KR960037758A - 결정질 프로필렌 중합체 조성물 - Google Patents

결정질 프로필렌 중합체 조성물 Download PDF

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Publication number
KR960037758A
KR960037758A KR1019960009917A KR19960009917A KR960037758A KR 960037758 A KR960037758 A KR 960037758A KR 1019960009917 A KR1019960009917 A KR 1019960009917A KR 19960009917 A KR19960009917 A KR 19960009917A KR 960037758 A KR960037758 A KR 960037758A
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South Korea
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composition
propylene polymer
crystalline propylene
weight
fatty acid
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KR1019960009917A
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English (en)
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KR0179443B1 (ko
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노쓰 쯔또무
사와 요시하루
Original Assignee
게이죠 마쯔시마
교와 케미칼 인더스트리 캄파니 리미티드
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Publication of KR960037758A publication Critical patent/KR960037758A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

본 발명은 프로필렌 중합체 100중량부, 방향족 퍼옥사이드 0.01∼1중량부 및 하기 식(1)의 하이드로탈사이트(hydrotalcite) 화합물 0.01∼1중량부를 포함하는, 수지 흐름성, 가공성이 증진되고, 내발색현상(핑킹성)이 현저하며 방청성과 열안정성의 효과가 우수한 결정질 프로필렌 조성물이 제공된다.
(MgyZnz)1-xAlx(OH)2(A)n- x/2·mH2O (1)
단 상기 식에서 (A)n-은 n가의 음이온이고, x, y 및 z는 y+z=1, 0≤y≤0.9, 0.1≤z≤1 및 0.2≤x≤0.8을 만족하는 수이며, m은 0 혹은 양수이다.

Description

결정질 프로필렌 중합체 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 결정질 프로필렌 중합체 100중량부; 방향족 퍼옥사이드 0.01∼1중량부; 및 상기 식(1)의 하이드로탈사이트(hydrotalcite) 0.001∼1중량부를 포함하는 결정질 프로필렌 중합체 조성물.
    (MgyZnz)1-xAlx(OH)2(A)n- x/2·mH2O (1)
    단 상기 식에서 (A)n-은 n가의 음이온이고, x,y 및 y+z=1 0≤y≤0.9, 0.1≤z≤1 및 0.2≤x≤0.8 을 만족하는 수이며 ,m은 0 혹은 양수이다.
  2. 제1항에 있어서, 상기 결정질 프로필렌 중합체는 찌글러(Ziegier) 촉매 존재하에 제조되는 산물임을 특징으로 하는 조성물.
  3. 제2항에 있어서, 상기 결정질 프로필렌 중합체는 촉매를 제거하는 단계를 거치지 않고 제조되는 산물로서 수ppm-수백ppm의 할로겐을 포함함을 특징으로 하는 조성물.
  4. 제1항에 있어서, 상기 결정질 프로필렌 중합체는 프로필렌 단일중합체 혹은 프로필렌 공중합체임을 특징으로 하는 조성물.
  5. 제1항에 있어서, 상기 방향족 퍼옥사이드는 벤젠 고리를 포함한 분자임을 특징으로 하는 조성물.
  6. 제1항에 있어서, 상기 (A)n-은 CO3 2-, HPO4 2-, OH-, ClO4 -, NO3 -, 아세테이트 이온 및 타르타레이트 이온으로 구성되는 그룹으로부터 선택된 최소 하나 단위임을 특징으로 하는 조성물.
  7. 제1항에 있어서, 상기 식(1)의 하이드로탈사이트(hydrotalcite) 화합물은 BET 비표면적 30㎡/g 이하이고 평균 이차 입경이 5㎛ 이하임을 특징으로 하는 조성물.
  8. 제1항에 있어서, 상기 식(1)의 하이드로탈사이트(hydrotalcite) 화합물은 고 지방산, 고 지방산 금속염, 커플링제, 고 지방산 아미드, 고 지방산 에스테르 및 왁스로 구성되는 그룹으로부터 선택되는 최소 하나로써 표면-처리한 산물임을 특징으로 하는 조성물.
  9. 제1항에 있어서, 상기 식(1)의 하이드로탈사이트(hydrotalcite) 화합물은 150∼350℃에서 소성시킨 산물임을 특징으로 하는 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960009917A 1995-04-05 1996-04-02 결정질 프로필렌 중합체 조성물 KR0179443B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP95-103198 1995-04-05
JP7103198A JPH08277351A (ja) 1995-04-05 1995-04-05 結晶性プロピレン重合体組成物

