KR970065648A - 할로겐을 함유하지 않은 불연성 혼합물 - Google Patents

할로겐을 함유하지 않은 불연성 혼합물 Download PDF

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KR970065648A
KR970065648A KR1019970009076A KR19970009076A KR970065648A KR 970065648 A KR970065648 A KR 970065648A KR 1019970009076 A KR1019970009076 A KR 1019970009076A KR 19970009076 A KR19970009076 A KR 19970009076A KR 970065648 A KR970065648 A KR 970065648A
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mixture
base polymer
parts
mixture according
heat resistance
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루즈 프리데만
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크리스띠앙 그레고리
알카텔 알스톰 꽁파니 제네랄 델렉트리시트
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/22—Thermoplastic resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
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Abstract

본 발명은 내열성이 높은 열가소성 중합체 물질을 주성분으로 하는, 전기 및/또는 광학적 케이블 및 라인의 제조시 특히 유용한 할로겐-비함유의 불연성 혼합물에 관한 것으로서, 이 혼합물은 상기 기본 중합체 이외에도, -주기율표의 Ⅱ, Ⅱa 또는 Ⅱb족 금속 염, -금속 수산화물, 및 -충분량의 실리콘 유 또는 실리콘 고무, 및 이들의 혼합물중 한 성분 이상을 충분량 포함한다.

Description

할로겐을 함유하지 않은 불연성 혼합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. 내열성이 높은 열가소성 중합체 물질을 주성분으로 하며, 이 기본 중합체 이외에도 - 주기율표의 Ⅱ, Ⅱa 또는 Ⅱb족 금속 염, -금속 수산화물, 및 -실리콘 유 또는 실리콘 고무, 및 이들의 혼합물을 포함하는, 전기 및/또는 광학 케이블 및 라인을 제조하는데 특히 유용한 불연성의 할로겐-비함유 혼합물.
  2. 제1항에 있어서, 100부의 기본 중합체 물질에 대해 1 내지 15부의 금속염, 30 내지 180부의 금속 히드록시드, 0.3 내지 20부의 실리콘 유 또는 실리콘 고무, 또는 이들의 혼합물을 포함하는 것을 특징으로 하는 혼합물.
  3. 제1항 또는 제2항에 있어서, 금속염이 카르복실산의 염인 것을 특징으로 하는 혼합물.
  4. 제1항 또는 제2항에 있어서, 카르복실산의 금속염이 칼슘 스테아레이트인 것을 특징으로 하는 혼합물.
  5. 제1항 또는 제2항에 있어서, 카르복실산의 금속염이 마그네슘 스테아레이트인 것을 특징으로 하는 혼합물.
  6. 제1항 또는 제2항에 있어서, 금속 히드록시드가 수산화 마그네슘인 것을 특징으로 하는 혼합물.
  7. 제1항 또는 제2항에 있어서, 금속 히드록시드가 수산화 알루미늄인 것을 특징으로 하는 혼합물.
  8. 제1항 또는 제2항에 있어서, 내열성이 높은 기본 중합체가 고밀도의 폴리에틸렌인 것을 특징으로 하는 혼합물.
  9. 제1항 또는 제2항에 있어서, 내열성이 높인 기본 중합체가 폴리프로필렌인 것을 특징으로 하는 혼합물.
  10. 제9항 있어서, 폴리프로필렌이 PP 블록 공중합체, PP 램던 공중합체 또는 PP 랜덤 블록 공중합체 같은 공중합체인 것을 특징으로 하는 혼합물.
  11. 제1항 또는 제2항에 있어서, 기본 중합체가 내열성이 낮은 중합체와 내열성을 향상시키는 성분의 혼합물인 것을 특징으로 하는 혼합물.
  12. 제1항 또는 제2항에 있어서, 100부의 기본 중합체당 10 내지 80부의 무기 충전제를 포함하는 것을 특징으로 하는 혼합물.
  13. 제12항 있어서, 충전제로서 초크(CaCO3)가 사용되는 혼합물.
  14. 제1항 또는 제2항에 있어서, 부가량의 말레산 무수물-결합 기본 중합체를 포함하는 것을 특징으로 하는 혼합물.
  15. 제14항 있어서, 말레산 무수물-결합 기본 중합체의 비율이 기본 중합체 100부당 0.5 내지 5부인 것을 특징으로 하는 혼합물.
  16. 제1항 또는 제2항에 있어서, 기본 중합체가 가교결합된 것을 특징으로 하는 혼합물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970009076A 1996-03-19 1997-03-18 할로겐을함유하지않은내연성혼합물 KR100479529B1 (ko)

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DE19610513A DE19610513B4 (de) 1996-03-19 1996-03-19 Flammwidrige, halogenfreie Mischung
DE19610513.7 1996-03-19

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US (1) US6429246B1 (ko)
EP (1) EP0802235B1 (ko)
JP (1) JP4074681B2 (ko)
KR (1) KR100479529B1 (ko)
DE (2) DE19610513B4 (ko)
ES (1) ES2258276T3 (ko)

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JP6069573B1 (ja) * 2015-12-14 2017-02-01 株式会社フジクラ 難燃性樹脂組成物、これを用いたメタルケーブル、光ファイバケーブル及び成形品
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WO2018034173A1 (ja) * 2016-08-16 2018-02-22 株式会社フジクラ 難燃性樹脂組成物、これを用いた絶縁電線、メタルケーブル、光ファイバケーブル及び成形品
WO2018034174A1 (ja) * 2016-08-16 2018-02-22 株式会社フジクラ 難燃性樹脂組成物、これを用いた絶縁電線、メタルケーブル、光ファイバケーブル及び成形品
JP2018039902A (ja) * 2016-09-07 2018-03-15 株式会社フジクラ 難燃性樹脂組成物、これを用いた絶縁電線、メタルケーブル、光ファイバケーブル、自動車用ワイヤハーネス、及び成形品
JP6239081B1 (ja) 2016-11-22 2017-11-29 株式会社フジクラ 難燃性樹脂組成物、これを用いた絶縁電線、メタルケーブル、光ファイバケーブル及び成形品
CN108164781B (zh) * 2016-12-07 2020-06-16 上海凯波特种电缆料厂有限公司 一种布电线用无卤低烟阻燃聚乙烯电缆料及其制备方法
CN108129762A (zh) * 2017-12-06 2018-06-08 淮北市天相电缆有限责任公司 一种新型环保型电缆绝缘层护套料
CN108976536A (zh) * 2018-06-22 2018-12-11 安徽旺达铜业发展有限公司 一种高耐热耐辐射电缆护套料
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EP0802235A1 (de) 1997-10-22
JPH107913A (ja) 1998-01-13
KR100479529B1 (ko) 2005-07-18
US6429246B1 (en) 2002-08-06
ES2258276T3 (es) 2006-08-16
DE19610513B4 (de) 2006-10-19
DE59712625D1 (de) 2006-06-01
JP4074681B2 (ja) 2008-04-09
DE19610513A1 (de) 1997-09-25
EP0802235B1 (de) 2006-04-26

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