LU86284A1 - Procede d'obtention d'ethylene a partir d'ethanol - Google Patents
Procede d'obtention d'ethylene a partir d'ethanol Download PDFInfo
- Publication number
- LU86284A1 LU86284A1 LU86284A LU86284A LU86284A1 LU 86284 A1 LU86284 A1 LU 86284A1 LU 86284 A LU86284 A LU 86284A LU 86284 A LU86284 A LU 86284A LU 86284 A1 LU86284 A1 LU 86284A1
- Authority
- LU
- Luxembourg
- Prior art keywords
- catalyst
- zeolite
- ethanol
- ethylene
- weight
- Prior art date
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 132
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000005977 Ethylene Substances 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 24
- 239000003054 catalyst Substances 0.000 claims abstract description 110
- 239000010457 zeolite Substances 0.000 claims abstract description 91
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 87
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 75
- 238000006243 chemical reaction Methods 0.000 claims description 38
- 239000000203 mixture Substances 0.000 claims description 18
- 229910001657 ferrierite group Inorganic materials 0.000 claims description 16
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 13
- 229910052675 erionite Inorganic materials 0.000 claims description 12
- 238000011282 treatment Methods 0.000 claims description 12
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 claims description 11
- 229910052676 chabazite Inorganic materials 0.000 claims description 11
- 239000011148 porous material Substances 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 238000005342 ion exchange Methods 0.000 claims description 9
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 7
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 claims description 6
- 229910001603 clinoptilolite Inorganic materials 0.000 claims description 6
- 238000000855 fermentation Methods 0.000 claims description 6
- 230000004151 fermentation Effects 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 3
- 239000002028 Biomass Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- 229910052677 heulandite Inorganic materials 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 claims description 2
- 229910052678 stilbite Inorganic materials 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims 1
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract description 5
- 238000002360 preparation method Methods 0.000 description 23
- 229910001868 water Inorganic materials 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000000243 solution Substances 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- 238000002441 X-ray diffraction Methods 0.000 description 11
- 229930195733 hydrocarbon Natural products 0.000 description 11
- 150000002430 hydrocarbons Chemical class 0.000 description 11
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 10
- 230000009466 transformation Effects 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 8
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- OHBTULDTCSOWOY-UHFFFAOYSA-N [C].C=C Chemical compound [C].C=C OHBTULDTCSOWOY-UHFFFAOYSA-N 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 238000001354 calcination Methods 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 150000001768 cations Chemical class 0.000 description 6
- 229910052681 coesite Inorganic materials 0.000 description 6
- 229910052906 cristobalite Inorganic materials 0.000 description 6
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 229910052682 stishovite Inorganic materials 0.000 description 6
- 229910052905 tridymite Inorganic materials 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 235000019270 ammonium chloride Nutrition 0.000 description 5
- 238000006297 dehydration reaction Methods 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 4
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 4
- -1 hydrogen ions Chemical class 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 239000012265 solid product Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 230000009849 deactivation Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052680 mordenite Inorganic materials 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000003965 capillary gas chromatography Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052914 metal silicate Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the eroionite or offretite type, e.g. zeolite T
