/21—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms with simultaneous increase of the number of halogen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un procedimiento para la preparación de 1,1,1,-trifluorodicloroetano y/o 1,1,1,2-tetrafluorocloroetano mediante la fluoración de un tetrahaloetileno, C2C14-xFx, en donde x es igual a 0 a 3, y/o un pentahaloetano, C2HC15-xFx, en donde x es igual a 0 a 2, el procedimiento está caracterizado porque comprende poner en contacto en la fase gaseosa a una temperatura, proporción en mol y tiempo de contacto efectivos, el tetrahaloetileno y/o pentahaloetano con HF y Cr203, en donde el Cr203 está preparado por pirólisis de (NH4)2Cr203, dicho contacto produce una corriente del producto que contiene 1,1,1-trifluorodicloroetano y/o 1,1,1,2-tetrafluorocloroetano y pentafluoroetano, en donde la cantidad de 1, 1, 1-trifluorodicloroetano y/o 1,1,1,2-tetrafluorocloroetano es mayor que la cantidad de pentafluroetano producida y posteriormente, separar el 1,1,1,-trifluorodicloroetano y/o 1,1,1,2-tetrafluorocloroetano de la corriente de productos.
MX013518A 1987-10-22 1988-10-12 Procedimiento para la preparacion de 1,1,1-triflurodicloroetano y/o 1,1,1,2-tetrafluorocloroetano MX165875B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/111,292 US4843181A (en) 1987-10-22 1987-10-22 Process for the manufacture of 1,1,1-trifluorodichloroethane and 1,1,1,2-tetrafluorochloroethane

Publications (1)

Publication Number Publication Date
MX165875B true MX165875B (es) 1992-12-08

Family

ID=22337652

Family Applications (1)

Application Number Title Priority Date Filing Date
MX013518A MX165875B (es) 1987-10-22 1988-10-12 Procedimiento para la preparacion de 1,1,1-triflurodicloroetano y/o 1,1,1,2-tetrafluorocloroetano

Country Status (14)

