KR950703031A - 개선된 금속성 안료 배향을 갖는 수성 코팅 조성물(waterborne coating compositions having improved metallic pigment orientation) - Google Patents

개선된 금속성 안료 배향을 갖는 수성 코팅 조성물(waterborne coating compositions having improved metallic pigment orientation) Download PDF

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KR950703031A
KR950703031A KR1019950700759A KR19950700759A KR950703031A KR 950703031 A KR950703031 A KR 950703031A KR 1019950700759 A KR1019950700759 A KR 1019950700759A KR 19950700759 A KR19950700759 A KR 19950700759A KR 950703031 A KR950703031 A KR 950703031A
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coating composition
aqueous coating
acid
anhydride
aqueous
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KR1019950700759A
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KR100240908B1 (ko
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데니스 탈잔
제임스 에드워드 풀
마비스 에드가 하트만
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리타 버그스트롬
피피지 인더스트리즈, 인코포레이티드(Ppg Industries, Inc.)
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • C08F283/008—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00 on to unsaturated polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/024—Emulsion paints including aerosols characterised by the additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/38—Paints containing free metal not provided for above in groups C09D5/00 - C09D5/36

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

수성 코팅 조성물은 수성 매질중에 중합체성 필름 형성 수지, 및 상기 조성물의 수지 고형물을 기준으로 약 1 내지 약 40중량%의 하기 일반식의 올리고머성 에스테르를 함유한다.
상기식에서, X는 산 또는 무수물과 반응후의 폴리올의 잔기이고, R는 산 또는 무수물과 관련된 유기 잔기이고, A는 약 2 이상의 평균값을 갖는다.
상기 수성 코팅 조성물은 탁월한 얼룩 저항성을 나타내고, 우수한 플로프를 가지며, 상대 습도 변동에 대한 민감성이 감소되었기 때문에 자동차 하도막 용도를 위한 착색된 금속성 코팅 조성물로서 특히 유리하다.

Description

개선된 금속성 안료 배향을 갖는 수성 코팅 조성물(WATERBORNE COATING COMPOSITIONS HAVING IMPROVED METALLIC PIGMENT ORIENTATION)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (24)

