MD940197A - Oligomeri cu solidificare termică cu capacitate de penetrare şi compoziţia lichidă cu solidificare termică obţinută în baza lor pentru acoperirea suprafeţei sticlei - Google Patents

Oligomeri cu solidificare termică cu capacitate de penetrare şi compoziţia lichidă cu solidificare termică obţinută în baza lor pentru acoperirea suprafeţei sticlei

Info

Publication number
MD940197A
MD940197A MD94-0197A MD940197A MD940197A MD 940197 A MD940197 A MD 940197A MD 940197 A MD940197 A MD 940197A MD 940197 A MD940197 A MD 940197A
Authority
MD
Moldova
Prior art keywords
component
penetrating power
heatsealable
glass surface
surface coating
Prior art date
Application number
MD94-0197A
Other languages
English (en)
Russian (ru)
Inventor
Hintze-Bruning Horst
Schunk Stephan
Original Assignee
Basf Lacke+Farben Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Lacke+Farben Ag filed Critical Basf Lacke+Farben Ag
Publication of MD940197A publication Critical patent/MD940197A/ro

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • C03C17/322Polyurethanes or polyisocyanates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10Coating
    • C03C25/104Coating to obtain optical fibres
    • C03C25/106Single coatings
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10Coating
    • C03C25/104Coating to obtain optical fibres
    • C03C25/1065Multiple coatings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4804Two or more polyethers of different physical or chemical nature
    • C08G18/4812Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4887Polyethers containing carboxylic ester groups derived from carboxylic acids other than acids of higher fatty oils or other than resin acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67Unsaturated compounds having active hydrogen
    • C08G18/671Unsaturated compounds having only one group containing active hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67Unsaturated compounds having active hydrogen
    • C08G18/671Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C08G18/6725Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen containing ester groups other than acrylate or alkylacrylate ester groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81Unsaturated isocyanates or isothiocyanates
    • C08G18/8141Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • C08G18/8175Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
  • Surface Treatment Of Glass (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Medicinal Preparation (AREA)
  • Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
  • Glass Compositions (AREA)
  • Laminated Bodies (AREA)

Abstract

Obiectul invenţiei prezente sunt oligomerii cu solidificare termică cu capacitate de penetrare, care se obţin din:a) un compus hidroxi- şi/sau aminofuncţional cu funcţionalitatea de la 3 până la 4 şi cu masă moleculară medie de la 500 până la 4000;b) un compus cu două grupări hidroxile şi/sau aminice şi cu masa moleculară medie de la 200 până la 4000;c) un compus monoetilen nesaturat cu o grupă cu un atom de hidrogen activ la o moleculă şi cu masa moleculară medie de la 116 până la 1000;d) diizocianat alifatic şi/sau cicloalifatic.Compoziţia diferă prin faptul, că componentele “a” se conţin în aşa cantităţi, că:1. Raportul molar al componentelor “a” faţă de componentul “b” constituie de la 0,1 până la 1,1.2. Raportul molar al componentelor “c” faţă de componentul “a” e de la 2,0 până la 10:1.3. Raportul echivalent al grupărilor de izocianat ale componentului “d” faţă de grupările hidroxile şi/sau aminice ale sumei componentelor de la “a” până la “c” constituie de la 0,9 până la 1,0. Obiectul invenţiei prezente sunt, de asemenea, compoziţiile cu solidificare termică cu capacitate de penetrare pentru aplicarea învelişului, care conţin oligomeri cu solidificare termică cu capacitate de penetrare cu adaos de fotoiniţiator şi substanţe auxiliare, precum şi metoda de acoperire a suprafeţei sticlei, în particular a fibrelor de sticlă optică, în care se folosesc aceste compoziţii.
MD94-0197A 1990-09-01 1994-07-14 Oligomeri cu solidificare termică cu capacitate de penetrare şi compoziţia lichidă cu solidificare termică obţinută în baza lor pentru acoperirea suprafeţei sticlei MD940197A (ro)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4027770A DE4027770A1 (de) 1990-09-01 1990-09-01 Fluessige, strahlenhaertbare ueberzugsmasse fuer die beschichtung von glasoberflaechen

Publications (1)

Publication Number Publication Date
MD940197A true MD940197A (ro) 1996-01-31

Family

ID=6413412

Family Applications (1)

Application Number Title Priority Date Filing Date
MD94-0197A MD940197A (ro) 1990-09-01 1994-07-14 Oligomeri cu solidificare termică cu capacitate de penetrare şi compoziţia lichidă cu solidificare termică obţinută în baza lor pentru acoperirea suprafeţei sticlei

Country Status (18)