Country Link
US (1) US4843181A (es)
EP (1) EP0313061B1 (es)
JP (1) JPH01146832A (es)
KR (1) KR890006550A (es)
CN (1) CN1014988B (es)
AU (1) AU609529B2 (es)
BR (1) BR8805440A (es)
CA (1) CA1310022C (es)
DE (1) DE3887625T2 (es)
ES (1) ES2063750T3 (es)
IN (1) IN171034B (es)
MX (1) MX165875B (es)
RU (1) RU2007380C1 (es)
ZA (1) ZA887889B (es)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1202652B (it) * 1987-03-09 1989-02-09 Ausimont Spa Processo per la preparazione di 1,1,1-trifluoro-2,2-dicloroetano mediante idrofluorurazione in presenza di catalizzatori
US5276224A (en) * 1987-03-09 1994-01-04 Ausimont S.P.A. Process for preparing 1,1,1-trifluoro-2,2-dichloroethane by hydrofluorination in the presence of catalysts
US5262574A (en) * 1987-03-09 1993-11-16 Ausimont S.P.A. Process for preparing 1,1,1-trifluoro-2,2-dichloroethane by hydrofluorination in the presence of catalysts
CA1310335C (en) * 1988-02-12 1992-11-17 Leo E. Manzer Gas-phase fluorination process
IN172054B (es) * 1988-02-24 1993-03-27 Du Pont
IN171977B (es) * 1988-06-29 1993-02-27 Du Pont
US5036036A (en) * 1989-06-13 1991-07-30 E. I. Du Pont De Nemours And Company Chromium oxide catalyst composition
IT1230779B (it) * 1989-07-12 1991-10-29 Ausimont Srl Procedimento per preparare 1,1,1,2 tetrafluoroetano.
FR2661906B1 (fr) * 1990-05-11 1993-10-01 Atochem Procede de fabrication du 1,1,1,2-tetrafluoro-chloroethane et du pentafluoroethane.
US5045634A (en) * 1990-06-28 1991-09-03 E. I. Du Pont De Nemours And Company Fluorination of haloolefins
US5030372A (en) * 1990-07-31 1991-07-09 E. I. Du Pont De Nemours And Company Catalytic equilibration to improve the relative yield of selected halocarbons
US5177273A (en) * 1991-02-01 1993-01-05 E. I. Du Pont De Nemours And Company Process for the manufacture of halogen-substituted propanes containing hydrogen and at least five fluorine substituents
AU2265592A (en) * 1991-05-06 1992-12-21 E.I. Du Pont De Nemours And Company Process for the manufacture of pentafluoroethane
ZA923274B (en) * 1991-05-06 1993-11-08 Du Pont Process for the manufacture of pentafluoroethane
US5182042A (en) * 1991-10-21 1993-01-26 Allied-Signal Inc. Azeotrope-like compositions of 1,1,1-trifluorohexane and perfluoromethylcyclohexane
US5569797A (en) * 1992-01-07 1996-10-29 E. I. Du Pont De Nemours And Company Method of removing olefinic impurities from hydrochlorofluorocarbons
US5395999A (en) * 1992-11-06 1995-03-07 E. I. Du Pont De Nemours And Company Catalytic chlorofluorination process for producing CHClFCF3 and CHF2 CF3
WO1994020441A1 (en) * 1993-03-05 1994-09-15 Daikin Industries, Ltd. Process for producing 1,1,1,2,2-pentafluoroethane, process for producing 2,2-dichloro-1,1,1-trifluoroethane, and method of purifying 1,1,1,2,2-pentafluoroethane
IT1270959B (it) * 1993-08-13 1997-05-26 Ausimont Spa Processo per la preparazione di pentafluoroetano
WO1995011875A1 (en) * 1993-10-28 1995-05-04 Alliedsignal Inc. Process for purifying 1,1-dichloro-2,2,2-trifluoroethane and 1-chloro-1,2,2,2-tetrafluoroethane
EP0754171B1 (en) * 1994-04-08 2001-03-14 Imperial Chemical Industries Plc Process for the purification of pentafluoroethane
US5545778A (en) * 1994-05-25 1996-08-13 Alliedsignal Inc. Single stage process for producing hydrofluorocarbons from perchloroethylene
US5569794A (en) * 1994-05-24 1996-10-29 Alliedsignal Inc. Vapor phase process for producing hydroflourocarbons from perchloroethylene having a phenolic inhibitor
US5563304A (en) 1994-05-26 1996-10-08 E. I. Du Pont De Nemours And Company Production of 1,2-dihydro and 2,2-dihydro hexafluoropropanes and azeotropes thereof with HF
US5414165A (en) * 1994-07-29 1995-05-09 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1,3,3,3,-hexafluoropropane
ZA959435B (en) * 1994-11-14 1996-05-31 Great Lakes Chemical Corp Process for production of 1,1,1,3,3,3-hexafluoropropane
KR0125143B1 (ko) * 1994-12-02 1997-11-27 김은영 1,1,1-트리플루오로-2,2-디클로로에탄의 불소화 촉매 및 그것의 제조방법