  1. 조성물의 수지 고형물을 기준으로 약 1 내지 약 40중량%의 하기 일반식의 올리고머성 에스테르를 함유함을 특징으로 하는, 수성 매질중에 중합체성 필름 형성 수지를 함유하는 수성 코팅 조성물 :
    상기식에서, X는 산 또는 무수물과 반응후의 폴리올의 잔기이고, R는 산 또는 무수물과 관련된 유기 잔기이고, A는 약 2 이상의 평균값을 갖는다.
  2. 제1항에 있어서, 약 1 내지 약 25중량%의 상기 올리고머성 에스테르륜 함유하는 수성 코팅 조성물.
  3. 제1항에 있어서, X가 하이드록실 그룹당 하나 내지 50개의 탄소원자, 바람직하게 하이드록실 그룹당 2 내지 25개의 탄소원자를 함유하는 폴리올의 잔기인 수성 코팅 조성물.
  4. 제3항에 있어서, 상기 포리올이 1-3-하이드록시 -2,2-디메틸프로필)-3-하이드록시-2,2-디메틸프로피오네이트, 1,4-사이클로헥산 디메탄올, 트리메틸올프로판, 디-트리메틸올프로판, 네오펜틸글리콜, 1,4-부탄디올, 1,6-헥산디올 및 펜타에리쓰리톨로 이루어진 그룹중에서 선택된 수성 코팅 조성물.
  5. 제1항에 있어서, R이 탄소수 2 내지 30의 방향족 또는 지환족 잔기인 수성 코팅 조성물.
  6. 제5항에 있어서, R이 알킬 치환된 프탈산, 헥사하이드로프탈산 및 알킬 치환된 헥사하이드로프탈산으로 이루어진 그룹중에서 선택된 폴리카복실산의 잔기인 수성 코팅 조성물.
  7. 제1항에 있어서, 상기 올리고머성 에스테르가 1-(3-하이드록시-2,2-디메틸프로필)-3-하이드록시-2,2-디메틸프로피오네이트와 메틸 헥사하이드로프탈산 무수물의 반응 생성물인 수성 코팅 조성물.
  8. 제1항에 있어서, 상기 올리고머성 에스테르가 사이클로헥산디메탄올과, 메틸헥사하이드로프탈산 무수물 및 헥사하이드로프탈산 무수물의 혼합물과의 반응 생성물인 수성 코팅 조성물.
  9. 제1항에 있어서, 상기 올리고머성 에스테르가 1-(3-하이드록시-2,2-디메틸프로필)-3-하이드록시-2,2-디메틸프로피오네이트와 아디프산의 반응 생성물인 수성 코팅 조성물.
  10. 제1항에 있어서, 상기 필름 형성 수지가 가교결합제와 반응할 수 있는 작용기를 함유하는 수성 코팅 조성물.
  11. 제10항에 있어서, 가교결합제를 함유하는 수성 코팅 조성물.
  12. 제11항에 있어서, 상기 가교결합제가 아미노플라스트 수지인 수성 코팅 조성물.
  13. 제1항에 있어서, 상기 휘발성 유기성분 함량이 3. 51b/gal 미만인 수성 코팅 조성물.
  14. 제1항에 있어서, 상기 필름 형성 수지가, 비닐 단량체(들) 및 소수성 중합체의 중량을 기준으로 30중량% 이상의 실질적으로 소수성인 중합체(이때 상기 중합체는 상기 중합체 주쇄중에 아크릴 또는 비닐 반복 단위가 필수적으로 없으며 분자량이 300℃ 이상이다)와 비닐 단량체 또는 비닐 단량체들의 혼합물과의 혼합물을 수성 매질중에 형성시키고 상기 혼합물을 고압 기법에 의해 미립자로 미립화시킨 다음 상기 비닐 단량체(들)를 중합시켜 상기 수성 매질중에 안정하게 분산된 미립자를 형성시킴으로써 제조된 중합체성 미립자를 포함하는 라텍스인 수성 코팅 조성물.
  15. 제14항에 있어서, 상기 소수성 중합체가 폴리에스테르 또는 폴리우레탄인 수성 코팅 조성물.
  16. 제14항에 있어서, 상기 미립자가 가교결합된 수성 코팅 조성물.
  17. 제14항에 있어서, 가교결합제를 함유하는 수성 코팅 조성물.
  18. (I) 조성물의 수지 고형물을 기준으로 약 1 내지 약 40중량%의 하기 일반식의 올리고머성 에스테르를 함유함을 특징으로 하는, 수성 매질중에 중합체성 필름 형성 수지를 함유하는 착색된 수성 코팅 조성물을 하도막으로서 기재의 표면에 도포하고 :
    상기식에서, X는 산 또는 무수물과 반응후의 폴리올의 잔기이고, R는 산 또는 무수물과 관련된 유기 잔기이고, A는 약 2 이상의 평균값을 갖고; (II) 상기 단계(I)에서 도포된 조성물을 적어도 부분적으로 건조 또는 경화시켜 상기 기재 표면상에 하도막을 형성시키고; (III) 상기 단계(II)의 하도막상에 투명한 필름 형성 조성물을 도포하고, (IV) 상기 단계(III)의 투명한 조성물을 적어도 부분적으로 건조 또는 경화시켜 상기 하도막상에 투명한 상도막을 형성시킴을 포함하는, 기재상에 다층 코팅을 형성시키는 방법.
  19. 제18항에 있어서, 상기 하도막이 가교결합체를 함유하는 방법.
  20. 제18항에 있어서, 상기 투명 상도막이 용매 기재인 방법.
  21. 제18항에 있어서, 상기 투명 상도막이 수성 기재인 방법.
  22. 제18항에 있어서, 상기 투명 상도막이 분말 코팅 조성물인 방법.
  23. 제18항에 있어서, 상기 하도막이 금속 안료를 함유하는 방법.
  24. 제18항이 방법에 따라 코팅된 기재.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950700759A 1992-08-31 1993-08-11 개선된금속성안료배향을갖는수성코팅조성물 KR100240908B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US07/938,912 US5356973A (en) 1992-08-31 1992-08-31 Aqueous based coating compositions having improved metallic pigment orientation
US7/938912 1992-08-31
US07/938912 1992-08-31
PCT/US1993/007536 WO1994005733A1 (en) 1992-08-31 1993-08-11 Waterborne coating compositions having improved metallic pigment orientation

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KR950703031A true KR950703031A (ko) 1995-08-23
KR100240908B1 KR100240908B1 (ko) 2000-01-15

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US (2) US5356973A (ko)
EP (1) EP0656922B1 (ko)
JP (1) JP2661798B2 (ko)
KR (1) KR100240908B1 (ko)
CN (1) CN1039718C (ko)
AT (1) ATE231905T1 (ko)
AU (1) AU670969B2 (ko)
CA (1) CA2141823C (ko)
DE (1) DE69332667T2 (ko)
ES (1) ES2191667T3 (ko)
MX (1) MX9305244A (ko)
TW (1) TW314544B (ko)
WO (1) WO1994005733A1 (ko)
ZA (1) ZA936173B (ko)

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EP0656922A1 (en) 1995-06-14
CN1039718C (zh) 1998-09-09
MX9305244A (es) 1995-01-31
CN1084539A (zh) 1994-03-30
DE69332667D1 (de) 2003-03-06
TW314544B (ko) 1997-09-01
AU670969B2 (en) 1996-08-08
KR100240908B1 (ko) 2000-01-15
US5356973A (en) 1994-10-18
WO1994005733A1 (en) 1994-03-17
AU5004993A (en) 1994-03-29
CA2141823C (en) 1997-12-16
US5510148A (en) 1996-04-23
ZA936173B (en) 1995-02-23
JP2661798B2 (ja) 1997-10-08
EP0656922B1 (en) 2003-01-29
CA2141823A1 (en) 1994-03-17
ATE231905T1 (de) 2003-02-15
JPH07506621A (ja) 1995-07-20
DE69332667T2 (de) 2003-08-21
ES2191667T3 (es) 2003-09-16

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