KR970065574A - 3원공중합체 - Google Patents

3원공중합체 Download PDF

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Publication number
KR970065574A
KR970065574A KR1019970010295A KR19970010295A KR970065574A KR 970065574 A KR970065574 A KR 970065574A KR 1019970010295 A KR1019970010295 A KR 1019970010295A KR 19970010295 A KR19970010295 A KR 19970010295A KR 970065574 A KR970065574 A KR 970065574A
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group
carbon atoms
hydrogen
represented
structural unit
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KR1019970010295A
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아키노리 이토
스스무 혼다
세이고 키노시타
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우노 마사야스
니혼유시 가부시기가이샤
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Publication of KR970065574A publication Critical patent/KR970065574A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/285—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/38—Esters containing sulfur
    • C08F220/382—Esters containing sulfur and containing oxygen, e.g. 2-sulfoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/02—Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/04—Anhydrides, e.g. cyclic anhydrides
    • C08F222/06—Maleic anhydride
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Detergent Compositions (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

본 발명은, 폴리옥시알킬렌기, 술폰산기 및 카르복실기를 가지고, 또한, 가수분해에 대해서 안정적이며, 고분자계면활성제로서 유용한 3원공중합체를 제공하는 것을 과제로 한 것이며, 그 해결수단으로서 (a) 폴리옥시알킬렌알케닐에테르의 단위, (b) 알케닐술폰산의 단위 및 (c) 말레인산계화합물의 단위를 필수단량체단위로서 가지고, 필수단량체단위 (a), (b) 및 (c)의 조성비가 몰비로 ｛(a)+(b)｝: (c)=3:7∼7:3이며, 또한 (a) 및 (b)의 조성비가 몰비로 (a):(b)=1:5∼99:1이며, 중량평균분자량이 500∼100,000인 3원공중합체를 얻는 것을 특징으로 한 것이다.

Description

3원공중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. (a) 일반식〔1〕로 표시되는 폴리옥시알킬렌화합물의 단위
    R1O(AO)nR2(1)
    (단, 식중, R1은 탄소수 2∼5의 알케닐기이며, R2는 수소, 탄소수 1∼40의 탄화수소기 또는 탄소수 2∼18의 아실기이며, AO는 탄소수 2∼18의 옥시알킬렌기이며,n은 옥시알킬렌기의 평균부가몰수로 1∼500이다.)
    (b) 일반식〔2〕로 표시되는 술폰화합물의 단위
    R2SO3M1(2)
    (단, 식중, R3은 탄소수 2∼5의 알케닐기 또는 탄소수 8∼9의 알케닐페닐기이며, M1은 수소, 알카리금속, 알카리토류금속 또는 무치환 혹은 유기기치환 암모늄기이다.) 및 (c) 무수말레인산, 말레인산 또는 말레인산염으로 이루어진 말레인산계 화합물의 단위를 필수단량체단위로서 가지고, 필수단량체단위(a), (b) 및 (c)의 조성비가 몰비로 ｛(a)+(b)｝: (c)=3:7∼7:3이며, 또한 (a) 및 (b)의 조성비가 몰비로 (a):(b)=1:5∼99:1이며, 중량평균분자량이 500∼100,000인 3원공중합체.
  2. 일반식〔3〕으로 표시되고,
    (단, 식중, R2는 수소, 탄소수 1∼40의 탄화수소기 또는 탄소수 2∼18의 아실기이며, R4및 R5는 수소 또는 메틸기이며, AO는 탄소수 2∼18의 옥시알킬렌기이며, n은 옥시알킬렌기의 평균부가몰수로 1∼500이며, X는 CmH2m로 표시되는 탄화수기로 m은 0∼3이며, Y는 페닐렌기 또는 CpH2p로 표시되는 탄화수기로 p는 0∼3이며, M1, M2및 M3은 수소, 알카리금속, 알카리토류금속 또는 무치환 혹은 유기기치환 암모늄기이며, Z1및 Z2는 수소 또는 중합개시 혹은 연쇄이동에 의해 공중합체말단에 결합하는 잔기이며, a, b 및 c는 각 구성 단위의 몰수로, a는 1∼100, b는 1∼100, c는 1∼100이며, 각구성단위는 랜덤상으로 결합해 있다.) 각 구성 단위의 a, b 및 c의 몰비가 (a+b) :c=3 :7∼7 :3이며,또한 a 및 b의 몰비가 a:b=1:5∼99:1인 3원 공중합체.
  3. 일반식〔4〕로 표시되고,
    (단, 식중, R2는 수소, 탄소수 1∼40의 탄화수소기 또는 탄소수 2∼18의 아실기이며, R4및 R5는 수소 또는 메틸기이며, AO는 탄소수 2∼18의 옥시알킬렌기이며, n은 옥시알킬렌기의 평균부가몰수로 1∼500이며, X는 CmH2m로 표시되는 탄화수기로 m은 0∼3이며, Y는 페닐렌기 또는 CpH2p로 표시되는 탄화수기로 p는 0∼3이며, M1은 수소, 알카리금속, 알카리토류금속 또는 무치환 혹은 유기기치환 암모늄기이며, Z1및 Z2는 수소 또는 중합개시 혹은 연쇄이동에 의해 공중합체말단에 결합하는 잔기이며, a, b 및 c는 각 구성 단위의 몰수로, a는 1∼100, b는 1∼100, c는 1∼100이며, 각구성단위는 랜덤상으로 결합해 있다.) 각 구성 단위의 a, b 및 c의 몰비가 (a+b) :c=3 :7∼7 :3이며,또한 a 및 b의 몰비가 a:b=1:5∼99:1인 3원 공중합체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970010295A 1996-03-26 1997-03-25 3원공중합체 KR970065574A (ko)

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Application Number Priority Date Filing Date Title
JP8097531A JPH09255740A (ja) 1996-03-26 1996-03-26 三元共重合体
JP96-97531 1996-03-26

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EP0798320A2 (en) 1997-10-01
EP0798320A3 (de) 1998-12-16

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