KR970010906A - 환경 부식 내성이 있는 수성 코팅 조성물 - Google Patents

환경 부식 내성이 있는 수성 코팅 조성물 Download PDF

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KR970010906A
KR970010906A KR1019960033136A KR19960033136A KR970010906A KR 970010906 A KR970010906 A KR 970010906A KR 1019960033136 A KR1019960033136 A KR 1019960033136A KR 19960033136 A KR19960033136 A KR 19960033136A KR 970010906 A KR970010906 A KR 970010906A
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acrylic polymer
coating composition
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functional
carbamate
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디. 맥기 존
에이치. 캠벨 도날드
더블유. 레퍼스 존
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로버트 엠. 쇼
바스프 코오포레이숀
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    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
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    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
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    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
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    • C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
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    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
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    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
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    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09D161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
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Abstract

본 발명은 환경 부식 내성이 있는 코팅에 관한 것이다. 본 발명의 코팅은 하기 (a) 및 (b)성분을 포함하는 수성 경화성 조성물로부터 유도된다 : (a) 제1아크릴 중합체와 제2아크릴 중합체와의 반응 생성물을 포함하는 카르바메이트-작용성 그라프트(grafted) 아크릴 중합체로서, 상기 제1아크릴 중합체와 제2아크릴 중합체중 하나 이상은 상기 그라프트 아크릴 중합체에 수(水)-분산성을 제공하는 기를 가지며, 상기 제1아크릴 중합체와 제2아크릴 중합체중 하나 이상은 카르바메이트 작용기를 가지는 카르바메이트-작용성 그라프트 아크릴 중합체 ; 및 (b) 상기 카르바메이트 작용기와의 반응성이 있다는 다수의 작용기를 가진 화합물.

