JPH03503741A - 飽和炭化水素鎖の酸化 - Google Patents
飽和炭化水素鎖の酸化Info
- Publication number
- JPH03503741A JPH03503741A JP2500222A JP50022290A JPH03503741A JP H03503741 A JPH03503741 A JP H03503741A JP 2500222 A JP2500222 A JP 2500222A JP 50022290 A JP50022290 A JP 50022290A JP H03503741 A JPH03503741 A JP H03503741A
- Authority
- JP
- Japan
- Prior art keywords
- saturated hydrocarbon
- carbon atoms
- catalyst
- saturated
- use according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
- C07C27/10—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
- C07C27/16—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with other oxidising agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/40—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with ozone; by ozonolysis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Saccharide Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 (1)約950cm−1の赤外吸収バンドを有するチタン含有シリカライト(s ilicalite)触媒の、飽和炭化水素鎖の醇化への用途。 (2)触媒が下記の一般式の触媒である請求の範囲第1項記載の用途。 xTiO2(1−x)SiO2 (式中xは0.0001〜0.04である。)(3)飽和炭化水素鎖が2〜18 個の炭素原子を含むアルカンである請求の範囲第1項又は第2項記載の用途。 (4)飽和炭化水素鎖が環構造に結合した少なくとも2個の炭素原子を含むアル キル基である請求の範囲第1項〜第3項のいずれか1項記載の用途。 (5)アルキル基が少なくとも3個の炭素原子を含む請求の範囲第4項記載の用 途。 (6)環構造が芳香族である請求の範囲第4項又は第5項記載の用途。 (7)約950cm−1の赤外吸収バンドを有するチタン含有シリカライト触媒 の存在下、飽和有機基を含む化合物を酸化剤と処理することによって、飽和炭化 水素鎖を酸化する方法。 (8)触媒が下記の一般式の触媒である請求の範囲第7項記載の方法。 xTiO2(1−x)SiO2 (式中xは0.0001〜0.04である。)(9)醇化剤が過酸化水素又は有 機過酸化物である請求の範囲第7項又は第8項記載の方法。 (10)飽和有機基を含む化合物が反応に用いられる条件において液体又は高密 度相である請求の範囲第7項〜第9項記載の方法。 (11)飽和炭化水素鎖が2〜18個の炭素原子を含むアルカンである請求の範 囲第7項〜第10項のいずれか1項記載の方法。 (12)飽和炭化水素鎖が環構造に結合した少なくとも2個の炭素原子を含むア ルキル基である請求の範囲第7項〜第10項のいずれか1項記載の方法。 (13)アルキル基が少なくとも3個の炭素原子を含む請求の範囲第12項記載 の方法。 (14)溶媒の存在下、反応を行う請求の範囲第7項〜第13項のいずれか1項 に記載の方法。 (15)酸化剤が過酸化水素水である請求の範囲第7項〜第14項のいずれか1 項記載の方法。 (16)溶媒が極性溶媒である請求の範囲第7項〜第15項のいずれか1項記載 の方法。 (17)50〜150℃の温度で行う請求の範囲第7〜第16項のいずれか1項 記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE08801275 | 1988-11-08 | ||
BE8801275 | 1988-11-08 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH03503741A true JPH03503741A (ja) | 1991-08-22 |
JP3049086B2 JP3049086B2 (ja) | 2000-06-05 |
Family
ID=3883713
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2500222A Expired - Lifetime JP3049086B2 (ja) | 1988-11-08 | 1989-11-08 | 飽和炭化水素鎖の酸化 |
Country Status (12)
Country | Link |
---|---|
US (1) | US5021607A (ja) |
EP (1) | EP0376453B1 (ja) |
JP (1) | JP3049086B2 (ja) |
KR (1) | KR0151712B1 (ja) |
AT (1) | ATE96140T1 (ja) |
AU (1) | AU628439B2 (ja) |
CA (1) | CA2002494C (ja) |
DE (1) | DE68910101T2 (ja) |
DK (1) | DK163890A (ja) |
ES (1) | ES2059782T3 (ja) |
NO (1) | NO173821C (ja) |
WO (1) | WO1990005126A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012224538A (ja) * | 2011-04-19 | 2012-11-15 | Chinese Petrochemical Dev Corp | チタン−シリコン分子ふるいの製造方法とその分子ふるいを用いたシクロヘキサノンオキシムの製造方法 |
JP2014523860A (ja) * | 2011-05-05 | 2014-09-18 | 中国石油化工股▲ふん▼有限公司 | シクロヘキサンのエポキシ化方法 |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1231779B (it) * | 1989-08-09 | 1991-12-21 | Eniricerche Spa | Procedimento per l'ossidazione di composti paraffinici. |
IT1243772B (it) * | 1990-08-01 | 1994-06-28 | Eniricerche Spa | Procedimento per l'ossidazione di composti paraffinici con ossigeno |
GB9118959D0 (en) * | 1991-09-04 | 1991-10-23 | Exxon Chemical Patents Inc | Zeolite catalyst and catalysed reactions |
DE4138155A1 (de) | 1991-11-21 | 1993-05-27 | Basf Ag | Verfahren zur herstellung von im wesentlichen alkalifreien titansilikat-kristallen mit zeolithstruktur |
DE69212293T2 (de) * | 1991-11-26 | 1997-02-20 | Eniricerche Spa | Verfahren zur Oxidation von organischen Verbindungen mit nach einem Anthrachinon-Redoxverfahren hergestellten Wasserstoffperoxid |
