KR970070054A - 폴리프로필렌과 오가노폴리실록산의 공중합체 및 이의 제조 방법 - Google Patents

폴리프로필렌과 오가노폴리실록산의 공중합체 및 이의 제조 방법 Download PDF

Info

Publication number
KR970070054A
KR970070054A KR1019970013690A KR19970013690A KR970070054A KR 970070054 A KR970070054 A KR 970070054A KR 1019970013690 A KR1019970013690 A KR 1019970013690A KR 19970013690 A KR19970013690 A KR 19970013690A KR 970070054 A KR970070054 A KR 970070054A
Authority
KR
South Korea
Prior art keywords
organohydrido
polysiloxane
diene
copolymer
polypropylene
Prior art date
Application number
KR1019970013690A
Other languages
English (en)
Other versions
KR100498524B1 (ko
Inventor
다카시 사와구치
마나부 세노
데루히토 마루야마
Original Assignee
마쓰무라 다다시
다우 코닝 아시아, 리미티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP09246396A external-priority patent/JP3579535B2/ja
Priority claimed from JP09246496A external-priority patent/JP3579536B2/ja
Application filed by 마쓰무라 다다시, 다우 코닝 아시아, 리미티드 filed Critical 마쓰무라 다다시
Publication of KR970070054A publication Critical patent/KR970070054A/ko
Application granted granted Critical
Publication of KR100498524B1 publication Critical patent/KR100498524B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/08—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/10—Block- or graft-copolymers containing polysiloxane sequences

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Silicon Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

본 발명은 폴리프로필렌과 오가노폴리실록산의 공중합체를 제조하는 방법에 관한 것이다. 이 방법은 α, ω-디엔-프로필렌 중합체와 분자당 평균 두개 이상의 SiH 그룹을 갖는 오가노하이드리도 폴리실록산의 용액을 용매의 비점 이하의 온도로 가열하는 것을 포함한다. 바람직하게는, 대기압 이하의 압력에서 불활성 대기하에 폴리프로필렌을 열 분해시킴으로써 α, ω-디엔-프로필렌 중합체를 수득한다.

Description

폴리프로필렌과 오가노폴리실록산의 공중합체 및 이의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 비점(b. p.)을 갖는 용매(Ⅲ)중의 α, ω-디엔-프로필렌 중합체(Ⅰ) 및 한 두개의 SiH 그룹을 갖는 오가노하이드리도 폴리실록산(Ⅱ)의 용액을 상기 용매의 비점 이하의 온도에서 가열시킴을 특징으로 하여 폴리프로필렌과 오가노폴리실록산의 공중합체를 제조하는 방법.
  2. 제1항에 있어서, 오가노하이드리도 폴리실록산(Ⅱ)의 하나 이상의 SiH 그룹이 식 -SiH(CH3)(CH3)의 말단 그룹인 방법.
  3. 제1항 또는 제2항에 있어서, 오가노하이드리도 폴리실록산(Ⅱ)의 식 -OSiH(CH3)-의 실록산 단위를 하나 이상 함유하는 방법.
  4. 제1항 또는 제3항 중의 어느 한 항에 있어서, 오가노하이드리도 폴리실록산(Ⅱ)이 Ra가 -OSiH(CH3)-의 실록산 단위를 하나 이상 갖는 폴리오가노실록산 그룹이고 Rb가 탄소수 1 내지 5의 아릴 그룹 및 알킬 그룹 중에서 선택되는 식 -OSiRaRb-의 실록산 단위를 하나 이상 함유하는 방법.
  5. 제1항 내지 제4항 중의 어느 한 항에 있어서, α, ω-디엔-프로필렌 중합체(Ⅰ)가 대기압 이하의 압력에서 불활성 대기 하에 폴리프로필렌을 열 분해시킴으로써 수득되는 방법.
  6. α, ω-디엔-프로필렌 중합체(Ⅰ)와 한 분자당 평균 두개 이상의 SiH 그룹을 갖는 오가노하이드리도 폴리실록산(Ⅱ)간의 규화수소환 반응에 의해 제조되는 폴리프로필렌과 오가노폴리실록산의 공중합체.
  7. 제6항에 있어서, 오가노하이드리도 폴리실록산(Ⅱ)이 화학식(1)인 공중합체.
    상기 식에서, R1및 R2는 메틸 라디칼이고, R3및 R4는 독립적으로 탄소수 1 내지 5의 아릴 라디칼 및 알킬 라디칼 중에서 선택되고, m은 0 이상의 정수이다.
  8. 제7항에 있어서, α, ω-디엔-프로필렌 중합체(Ⅰ)가 대기압 이하의 압력에서 불활성 대기 하에 폴리프로필렌을 열 분해시켜 수득되는 공중합체.
  9. 제7하에 있어서, m이 20 내지 1,000이고, α, ω-디엔-프로필렌 중합체(Ⅰ)의 수평균 분자량이 2,000 내지 3,000인 공중합체
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970013690A 1996-04-15 1997-04-15 폴리프로필렌과오가노폴리실록산의공중합체및이의제조방법 KR100498524B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP09246396A JP3579535B2 (ja) 1996-04-15 1996-04-15 ポリプロピレン−オルガノポリシロキサン共重合体
JP96-092464 1996-04-15
JP96-092463 1996-04-15
JP09246496A JP3579536B2 (ja) 1996-04-15 1996-04-15 ポリプロピレン−オルガノポリシロキサン共重合体の製造方法

