MD4420C1 - Aplicarea componentelor grele întunecate ale petrolului în calitate de catalizator la purificarea oxidativă de hidrogen sulfurat şi mercaptani uşori a compoziţiilor de hidrocarburi şi procedeu de purificare a compoziţiilor de hidrocarburi - Google Patents

Aplicarea componentelor grele întunecate ale petrolului în calitate de catalizator la purificarea oxidativă de hidrogen sulfurat şi mercaptani uşori a compoziţiilor de hidrocarburi şi procedeu de purificare a compoziţiilor de hidrocarburi

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Publication number
MD4420C1
MD4420C1 MDA20120057A MD20120057A MD4420C1 MD 4420 C1 MD4420 C1 MD 4420C1 MD A20120057 A MDA20120057 A MD A20120057A MD 20120057 A MD20120057 A MD 20120057A MD 4420 C1 MD4420 C1 MD 4420C1
Authority
MD
Moldova
Prior art keywords
hydrocarbonic
compositions
purification
catalyst
hydrogen sulphide
Prior art date
Application number
MDA20120057A
Other languages
English (en)
Russian (ru)
Other versions
MD4420B1 (ro
MD20120057A3 (ro
MD20120057A2 (ro
Inventor
Анатолие БИШИР
Иван ЛЕСНИК
Сергей ЧЕРНЫШЕВ
Confidential
Original Assignee
Оп "Matricon" Ооо
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Оп "Matricon" Ооо filed Critical Оп "Matricon" Ооо
Priority to MDA20120057A priority Critical patent/MD4420C1/ro
Priority to PCT/IB2013/001318 priority patent/WO2014001872A1/en
Priority to US14/410,971 priority patent/US20150224489A1/en
Publication of MD20120057A2 publication Critical patent/MD20120057A2/ro
Publication of MD20120057A3 publication Critical patent/MD20120057A3/ro
Publication of MD4420B1 publication Critical patent/MD4420B1/ro
Publication of MD4420C1 publication Critical patent/MD4420C1/ro

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
    • B01J23/8472—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Invenţia se referă la purificarea oxidativă de hidrogen sulfurat şi mercaptani uşori a compoziţiilor de hidrocarburi în prezenţa catalizatorului şi poate fi utilizată în industria de petrol şi gaze, de procesare a petrolului, petrochimică şi în alte domenii ale industriei.Se propune aplicarea componentelor grele întunecate ale petrolului în calitate de catalizator la purificarea oxidativă de hidrogen sulfurat şi mercaptani uşori a compoziţiilor de hidrocarburi. Componentele aplicate reprezintă reziduul, având un conţinut de cupru şi/sau vanadiu de cel puţin 0,005% mas., obţinut în urma distilării din petrol a fracţiilor cu o temperatură de fierbere de până la 350°C.Procedeul de purificare de hidrogen sulfurat şi mercaptani uşori a compoziţiilor de hidrocarburi prevede oxidarea compuşilor de sulf cu oxigenul din aer sau cu gaz cu conţinut de oxigen la temperaturi de la 55°C până la 135°C în prezenţa catalizatorului menţionat.
MDA20120057A 2012-06-26 2012-06-26 Aplicarea componentelor grele întunecate ale petrolului în calitate de catalizator la purificarea oxidativă de hidrogen sulfurat şi mercaptani uşori a compoziţiilor de hidrocarburi şi procedeu de purificare a compoziţiilor de hidrocarburi MD4420C1 (ro)

Priority Applications (3)

Application Number Priority Date Filing Date Title
MDA20120057A MD4420C1 (ro) 2012-06-26 2012-06-26 Aplicarea componentelor grele întunecate ale petrolului în calitate de catalizator la purificarea oxidativă de hidrogen sulfurat şi mercaptani uşori a compoziţiilor de hidrocarburi şi procedeu de purificare a compoziţiilor de hidrocarburi
PCT/IB2013/001318 WO2014001872A1 (en) 2012-06-26 2013-06-21 Purification of hydrocarbon composition
US14/410,971 US20150224489A1 (en) 2012-06-26 2013-06-21 Use of heavy dark oil components as catalyst in oxidative purification of hydrocarbon compositions from hydrogen sulphide and light mercaptans, catalyst based of heavy dark oil components from hydrogen sulphide and light mercaptans

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MDA20120057A MD4420C1 (ro) 2012-06-26 2012-06-26 Aplicarea componentelor grele întunecate ale petrolului în calitate de catalizator la purificarea oxidativă de hidrogen sulfurat şi mercaptani uşori a compoziţiilor de hidrocarburi şi procedeu de purificare a compoziţiilor de hidrocarburi

Publications (4)

Publication Number Publication Date
MD20120057A2 MD20120057A2 (ro) 2013-12-31
MD20120057A3 MD20120057A3 (ro) 2015-10-31
MD4420B1 MD4420B1 (ro) 2016-05-31
MD4420C1 true MD4420C1 (ro) 2017-02-28

Family

ID=49782345

Family Applications (1)

Application Number Title Priority Date Filing Date
MDA20120057A MD4420C1 (ro) 2012-06-26 2012-06-26 Aplicarea componentelor grele întunecate ale petrolului în calitate de catalizator la purificarea oxidativă de hidrogen sulfurat şi mercaptani uşori a compoziţiilor de hidrocarburi şi procedeu de purificare a compoziţiilor de hidrocarburi

Country Status (3)

Country Link
US (1) US20150224489A1 (ro)
MD (1) MD4420C1 (ro)
WO (1) WO2014001872A1 (ro)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MD4400C1 (ro) * 2014-12-16 2016-09-30 Государственный Университет Молд0 Procedeu de purificare a aerului de hidrogen sulfurat

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US4908122A (en) * 1989-05-08 1990-03-13 Uop Process for sweetening a sour hydrocarbon fraction
RU2087521C1 (ru) * 1994-08-08 1997-08-20 Всероссийский научно-исследовательский институт углеводородного сырья Способ очистки нефти и газоконденсата от низкомолекулярных меркаптанов
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RU2398735C1 (ru) * 2009-05-29 2010-09-10 Ирина Геннадиевна Тарханова Способ очистки газовых потоков от сероводорода
RU2404225C2 (ru) * 2009-02-03 2010-11-20 Государственное учебно-научное учреждение Химический факультет МГУ имени М.В. Ломоносова Способ очистки углеводородных композиций от меркаптанов
RU2408658C1 (ru) * 2009-05-25 2011-01-10 Ввса Инвестментс Групп Инк Способ окислительной демеркаптанизации нефти и нефтяных дистиллятов

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RU2404225C2 (ru) * 2009-02-03 2010-11-20 Государственное учебно-научное учреждение Химический факультет МГУ имени М.В. Ломоносова Способ очистки углеводородных композиций от меркаптанов
RU2408658C1 (ru) * 2009-05-25 2011-01-10 Ввса Инвестментс Групп Инк Способ окислительной демеркаптанизации нефти и нефтяных дистиллятов
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Also Published As

Publication number Publication date
US20150224489A1 (en) 2015-08-13
MD4420B1 (ro) 2016-05-31
MD20120057A3 (ro) 2015-10-31
WO2014001872A1 (en) 2014-01-03
MD20120057A2 (ro) 2013-12-31

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