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU86284A LU86284A1 (fr) | 1986-01-30 | 1986-01-30 | Procede d'obtention d'ethylene a partir d'ethanol |
| AT87870013T ATE52074T1 (de) | 1986-01-30 | 1987-01-29 | Verfahren zur gewinnung von aethylen aus aethanol. |
| ES87870013T ES2014331B3 (es) | 1986-01-30 | 1987-01-29 | Procedimiento de obtencion de etileno a partir de etanol. |
| EP87870013A EP0231163B1 (de) | 1986-01-30 | 1987-01-29 | Verfahren zur Gewinnung von Äthylen aus Äthanol |
| DE8787870013T DE3762334D1 (de) | 1986-01-30 | 1987-01-29 | Verfahren zur gewinnung von aethylen aus aethanol. |
| US07/008,728 US4727214A (en) | 1986-01-30 | 1987-01-30 | Process for obtaining ethylene from ethanol |
| BR8700422A BR8700422A (pt) | 1986-01-30 | 1987-01-30 | Processo para obtencao de etileno a partir de etanol anidro ou aquoso |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU86284 | 1986-01-30 | ||
| LU86284A LU86284A1 (fr) | 1986-01-30 | 1986-01-30 | Procede d'obtention d'ethylene a partir d'ethanol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| LU86284A1 true LU86284A1 (fr) | 1987-09-03 |
Family
ID=19730631
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LU86284A LU86284A1 (fr) | 1986-01-30 | 1986-01-30 | Procede d'obtention d'ethylene a partir d'ethanol |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4727214A (de) |
| EP (1) | EP0231163B1 (de) |
| AT (1) | ATE52074T1 (de) |
| BR (1) | BR8700422A (de) |
| DE (1) | DE3762334D1 (de) |
| ES (1) | ES2014331B3 (de) |
| LU (1) | LU86284A1 (de) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3840506A1 (de) * | 1988-12-01 | 1990-06-07 | Linde Ag | Verfahren und vorrichtung zur luftzerlegung |
| US20040225164A1 (en) * | 2003-05-09 | 2004-11-11 | Conocophillips Company | Method for treating ethane |
| US20060149109A1 (en) * | 2004-12-30 | 2006-07-06 | Ruziska Philip A | Converting methanol and ethanol to light olefins |
| EP1792886A1 (de) * | 2005-11-29 | 2007-06-06 | BP Chemicals Limited | Verfahren zur Herstellung von Propylen |
| EP1792885A1 (de) * | 2005-11-29 | 2007-06-06 | BP Chemicals Limited | Verfahren zur Herstellung von Ethylen |
| EP1790627A1 (de) * | 2005-11-29 | 2007-05-30 | BP Chemicals Limited | Verfahren zur Herstellung von Olefinen |
| CN101104571B (zh) * | 2006-07-13 | 2010-05-12 | 中国石油化工股份有限公司 | 一种联合烃类催化转化从乙醇生产乙烯的方法 |
| CN101104576B (zh) * | 2006-07-13 | 2010-08-25 | 中国石油化工股份有限公司 | 一种有机含氧化合物和烃类的联合催化转化方法 |
| EP2090561A1 (de) | 2008-02-07 | 2009-08-19 | Total Petrochemicals Research Feluy | Dehydrierung von Alkoholen auf kristallinen Silicaten |
| EP2108636A1 (de) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Alkoholdehydrierung in Gegenwart einer inerten Komponente |
| EP2108634A1 (de) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Dehydrierung von Alkoholen auf Kristallsilicaten |
| EP2108635A1 (de) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Verfahren zur Herstellung von Olefinen aus Ethanol |
| EP2108637A1 (de) | 2008-04-11 | 2009-10-14 | Total Petrochemicals Research Feluy | Verfahren zur Herstellung von Olefinen aus Ethanol |
| EP2192101A1 (de) | 2008-11-28 | 2010-06-02 | Total Petrochemicals Research Feluy | Reinigung von Alkohol vor der Verwendung bei Vorhandensein eines Säurekatalysators |
| AU2009319002B2 (en) | 2008-11-28 | 2012-11-29 | Total Petrochemicals Research Feluy | Purification of alcohols prior to their use in the presence of an acid catalyst |
| CN101747136B (zh) * | 2008-12-04 | 2013-09-25 | 焦作市河阳酒精实业有限公司 | 乙醇经催化脱水生产乙烯的工艺 |
| EP2348006A1 (de) | 2010-01-26 | 2011-07-27 | Total Petrochemicals Research Feluy | Entwässerung von Alkoholen auf einem kristallinen Silikat mit niedrigem Si/Al-Verhältnis |
| EP2526078B1 (de) | 2010-01-22 | 2018-10-17 | Total Research & Technology Feluy | Dehydrierung von alkoholen auf einem kristallinen silikat mit niedrigem si/al-verhältnis |
| EP2348005A1 (de) | 2010-01-22 | 2011-07-27 | Total Petrochemicals Research Feluy | Dehydrierung von Alkoholen auf kristallinem Silikat einer FER-Struktur |