Publications (2)

Publication Number Publication Date
KR970070054A true KR970070054A (ko) 1997-11-07
KR100498524B1 KR100498524B1 (ko) 2005-10-21

Family

ID=26433884

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019970013690A KR100498524B1 (ko) 1996-04-15 1997-04-15 폴리프로필렌과오가노폴리실록산의공중합체및이의제조방법

Country Status (6)

Country Link
US (1) US5744541A (ko)
EP (1) EP0802216B1 (ko)
KR (1) KR100498524B1 (ko)
DE (1) DE69701201T2 (ko)
ES (1) ES2144810T3 (ko)
TW (1) TW505679B (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7502058B2 (en) 2003-06-09 2009-03-10 Micron Technology, Inc. Imager with tuned color filter

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998033842A1 (en) * 1997-01-31 1998-08-06 Dsm N.V. Process for the reaction of polyolefins with hydrosilanes
GB9814212D0 (en) 1998-07-01 1998-09-02 Dow Corning Gmbh Polymer composition
CA2340430A1 (en) * 1998-08-14 2000-02-24 University Of Waterloo Melt phase hydrosilylation of polypropylene
US7247385B1 (en) 1998-08-14 2007-07-24 University Of Waterloo Melt phase hydrosilylation of polypropylene
US6805809B2 (en) * 2002-08-28 2004-10-19 Board Of Trustees Of University Of Illinois Decal transfer microfabrication
US6942926B2 (en) * 2003-04-18 2005-09-13 General Electric Company Curable coatings having low permeable to sulfur-bearing gases
DE602005025098D1 (de) * 2004-03-08 2011-01-13 Univ Illinois Mikrofluidische elektrochemische reaktoren
US7662545B2 (en) * 2004-10-14 2010-02-16 The Board Of Trustees Of The University Of Illinois Decal transfer lithography
US8399725B2 (en) 2008-06-20 2013-03-19 Exxonmobil Chemical Patents Inc. Functionalized high vinyl terminated propylene based oligomers
US8802797B2 (en) 2008-06-20 2014-08-12 Exxonmobil Chemical Patents Inc. Vinyl-terminated macromonomer oligomerization
US8283419B2 (en) 2008-06-20 2012-10-09 Exxonmobil Chemical Patents Inc. Olefin functionalization by metathesis reaction
US8283428B2 (en) 2008-06-20 2012-10-09 Exxonmobil Chemical Patents Inc. Polymacromonomer and process for production thereof
US8372930B2 (en) 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
US8399724B2 (en) 2011-03-25 2013-03-19 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin copolymers and methods to produce thereof
US8841397B2 (en) 2011-03-25 2014-09-23 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
US8940839B2 (en) 2011-03-25 2015-01-27 Exxonmobil Chemical Patents Inc. Diblock copolymers prepared by cross metathesis
US8785562B2 (en) 2011-03-25 2014-07-22 Exxonmobil Chemical Patents Inc. Amphiphilic block polymers prepared by alkene metathesis
US8623974B2 (en) 2011-03-25 2014-01-07 Exxonmobil Chemical Patents Inc. Branched vinyl terminated polymers and methods for production thereof
US8501894B2 (en) 2011-03-25 2013-08-06 Exxonmobil Chemical Patents Inc. Hydrosilyation of vinyl macromers with metallocenes
US8669330B2 (en) 2011-03-25 2014-03-11 Exxonmobil Chemical Patents Inc. Olefin triblock polymers via ring-opening metathesis polymerization
US8426659B2 (en) 2011-03-25 2013-04-23 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