GB9201872D0 (en) * | 1992-01-29 | 1992-03-18 | Exxon Chemical Patents Inc | Improved oxidation of saturated hydrocarbon chains |
DE19607577A1 (de) * | 1996-02-29 | 1997-09-04 | Basf Ag | Netzkatalysator auf Basis von Titan- oder Vanadiumzeolithen und inerten Netzgeweben zur Beschleunigung von Oxidationsreaktionen |
BE1010716A3 (fr) | 1996-10-25 | 1998-12-01 | Solvay | Procede de regeneration de catalyseurs de type silicalite au titane. |
BE1010717A3 (fr) * | 1996-10-25 | 1998-12-01 | Solvay | Procede de regeneration de catalyseurs. |
US6074447A (en) * | 1997-02-21 | 2000-06-13 | University Of Hawaii | Hydrogen storage |
BE1011577A3 (fr) * | 1997-11-27 | 1999-11-09 | Solvay | Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de catalyseur. |
BE1011578A3 (fr) * | 1997-11-27 | 1999-11-09 | Solvay | Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de ce catalyseur. |
DE19925534A1 (de) | 1999-06-04 | 2000-12-07 | Degussa | Verfahren zur Aufbereitung von Abwässern |
DE19939416A1 (de) | 1999-08-20 | 2001-02-22 | Basf Ag | Verfahren zur Herstellung eines kristallinen, zeolithischen Feststoffs |
GB9925971D0 (en) * | 1999-11-03 | 1999-12-29 | Exxon Chemical Patents Inc | Reduced particulate froming distillate fuels |
US6447558B1 (en) | 1999-12-21 | 2002-09-10 | Exxonmobil Research And Engineering Company | Diesel fuel composition |
US6447557B1 (en) | 1999-12-21 | 2002-09-10 | Exxonmobil Research And Engineering Company | Diesel fuel composition |
US6716258B2 (en) | 1999-12-21 | 2004-04-06 | Exxonmobil Research And Engineering Company | Fuel composition |
US6458176B2 (en) | 1999-12-21 | 2002-10-01 | Exxonmobil Research And Engineering Company | Diesel fuel composition |
CN101646751B (zh) | 2007-02-06 | 2014-06-18 | 马塞罗·阿卡斯塔埃斯特拉达 | 改变石油粘度的方法 |
WO2011161276A1 (es) | 2010-06-25 | 2011-12-29 | University College Cardiff Consultants Limited | Oxidación selectiva de hidrocarburos usando catalizadores heterogéneos |
EP2671861B1 (en) * | 2011-02-02 | 2016-10-12 | University College Cardiff Consultants Limited | Selective oxidation of hydrocarbons using heterogeneous catalysts |
HUE063796T2 (hu) | 2019-06-12 | 2024-01-28 | Nouryon Chemicals Int Bv | Eljárás diacil-peroxidok elõállítására |
HUE063679T2 (hu) | 2019-06-12 | 2024-01-28 | Nouryon Chemicals Int Bv | Eljárás diacil-peroxidok elõállítására |
WO2020249692A1 (en) * | 2019-06-12 | 2020-12-17 | Nouryon Chemicals International B.V. | Method for isolating carboxylic acid from an aqueous side stream |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2808442A (en) * | 1953-06-16 | 1957-10-01 | Shell Dev | Production of hydroxy ethers |
IT1152298B (it) * | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per l'ossidazione di alcooli ad aldeidi e/o chetoni |
IT1152296B (it) * | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per la sintesi di monometileteri dei glicoli |
IT1184316B (it) * | 1985-02-05 | 1987-10-28 | Enichem Sintesi | Procedimento per la monoepossidazione di composti contenenti due doppi legami |
ES2033693T3 (es) * | 1986-01-28 | 1993-04-01 | Eniricerche S.P.A. | Un procedimiento para la exposidacion de compuestos olefinicos. |
DE3801106A1 (de) * | 1988-01-16 | 1989-07-27 | Basf Ag | Verfahren zur herstellung von phenylethanolen |
-
1989
- 1989-08-11 KR KR1019900701455A patent/KR0151712B1/ko not_active IP Right Cessation
- 1989-11-08 ES ES89311569T patent/ES2059782T3/es not_active Expired - Lifetime
- 1989-11-08 AU AU46362/89A patent/AU628439B2/en not_active Expired
