KR960014188A - 저-포깅 폴리우레탄 포움의 제조방법, 및 이것을 위해 사용될 수 있는 특정 폴리옥시 알킬렌-폴리올 - Google Patents
저-포깅 폴리우레탄 포움의 제조방법, 및 이것을 위해 사용될 수 있는 특정 폴리옥시 알킬렌-폴리올 Download PDFInfo
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
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- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2618—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen
- C08G65/2621—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups
- C08G65/2624—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups containing aliphatic amine groups
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/125—Water, e.g. hydrated salts
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- C08G2110/00—Foam properties
- C08G2110/0016—Foam properties semi-rigid
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0033—Foam properties having integral skins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
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Abstract
본 발명은 (a) 적어도 하나의 유기 폴리이소시아네이트와, (b) N, N′-비스(3-아미노프로필)에틸렌디아민, 트리프로필렌테트라아민 및 테트라프로필렌펜타아민으로 구성된 군으로부터의 하나 이상의 개시제 분자를 하나 이상의 알킬렌 산화물, 바람직하게는 산화 에틸렌 및/또는 산화 1, 2-프로필렌을 사용하여 알콕시화시킴으로써 얻어질 수 있는 30 내지 500의 히드록실가를 갖는 폴리옥시알킬렌-폴리올(b1), 또는 폴리옥시알킬렌-폴리올(b1)의 혼합물, 및 2 내지 8의 작용기성 및 15 내지 500의 히드록실가를 갖는 다른 폴리히드록실 화합물, 및 (c) 바람직하다면 사슬 연장제 및/또는 교차 결합제를, (d) 발포제, 및 바람직하다면, (e) 촉매, 및 (f)첨가제의 존재하에 반응시킴에 의한 폴리우레탄 포움의 제조방법, 및 이를 위해 사용될 수 있는 신규의 폴리옥시알킬렌-폴리올(b1)에 관한 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (11)
- (a) 하나 이상의 유기 폴리이소시아네이트와, (b) 2개 이상의 반응성 수소원자를 함유하는 하나 이상의 비교적 고분자량의 폴리히드록실 화합물, 및 (c) 바람직하다면 저분자량의 사슬 연장제 및/또는 교차 결합제를, (d) 발포제의 존재하에 반응시킴에 의한 폴리우레탄 포움 제조방법으로서, 폴리히드록실 화합물(b)는 N, N′-비스(3-아미노프로필)에틸렌디아민, 트리프로필렌테트라아민 및 테트라프로필렌펜타아민으로 구성된 군으로부터의 하나 이상의 개시제 분자를 하나 이상의 알킬렌 산화물을 사용하여 알콕시화시킴으로써 얻어질 수 있는 30 내지 500의 히드록실가를 갖는 폴리옥시알킬렌-폴리올(b1)임을 특징으로 하는 방법.
- 제1항에 있어서, 사용되는 트리프로필렌테트라아민이 하기식의 화합물로 구성되는 공업용 트리프로필렌테트라아민 혼합물임을 특징으로 하는 방법 : H2N-CH2CH2CH2-NH-CH2CH2CH2-NH2,, N(CH2CH2CH2NH2)3, H2N-CH2CH2CH2-NH-CH2CH2CH2-NH-CH2CH2CH2NH2, 및 CH3CH2CH2-NH-CH2CH2CH2-NH-CH2CH2CH2-NH-CH2CH2CH3.
- 제1항에 있어서, 사용되는 테트라프로필렌펜타아민이 하기식의 화합물로 구성되는 공업용 테트라프로필렌펜타아민 혼합물임을 특징으로 하는 방법 : N(CH2CH2CH2-NH2)3, H2N-(CH2)3-NH-(CH2)3-NH-(CH2)3-NH2,, H2N-(CH2)3-NH-(CH2)3-NH-(CH2)3-NH-(CH2)3-NH2, 및.
- 제1항에 있어서, 알킬렌 산화물이 산화 에틸렌 또는 산화 1, 2-프로필렌 또는 산화 에틸렌과 산화 프로필렌의 혼합물임을 특징으로 하는 방법.
- 제1항에 있어서, 폴리히드록실 화합물이, (b1) N, N′-비스(3-아미노프로필)에틸렌디아민, 트리프로필렌테트라아민 및 테트라프로필렌펜타아민 또는 이것들의 공업용 혼합물로 구성된 군으로부터의 하나 이상의 개시제 분자를 하나 이상의 알킬렌 산화물을 사용하여 알콕시화시킴으로써 얻어질 수 있는 30 내지 500의 히드록실가를 갖는 하나 이상의 폴리옥시알킬렌-폴리올(b1), 및 (b2) 상기 (b1)에서 규정한 폴리옥시알킬렌-폴리올을 제외한 2 내지 8의 작용기성 및 15 내지 500의 히드록실가를 갖는 하나 이상의 폴리히드록실 화합물(b2)로 구성되는 혼합물임을 특징으로 하는 방법.