US8455597B2 (en) 2011-03-25 2013-06-04 Exxonmobil Chemical Patents Inc. Catalysts and methods of use thereof to produce vinyl terminated polymers
CN103459434B (zh) * 2011-03-25 2016-05-11 埃克森美孚化学专利公司 乙烯基大分子单体使用茂金属的氢硅烷化
US8669326B2 (en) 2011-03-25 2014-03-11 Exxonmobil Chemical Patents Inc. Amine functionalized polyolefin and methods for preparation thereof
CN103443133B (zh) * 2011-03-25 2015-01-07 埃克森美孚化学专利公司 来自甲硅烷基化乙烯基封端的大分子单体的嵌段共聚物
US8835563B2 (en) 2011-03-25 2014-09-16 Exxonmobil Chemical Patents Inc. Block copolymers from silylated vinyl terminated macromers
US8604148B2 (en) 2011-11-29 2013-12-10 Exxonmobil Chemical Patents Inc. Functionalization of vinyl terminated polymers by ring opening cross metathesis
US8796376B2 (en) 2012-03-26 2014-08-05 Exxonmobil Chemical Patents Inc. Functionalized polymers and oligomers
ES2726819T3 (es) 2012-09-24 2019-10-09 Exxonmobil Chemical Patents Inc Producción de polietileno terminado en vinilo
WO2014047248A1 (en) 2012-09-24 2014-03-27 Exxonmobil Chemical Patents, Inc. Branched polyethylenes by hydrosilation grafting to improve processability of polyethylene
US9434795B2 (en) 2012-09-24 2016-09-06 Exxonmobil Chemical Patents Inc. Production of vinyl terminated polyethylene using supported catalyst system
EP2922929A1 (en) 2012-11-20 2015-09-30 3M Innovative Properties Company Laminates and articles comprising a block copolymer coating comprising polyorganosiloxane and polyolefin
CN104797634B (zh) * 2012-11-20 2017-12-19 3M创新有限公司 包含聚有机硅氧烷嵌段和聚烯烃嵌段的嵌段共聚物
JP7256169B2 (ja) 2017-07-25 2023-04-11 ダウ シリコーンズ コーポレーション ポリオレフィン主鎖とポリオルガノシロキサンペンダント基とを有する、グラフトコポリマーを調製するための方法
WO2019182721A1 (en) * 2018-03-19 2019-09-26 Dow Silicones Corporation Polyolefin-polydiorganosiloxane block copolymer and hydrosilylaton reaction method for the synthesis thereof
US12037462B2 (en) 2018-03-19 2024-07-16 Dow Global Technologies Llc Polyolefin-polydiorganosiloxane block copolymer and method for the synthesis thereof
CA3093558A1 (en) 2018-03-19 2019-09-26 Dow Silicones Corporation Polyorganosiloxane hot melt adhesive compositions containing polyolefin - polydiorganoosiloxane copolymers and methods for the preparation and use thereof
CA3101628A1 (en) 2018-03-19 2019-09-26 Dow Silicones Corporation Hot melt adhesive composition containing a polyolefin - polydiorganoosiloxane copolymer and methods for the preparation and use thereof
US11702512B2 (en) 2018-07-17 2023-07-18 Dow Silicones Corporation Polysiloxane resin-polyolefin copolymer and methods for the preparation and use thereof
CN117586597B (zh) * 2024-01-19 2024-03-29 苏州禾昌聚合材料股份有限公司 一种耐老化聚丙烯材料及其制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1016512A (en) * 1961-07-28 1966-01-12 Kogyogijutsuin Preparation of a new type polymer silicopolypropylene
JPS5584302A (en) * 1978-12-20 1980-06-25 Takashi Sawaguchi Preparation of alpha,omega-diene-oligomer
US4526953A (en) * 1983-10-03 1985-07-02 General Electric Company Modified silicone release coating compositions
JPH0678505B2 (ja) * 1986-06-24 1994-10-05 五洋紙工株式会社 剥離剤及びそれを用いた剥離紙の製造法
JPH0657777B2 (ja) * 1988-03-31 1994-08-03 信越化学工業株式会社 ゴム組成物
KR100293498B1 (ko) * 1996-05-13 2001-09-17 모리시타 요이찌 사출장치