US5475167A (en) * 1995-02-17 1995-12-12 E. I. Du Pont De Nemours And Company Process for the manufacture of pentafluoroethane
US6034289A (en) * 1995-06-08 2000-03-07 E. I. Du Pont De Nemours And Company Treatment of chromium oxide and catalytic manufacture of vinyl fluoride
EP0840719B1 (en) * 1995-07-14 2002-09-18 E.I. Du Pont De Nemours And Company Distillation processes for recovering HFC-125 and HFC-32
FR2740994B1 (fr) 1995-11-10 1997-12-05 Atochem Elf Sa Catalyseurs massiques a base d'oxyde de chrome, leur procede de preparation et leur application a la fluoration d'hydrocarbures halogenes
US6417413B1 (en) 1999-11-03 2002-07-09 Alliedsignal Inc. Process for the preparation of halogenated ethanes
US6472574B2 (en) 1999-12-10 2002-10-29 E. I. Du Pont Nemours And Company Production of 1,2-dihydro and 2,2-dihydro hexafluoropropanes and azeotropes thereof with HF
FR2807751B1 (fr) * 2000-04-12 2005-05-20 Solvay Procede pour la preparation d'un hydro (chloro) fluoroalcane et catalyseur
US7217678B2 (en) * 2002-08-22 2007-05-15 E. I. Du Pont De Nemours And Company Cobalt-substituted chromium oxide compositions, their preparation, and their use as catalysts and catalyst precursors
RU2328482C2 (ru) * 2002-08-22 2008-07-10 Е.И.Дюпон Де Немур Энд Компани Способ получения 1,1,1,2,2-пентафторэтана
JP5096661B2 (ja) * 2002-08-22 2012-12-12 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー ニッケル置換ならびに混合ニッケルおよびコバルト置換酸化クロム組成物、それらの製造、ならびに触媒および触媒前駆物質としてのそれらの使用
AU2003265595A1 (en) * 2002-08-22 2004-03-11 E.I. Du Pont De Nemours And Company Processes for the preparation of 2-chloro-1,1,1,2,3,3,3-heptafluoropropane, hexafluoropropene and 1,1,1,2,3,3,3-heptafluoropropane
GB0525701D0 (en) * 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
GB0525699D0 (en) 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
GB0525702D0 (en) * 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
GB0525700D0 (en) * 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2458551A (en) * 1947-02-18 1949-01-11 Du Pont Preparation of carbon tetrafluoride
US2576823A (en) * 1947-11-13 1951-11-27 Du Pont Fluorination with granular crf3 catalyst
US3258500A (en) * 1959-08-17 1966-06-28 Du Pont Process for fluorinating halohydro-carbons
US3183276A (en) * 1960-03-16 1965-05-11 Edison Soc Process for the production of fluorinated organic compounds
GB1000485A (en) * 1962-02-07 1965-08-04 Sicedison Spa Improvements in or relating to the fluorination of halo-olefines
DE1910529C3 (de) * 1969-03-01 1978-09-28 Dynamit Nobel Ag, 5210 Troisdorf Verfahren zur katalytischen Hydrofluorierung von bestimmten gesattigten und ungesättigten halogenierten Kohlenwasserstoffen
GB1307224A (en) * 1969-06-27 1973-02-14 Ici Ltd Chromium oxide catalyst
JPS4872105A (es) * 1971-12-29 1973-09-29
FR2501062A1 (fr) * 1980-12-29 1982-09-10 Ugine Kuhlmann Catalyseurs de fluoruration en phase gazeuse de derives chlores aliphatiques, a base de microbilles d'oxyde de chrome, et procedes de fluoruration utilisant ces catalyseurs
IT1202652B (it) * 1987-03-09 1989-02-09 Ausimont Spa Processo per la preparazione di 1,1,1-trifluoro-2,2-dicloroetano mediante idrofluorurazione in presenza di catalizzatori
US4766260A (en) * 1987-07-07 1988-08-23 E. I. Du Pont De Nemours And Company Gas-phase fluorination process
AU3861089A (en) * 1988-06-23 1990-01-12 E.I. Du Pont De Nemours And Company Catalyzed hydrofluorination of alkenes
IN171977B (es) * 1988-06-29 1993-02-27 Du Pont

Also Published As

Publication number Publication date
ES2063750T3 (es) 1995-01-16
CN1014988B (zh) 1991-12-04
IN171034B (es) 1992-07-04
JPH01146832A (ja) 1989-06-08
US4843181A (en) 1989-06-27
AU2411588A (en) 1989-04-27
AU609529B2 (en) 1991-05-02
KR890006550A (ko) 1989-06-14
EP0313061A3 (en) 1989-06-07
EP0313061A2 (en) 1989-04-26
DE3887625D1 (de) 1994-03-17
EP0313061B1 (en) 1994-02-02
RU2007380C1 (ru) 1994-02-15
CN1033989A (zh) 1989-07-19
ZA887889B (en) 1990-06-27
CA1310022C (en) 1992-11-10
DE3887625T2 (de) 1994-07-14
BR8805440A (pt) 1989-06-27

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