Publications (2)

Publication Number Publication Date
KR960037758A true KR960037758A (ko) 1996-11-19
KR0179443B1 KR0179443B1 (ko) 1999-05-15

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KR1019960009917A KR0179443B1 (ko) 1995-04-05 1996-04-02 결정질 프로필렌 중합체 조성물

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Country Link
US (1) US5677364A (ko)
EP (1) EP0736572B1 (ko)
JP (1) JPH08277351A (ko)
KR (1) KR0179443B1 (ko)
CN (1) CN1099437C (ko)
AT (1) ATE168124T1 (ko)
AU (1) AU694331B2 (ko)
DE (1) DE69600400T2 (ko)
DK (1) DK0736572T3 (ko)
ES (1) ES2119545T3 (ko)
MY (1) MY116649A (ko)
NO (1) NO309003B1 (ko)
TW (1) TW374091B (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1199848C (zh) * 1997-07-21 2005-05-04 Bp北美公司 烃转化方法和催化剂及其催化剂前体
KR100450385B1 (ko) * 1997-10-21 2005-01-17 삼성아토피나주식회사 폴리프로필렌 필름용 조성물
US6964692B2 (en) 2001-02-09 2005-11-15 General Motors Corporation Carbon monoxide adsorption for carbon monoxide clean-up in a fuel cell system
JP4193044B2 (ja) * 2003-03-28 2008-12-10 戸田工業株式会社 Ｍｇ−Ｚｎ−Ａｌ系ハイドロタルサイト型粒子粉末及び該Ｍｇ−Ｚｎ−Ａｌ系ハイドロタルサイト型粒子粉末を用いた樹脂組成物
CN109400782B (zh) * 2017-08-18 2021-06-01 中国石化扬子石油化工有限公司 一种制备高抗冲共聚聚丙烯的方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5580447A (en) 1978-12-14 1980-06-17 Kyowa Chem Ind Co Ltd Prevention of rust, deterioration or coloring of polyolefin and composition
EP0416321B1 (en) * 1989-08-28 1994-11-09 Chisso Corporation Crystalline polyolefin composition
JPH06107717A (ja) * 1992-10-01 1994-04-19 Kyowa Chem Ind Co Ltd 塩化ビニル系単量体の重合方法および塩化ビニル系重合体組成物
JP3284209B2 (ja) * 1992-12-01 2002-05-20 東ソー株式会社 熱可塑性エラストマー組成物

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Publication number Publication date
NO309003B1 (no) 2000-11-27
DK0736572T3 (da) 1998-11-16
AU5041696A (en) 1996-10-17
KR0179443B1 (ko) 1999-05-15
EP0736572A1 (en) 1996-10-09
US5677364A (en) 1997-10-14
MY116649A (en) 2004-03-31
CN1099437C (zh) 2003-01-22
DE69600400D1 (de) 1998-08-13
CN1136052A (zh) 1996-11-20
DE69600400T2 (de) 1998-10-29
JPH08277351A (ja) 1996-10-22
TW374091B (en) 1999-11-11
NO961229D0 (no) 1996-03-27
NO961229L (no) 1996-10-07
AU694331B2 (en) 1998-07-16
ATE168124T1 (de) 1998-07-15
EP0736572B1 (en) 1998-07-08
ES2119545T3 (es) 1998-10-01

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