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7502058B2 (en) 2003-06-09 2009-03-10 Micron Technology, Inc. Imager with tuned color filter
US8105862B2 (en) 2003-06-09 2012-01-31 Micron Technology, Inc. Imager with tuned color filter

Also Published As

Publication number Publication date
EP0802216B1 (en) 2000-01-26
US5744541A (en) 1998-04-28
TW505679B (en) 2002-10-11
DE69701201D1 (de) 2000-03-02
ES2144810T3 (es) 2000-06-16
EP0802216A1 (en) 1997-10-22
KR100498524B1 (ko) 2005-10-21
DE69701201T2 (de) 2000-06-21

Similar Documents

Publication Publication Date Title
KR970070054A (ko) 폴리프로필렌과 오가노폴리실록산의 공중합체 및 이의 제조 방법
JP4382196B2 (ja) シロキサンをベースとするポリアミドの製造方法
US3274155A (en) Organosilicon compositions
CN110603283B (zh) 氢化硅烷化可固化的有机硅树脂
KR910006418A (ko) 백금 촉매화된 헤테로환형 화합물 조성물
CA2035396A1 (en) Siloxane copolymers containing alkenyloxy groups, a process for preparing the same and their use
US4388449A (en) Silicone resin
KR970707215A (ko) 선형 카르보란-(실록산 또는 실란)-아세틸렌 공중합체로부터 유래된 고온 열경화체 및 세라믹(High Temperature Thermosets and Ceramics Derived from Linear Carborane-(Siloxane or Silane)-Acetylene Copolymers)
US4267298A (en) Process for preparing M-stopped silicone fluids from silanol fluids
KR880001724A (ko) 비닐 말단 불소-함유 폴리디오르가노실옥산의 제조방법
KR900012941A (ko) 선택적으로 모노히드로사일레이션 (monohydrosilation)된 노보넨 화합물과 그의 제조 방법 및 그로부터 제조된 중합체
US4341888A (en) Diorganopolysiloxane copolymers and process for the preparation thereof
KR100459526B1 (ko) 실온경화성오가노실록산조성물
US3652711A (en) Method of polymerizing siloxanes
US6150488A (en) Process for preparing silanol-functional specifically branched organopolysiloxanes and products produced thereby
KR970070053A (ko) 실리콘 조성물 및 이의 용도
US5350824A (en) Fluorosilicone polymers and methods for the preparation thereof
US3678126A (en) Siloxane containing thermoplastic elastomers
EP0501077B1 (en) Method for the preparation of diorganopolysiloxane end-blocked with silanolic hydroxy groups
US4634755A (en) Method for making norbornane anhydride substituted polyorganosiloxane
US4049676A (en) Sulfolanyloxyalkyl cyclic polysiloxanes
US4778871A (en) High temperature insulators
EP0624616A2 (en) Organosiloxane ethers
US3328346A (en) Methylphenyl polysiloxanes
Mabry et al. Synthesis and thermal crosslinking of benzophenone‐modified poly (dimethylsiloxane) s

Legal Events

Date Code Title Description
A201 Request for examination
N231 Notification of change of applicant
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20130322

Year of fee payment: 9

FPAY Annual fee payment

Payment date: 20140319

Year of fee payment: 10

FPAY Annual fee payment

Payment date: 20160325

Year of fee payment: 12