Description

환경 부식 내성이 있는 수성 코팅 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. (a) (i) 작용기(I)를 가진 제1아크릴 중합체와, (ii) 상기 제1아크릴 중합체의 작용기(I)에 대해 반응성인 작용기(II)를 가진 제2아크릴 중합체와의 반응 생성물을 포함하는 카르바메이트-작용성 그라프트 아크릴 중합체로서, 상기 제1 및 제2아크릴 중합체중 하나 또는 2가지 모두가 상기 그라프트 아크릴 중합체에 수(水)-분산성을 제공하는 기를 갖고, 상기 제1 및 제2아크릴 중합체중 하나 또는 2가지 모두가 카르바메이트 작용기를 갖는 카르바메이트-작용성 그라프트 아크릴 중합체 및 (b) 상기 카르바메이트 작용기와의 반응성이 있는 다수의 작용기를 가진 화합물을 포함하는 것을 특징으로 하는 경화성 코팅 조성물.
  2. 제1항에 있어서, 상기 그라프트 아크릴 중합체에 수-분산성을 제공하는 기가 음이온성 또는 비이온성 기인 것을 특징으로 하는 코팅 조성물.
  3. 제2항에 있어서, 상기 그라프트 아크릴 중합체에 수-분산성을 제공하는 기가 카르복실산 기인 것을 특징으로 하는 코팅 조성물.
  4. 제1항에 있어서, 상기 그라프트 아크릴 중합체에 수-분산성을 제공하는 기가 상기 제2아크릴 중합체상에 존재하는 것을 특징으로 하는 코팅 조성물.
  5. 제4항에 있어서, 상기 작용기(I)가 에폭시 작용기이고, 상기 작용기(II) 및 상기 수-분산성을 제공하는 기는 둘다 카르복실산 기인 것을 특징으로 하는 코팅 조성물.
  6. 제1항 내지 제5항 중 어느 한 항에 있어서, 상기 그라프트 아크릴 중합체에 수-분산성을 제공하는 기가 상기 제1 및 제2아크릴 중합체상에 둘다 존재하는 것을 특징으로 하는 코팅 조성물.
  7. 제1항 내지 제5항 중 어느 한 항에 있어서, 상기 카르바메이트 작용기가 화학식-L-O-C(=O)-NHR로 표시되는 구조를 포함하며, 이때 L은 가의 연결기를 나타내고, R은 H, 알킬, 또는 시클로알킬을 나타내는 것을 특징으로 하는 코팅 조성물.
  8. 제7항에 있어서, R이 수소원자, C1-6알킬, 또는 고리 탄소원자가 6개인 시클로 알킬인 것을 특징으로 하는 코팅 조성물.
  9. 제7항에 있어서, L이 화학식 -COO-L′-로 표시되며, 이때 L′는 2가의 연결기인 것을 특징으로 하는 코팅 조성물.
  10. 제1항 내지 제5항 중 어느 한 항에 있어서, 상기 성분(b)가 실록산, 보호된 이 소시아네이트, 알콕시, 및 메틸을 작용기로 이루어진 군중에서 선택된 작용기를 갖는 것을 특징으로 하는 코팅 조성물.
  11. 제1항 내지 제5항 중 어느 한 항에 있어서, 상기 성분(b)가 아미노플라스트 수지인 것을 특징으로 하는 경화성 코팅 조성물.
  12. 제11항에 있어서, 상기 아미노플라스트 수지가 멜라민 포름알데히드 수지인 것을 특징으로 하는 코팅 조성물.
  13. 제1항 내지 제5항 중 어느 한 항에 있어서, 상기 카르바메이트-작용성 그라프트아크릴 중합체가 상기 제1아크릴 중합체의 존재하에서 상기 제2아크릴 중합체를 중합반응시키는 것을 포함하는 방법에 의해 제조되는 것을 특징으로 하는 코팅 조성물.
  14. 제1항 내지 제5항 중 어느 한 항에 있어서, 정의한 수성 경화성 코팅 조성물로부터 유도된 상도층(topcoat) 코팅.
  15. 제14항에 있어서, 착색+투명층 복합 코팅인 상도층 코팅.
  16. 착색된 코팅 조성물을 기재에 도포하는 단계, 상기 착색된 코팅 조성물상에 수성투명 코팅 조성물을 도포하는 단계, 및 상기 복합 코팅을 경화시키는 단계를 포함하여 기재상에 환경 부식 내성이 있는 코팅을 생성시키는 방법으로서, 상기 수성 투명 코팅 조성물이 제1항 내지 제5항 중 어느 한 항에서 정의한 경화성 코팅 조성물인 방법.
  17. 제16항에 있어서, 상기 수-분산성을 제공하는 기가 상기 제2아크릴 중합체상에 존재하며, 상기 카르바메이트 작용기는 상기 제1 및 제2아크릴 중합체상에 둘다 존재하는 것을 특징으로 하는 방법.
  18. 제16항에 있어서, 상기 수-분산성을 제공하는 기가 상기 제1아크릴 중합체상에 존재하며, 상기 카르바메이트 작용기는 상기 제2아크릴 중합체상에 존재하는 것을 특징으로 하는 방법.
  19. 제1항 내지 제5항중 어느 한 항에서 정의한 코팅 조성물로부터 형성된 경화된 코팅을 가진 코팅된 기재.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960033136A 1995-08-10 1996-08-09 환경부식내성이있는수성코팅조성물 KR100423271B1 (ko)

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US08/513,587 US5726244A (en) 1995-08-10 1995-08-10 Aqueous coating compositions for environmental etch resistant coatings
US08/513,587 1995-08-10

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AU (1) AU703033B2 (ko)
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JPH09221578A (ja) 1997-08-26
KR100423271B1 (ko) 2004-07-12
AU703033B2 (en) 1999-03-11
MX9603233A (es) 1997-07-31
EP0761695A2 (en) 1997-03-12
CN1148612A (zh) 1997-04-30
AU6198796A (en) 1997-02-13
DE69610805T2 (de) 2001-04-12
EP0761695A3 (en) 1997-07-09
US5726244A (en) 1998-03-10
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JP3973718B2 (ja) 2007-09-12

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