| FR2959749B1 (fr) * | 2010-05-06 | 2012-06-01 | Inst Francais Du Petrole | Procede flexible de transformation de l'ethanol en distillats moyens. |
| WO2012080421A1 (en) | 2010-12-17 | 2012-06-21 | Total Petrochemicals Research Feluy | Process for producing propylene from syngas via fermentative propanol production and dehydration |
| US9169444B2 (en) | 2011-04-21 | 2015-10-27 | Shell Oil Company | Liquid fuel composition |
| CN103597056A (zh) | 2011-04-21 | 2014-02-19 | 国际壳牌研究有限公司 | 转化固体生物质材料的方法 |
| US8927794B2 (en) | 2011-04-21 | 2015-01-06 | Shell Oil Company | Process for regenerating a coked catalytic cracking catalyst |
| AU2012245156A1 (en) | 2011-04-21 | 2013-10-31 | Shell Internationale Research Maatschappij B.V. | Process for converting a solid biomass material |
| CN103827058B (zh) * | 2011-06-15 | 2016-08-17 | Ut-巴特勒有限责任公司 | 醇转化为碳氢化合物的沸石催化 |
| CN103889932A (zh) * | 2011-09-07 | 2014-06-25 | 国际壳牌研究有限公司 | 由包含叔烷基醚的给料制备乙烯和丙烯的方法 |
| WO2013034678A1 (en) | 2011-09-07 | 2013-03-14 | Shell Internationale Research Maatschappij B.V. | Process for preparing ethylene and propylene |
| EP2594547A1 (de) | 2011-11-17 | 2013-05-22 | Solvay Sa | Verfahren zur Herstellung von mindestens einer Ethylen-Derivat-Verbindung aus Bioethanol |
| US8697802B2 (en) | 2011-11-28 | 2014-04-15 | Celanese International Corporation | Process for producing polyvinyl alcohol or a copolymer thereof |
| WO2013160253A1 (en) | 2012-04-23 | 2013-10-31 | Shell Internationale Research Maatschappij B.V. | Process for converting a solid biomass material |
| US9434658B2 (en) | 2013-03-06 | 2016-09-06 | Ut-Battelle, Llc | Catalytic conversion of alcohols to hydrocarbons with low benzene content |
| BR112015032871B1 (pt) | 2013-07-02 | 2021-07-06 | Ut-Battelle, Llc | métodos para produzir um componente de mistura de hidrocarbonetos |
| US10696606B2 (en) | 2016-06-09 | 2020-06-30 | Ut-Battelle, Llc | Zeolitic catalytic conversion of alcohols to hydrocarbon fractions with reduced gaseous hydrocarbon content |
| US11053181B2 (en) | 2018-08-09 | 2021-07-06 | Ut-Battelle, Llc | Zeolitic catalytic conversion of alcohols to olefins |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3240697A (en) * | 1964-12-17 | 1966-03-15 | Socony Mobil Oil Co Inc | Catalytic conversion with activated catalyst |
| US4049573A (en) * | 1976-02-05 | 1977-09-20 | Mobil Oil Corporation | Zeolite catalyst containing oxide of boron or magnesium |
| US4062905A (en) * | 1976-08-02 | 1977-12-13 | Mobil Oil Corporation | Manufacture of light olefins |
| US4148835A (en) * | 1978-04-14 | 1979-04-10 | Mobil Oil Corporation | Hydrocarbon manufacture from alcohols |
| CA1196031A (en) * | 1982-02-05 | 1985-10-29 | Wooyoung Lee | Process for converting alcohols into olefins |
| US4481177A (en) * | 1982-12-09 | 1984-11-06 | Mobil Oil Corporation | Synthesis of zeolite ZSM-22 with a heterocyclic organic compound |
| US4638106A (en) * | 1984-07-13 | 1987-01-20 | Exxon Research & Engineering Co. | Two stage process for improving the catalyst life of zeolites in the synthesis of lower olefins from alcohols and their ether derivatives |
| LU85515A1 (fr) * | 1984-08-28 | 1986-03-11 | Belge Etat | Catalyseurs pour la transformation d'ethanol en ethylene et leur utilisation |
| US4547616A (en) * | 1984-12-28 | 1985-10-15 | Mobil Oil Corporation | Conversion of oxygenates to lower olefins in a turbulent fluidized catalyst bed |
-
1986
- 1986-01-30 LU LU86284A patent/LU86284A1/fr unknown
-
1987
- 1987-01-29 DE DE8787870013T patent/DE3762334D1/de not_active Expired - Fee Related
- 1987-01-29 EP EP87870013A patent/EP0231163B1/de not_active Expired - Lifetime
- 1987-01-29 AT AT87870013T patent/ATE52074T1/de active
- 1987-01-29 ES ES87870013T patent/ES2014331B3/es not_active Expired - Lifetime
- 1987-01-30 BR BR8700422A patent/BR8700422A/pt unknown
- 1987-01-30 US US07/008,728 patent/US4727214A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BR8700422A (pt) | 1987-12-15 |
| EP0231163A1 (de) | 1987-08-05 |
| ES2014331B3 (es) | 1990-07-01 |
| US4727214A (en) | 1988-02-23 |
| DE3762334D1 (de) | 1990-05-23 |
| ATE52074T1 (de) | 1990-05-15 |
| EP0231163B1 (de) | 1990-04-18 |
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