Country Link
EP (1) EP0545969B1 (ro)
JP (1) JP2509409B2 (ro)
KR (1) KR930702411A (ro)
AT (1) ATE115598T1 (ro)
AU (1) AU648099B2 (ro)
BG (1) BG60917B1 (ro)
BR (1) BR9106811A (ro)
CA (1) CA2090450C (ro)
DE (2) DE4027770A1 (ro)
DK (1) DK0545969T3 (ro)
ES (1) ES2068603T3 (ro)
FI (1) FI930851A0 (ro)
LT (1) LT3332B (ro)
LV (1) LV10463B (ro)
MD (1) MD940197A (ro)
NO (1) NO930689L (ro)
WO (1) WO1992004391A1 (ro)
YU (1) YU47699B (ro)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4302327A1 (de) * 1993-01-28 1994-08-04 Basf Lacke & Farben Strahlenhärtbare Oligomere sowie flüssige, strahlenhärtbare Überzugsmasse für die Beschichtung von Glasoberflächen
DE19715382C1 (de) * 1997-04-14 1998-11-19 Synthopol Chemie Dr Koch Wasserdispergierte, strahlenhärtbare Polyurethane
WO2003091346A1 (en) 2002-04-24 2003-11-06 Dsm Ip Assets B.V. Radiation curable coating composition for optical fiber with reduced attenuation loss
EP1497237B1 (en) * 2002-04-24 2007-11-14 Prysmian Cavi e Sistemi Energia S.r.l. Optical fiber with reduced attenuation loss
EP1497686B1 (en) 2002-04-24 2015-03-04 Prysmian S.p.A. Method for controlling microbending induced attenuation losses in an optical fiber
US20210208333A1 (en) 2018-06-01 2021-07-08 Dsm Ip Assets B.V. Radiation curable compositions for coating optical fiber via alternative oligomers and the coatings produced therefrom
WO2021021971A1 (en) * 2019-07-31 2021-02-04 Dsm Ip Assets B.V. Radiation curable compositions with multi-functional long-armed oligomers for coating optical fibers

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4121089A (en) 1977-07-29 1978-10-17 International Business Machines Corporation Apparatus for the reversal of a hot roll in a fusing assembly
US4131602A (en) * 1977-09-29 1978-12-26 Union Carbide Corporation Radiation curable acrylated polyurethane
JPS5940102B2 (ja) 1978-11-17 1984-09-28 日本クラウンコルク株式会社 剥離可能な接着構造物
US4607084A (en) * 1984-06-11 1986-08-19 Celanese Specialty Resins, Inc. Radiation curable acrylated polyurethane oligomer compositions
NL8401981A (nl) 1984-06-22 1986-01-16 Philips Nv Optische glasvezel voorzien van een kunststofbedekking en werkwijze voor de vervaardiging daarvan.
DE3613082A1 (de) * 1985-05-07 1986-11-13 Hüls AG, 45772 Marl Haftklebstoffe auf der basis von strahlenhaertbaren, (meth-)acrylgruppenhaltigen polyestern
US4609718A (en) 1985-05-08 1986-09-02 Desoto, Inc. Ultraviolet curable buffer coatings for optical glass fiber based on long chain oxyalkylene diamines
US4608409A (en) 1985-05-08 1986-08-26 Desoto, Inc. Polyacrylated oligomers in ultraviolet curable optical fiber coatings
US4690502A (en) 1985-07-08 1987-09-01 Desoto, Inc. Ultraviolet curable optical glass fiber coatings from acrylate terminated, end-branched polyurethane polyurea oligomers
US4806574A (en) * 1985-07-22 1989-02-21 Desoto, Inc. Ultraviolet curable coatings for optical glass fiber based on a polyfunctional core
CA1292752C (en) * 1985-10-29 1991-12-03 John M. Zimmerman Ultraviolet curable coatings for optical glass fiber
US4782129A (en) * 1988-01-04 1988-11-01 Desoto, Inc. Acrylated polyurethanes based on polyoxytetramethylene glycol chain extended with substituted diacids

Also Published As

Publication number Publication date
DE59103926D1 (de) 1995-01-26
YU146191A (sh) 1994-06-10
BG97481A (bg) 1994-03-24
NO930689D0 (no) 1993-02-26
ES2068603T3 (es) 1995-04-16
EP0545969B1 (de) 1994-12-14
FI930851L (fi) 1993-02-25
FI930851A7 (fi) 1993-02-25
DE4027770A1 (de) 1992-03-05
NO930689L (no) 1993-02-26
KR930702411A (ko) 1993-09-09
LV10463B (en) 1996-04-20
EP0545969A1 (de) 1993-06-16
LTIP531A (en) 1994-11-25
LV10463A (lv) 1995-02-20
BR9106811A (pt) 1993-08-24
CA2090450A1 (en) 1992-03-02
ATE115598T1 (de) 1994-12-15
LT3332B (en) 1995-07-25
CA2090450C (en) 1996-07-02
AU8331491A (en) 1992-03-30
BG60917B1 (bg) 1996-06-28
JP2509409B2 (ja) 1996-06-19
AU648099B2 (en) 1994-04-14
DK0545969T3 (da) 1995-04-18
WO1992004391A1 (de) 1992-03-19
FI930851A0 (fi) 1993-02-25
JPH06502435A (ja) 1994-03-17
YU47699B (sh) 1996-01-08

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