- 1989-11-08 AT AT89311569T patent/ATE96140T1/de not_active IP Right Cessation
- 1989-11-08 WO PCT/GB1989/001328 patent/WO1990005126A1/en active Application Filing
- 1989-11-08 JP JP2500222A patent/JP3049086B2/ja not_active Expired - Lifetime
- 1989-11-08 DE DE68910101T patent/DE68910101T2/de not_active Expired - Lifetime
- 1989-11-08 EP EP89311569A patent/EP0376453B1/en not_active Expired - Lifetime
- 1989-11-08 CA CA002002494A patent/CA2002494C/en not_active Expired - Lifetime
- 1989-11-11 US US07/536,679 patent/US5021607A/en not_active Expired - Lifetime
-
1990
- 1990-07-06 DK DK163890A patent/DK163890A/da not_active Application Discontinuation
- 1990-07-06 NO NO903037A patent/NO173821C/no not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012224538A (ja) * | 2011-04-19 | 2012-11-15 | Chinese Petrochemical Dev Corp | チタン−シリコン分子ふるいの製造方法とその分子ふるいを用いたシクロヘキサノンオキシムの製造方法 |
JP2014523860A (ja) * | 2011-05-05 | 2014-09-18 | 中国石油化工股▲ふん▼有限公司 | シクロヘキサンのエポキシ化方法 |
Also Published As
Publication number | Publication date |
---|---|
US5021607A (en) | 1991-06-04 |
DK163890A (da) | 1990-08-23 |
NO173821B (no) | 1993-11-01 |
AU628439B2 (en) | 1992-09-17 |
EP0376453A1 (en) | 1990-07-04 |
NO173821C (no) | 1994-02-09 |
KR900701709A (ko) | 1990-12-04 |
CA2002494C (en) | 2001-07-17 |
JP3049086B2 (ja) | 2000-06-05 |
ES2059782T3 (es) | 1994-11-16 |
ATE96140T1 (de) | 1993-11-15 |
WO1990005126A1 (en) | 1990-05-17 |
EP0376453B1 (en) | 1993-10-20 |
DE68910101D1 (de) | 1993-11-25 |
KR0151712B1 (ko) | 1998-10-15 |
CA2002494A1 (en) | 1990-05-08 |
DE68910101T2 (de) | 1994-06-30 |
NO903037D0 (no) | 1990-07-06 |
NO903037L (no) | 1990-09-04 |
AU4636289A (en) | 1990-05-28 |
DK163890D0 (da) | 1990-07-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPH03503741A (ja) | 飽和炭化水素鎖の酸化 | |
KR100339284B1 (ko) | 결정성티탄함유분자체촉매,그제조방법및그분자를이용한올레핀에폭시화방법 | |
US5262550A (en) | Epoxidation process using titanium-rich silicalite catalysts | |
EP0651674B1 (en) | Catalysts and their use in oxidation of satured hydrocarbons | |
CN101291877B (zh) | 钛硅酸盐沸石ts-1的制备 | |
JP5235406B2 (ja) | オレフィンのエポキシ化方法とナイロン前駆体の同時製造方法 | |
JP3074540B2 (ja) | パラフィン系化合物の酸化法 | |
US5968474A (en) | Pure phase titanium-containing zeolite having MEL structure, process for preparing same, and oxidation processes using same as catalyst | |
JP2995575B2 (ja) | パラフィン系化合物の酸化法 | |
US5869706A (en) | Epoxidation process using a synthetic crystalline material oxides of silicon and titanium | |
WO1996034827A1 (en) | Pure phase titanium, containing zeolite having mel structure | |
IL27188A (en) | Oxidation of ethylbenzene to ethylbenzene hydroperoxide and epoxidation of olefins by reaction with ethylbenzene hydroperoxide | |
US5618512A (en) | Niobium-containing zeolites | |
AU678597B2 (en) | Process for the manufacture of a zeolite | |
WO1993015035A1 (en) | Improved oxidation of saturated hydrocarbon chains | |
RU2036191C1 (ru) | Титансодержащий силикатный катализатор и способ получения смеси спиртов и кетонов | |
JPH09512246A (ja) | ゼオライト及び該ゼオライトを使用したプロセス | |
US5406002A (en) | Zeolite catalyst and catalysed reactions | |
JP4088433B2 (ja) | オレフィン類の酸化方法およびこれを用いる含酸素化合物の製造方法 | |
GB2322364A (en) | Zirconium molecular sieve catalysts |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090324 Year of fee payment: 9 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090324 Year of fee payment: 9 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100324 Year of fee payment: 10 |
|
EXPY | Cancellation because of completion of term | ||
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100324 Year of fee payment: 10 |