- 제1항에 있어서, 사용되는 폴리히드록실 화합물이 성분 (b1) 및 (b2)의 전체 중량에 대해, (b1)N, N′-비스(3-아미노프로필)에틸렌디아민, 트리프로필렌테트라아민 및 테트라프로필렌펜타아민 또는 이것들의 공업용 혼합물로 구성된 군으로부터의 하나 이상의 개시제 분자를 하나 이상의 알킬렌 산화물을 사용하여 알콕시화시킴으로써 얻어질 수 있는 0.1 내지 50중량%의 30 내지 500의 히드록실가를 갖는 폴리옥시알킬렌-폴리올(b1), 및 (b2) 상기 (b1)에서 규정한 폴리옥시알킬렌-폴리올을 제외한 2 내지 8의 작용기성 및 15 내지 500의 히드록실가를 갖는 99.9 내지 50중량%의 하나 이상의 폴리히드록실 화합물(b2)로 구성되는 혼합물임을 특징으로 하는 방법.
- 제1항에 있어서, 불포제가 물임을 특징으로 하는 방법.
- 제1항에 있어서, 폴리우레탄 포움이 (e)촉매 및 (f)첨가제의 존재하에 생성됨을 특징으로 하는 방법.
- 제1항에 있어서, 폴리우레탄 포움이 첨가제로서 리시놀레산, 히드록시 지방산 및/또는 알킬 라디칼중에 4 내지 20개의 탄소원자를 갖는 프탈산 디알킬의 존재하에 생성됨을 특징으로 하는 방법.
- N, N′-비스(3-아미노프로필)에틸렌디아민, 트리프로필렌테트라아민, 테트라프로필렌펜타아민 및 이것들의 공업용 혼합물로 구성된 군으로부터의 하나 이상의 개시제 분자상에 하나 이상의 알킬렌 산화물을 중첨가함으로써 얻어질 수 있는 30 내지 500의 히드록실가를 갖는 폴리옥시알킬렌-폴리올.
- 제10항에 있어서, 알킬렌 산화물이 산화 에틸렌 및 산화 1, 2-프로필렌으로 구성된 군으로부터 선택됨을 특징으로 하는 폴리옥시알킬렌-폴리올.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DEP4437878.5 | 1994-10-22 | ||
DE4437878A DE4437878A1 (de) | 1994-10-22 | 1994-10-22 | Verfahren zur Herstellung von fogging-armen Polyurethan-Schaumstoffen und hierfür verwendbare spezielle Polyoxyalkylen-polyole |
Publications (1)
Publication Number | Publication Date |
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KR960014188A true KR960014188A (ko) | 1996-05-22 |
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Application Number | Title | Priority Date | Filing Date |
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KR1019950036819A KR960014188A (ko) | 1994-10-22 | 1995-10-20 | 저-포깅 폴리우레탄 포움의 제조방법, 및 이것을 위해 사용될 수 있는 특정 폴리옥시 알킬렌-폴리올 |
Country Status (9)
Country | Link |
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US (1) | US5672636A (ko) |
EP (1) | EP0708126B1 (ko) |
JP (1) | JPH08208797A (ko) |
KR (1) | KR960014188A (ko) |
CN (1) | CN1070506C (ko) |
AT (1) | ATE221903T1 (ko) |
CA (1) | CA2161064C (ko) |
DE (2) | DE4437878A1 (ko) |
ES (1) | ES2181738T3 (ko) |
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WO2017104608A1 (ja) * | 2015-12-16 | 2017-06-22 | 株式会社ブリヂストン | 軟質ポリウレタンフォーム、及びシート用パッド |
EP3330308A1 (de) * | 2016-12-05 | 2018-06-06 | Covestro Deutschland AG | Verfahren zur herstellung von tdi-basierten polyurethanweichschaumstoffen enthaltend organische säureanhydride und/oder organische säurechloride |
JP6917341B2 (ja) * | 2017-11-15 | 2021-08-11 | 株式会社エフコンサルタント | 被覆材 |
US20220235168A1 (en) * | 2021-01-22 | 2022-07-28 | Covestro Llc | Processes for making molded flexible foams and flexible foams produced thereby |
US11738487B2 (en) * | 2021-01-22 | 2023-08-29 | Covestro Llc | Processes for making molded flexible foams and flexible foams produced thereby |
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US4230824A (en) * | 1978-06-12 | 1980-10-28 | Mobay Chemical Corporation | Sucrose based polyether polyols |
US4368137A (en) * | 1981-05-18 | 1983-01-11 | Petrolite Corporation | Polymers of oxyalkylated piperazines and uses thereof |
US4555531A (en) * | 1985-01-14 | 1985-11-26 | Basf Wyandotte Corporation | Rigid polyurethane foams employing alkylene oxide adducts of alkanolamines |
US6299655B1 (en) * | 1985-03-14 | 2001-10-09 | The Lubrizol Corporation | Diesel fuel compositions |
DD235878B5 (de) * | 1985-04-02 | 1994-04-28 | Basf Schwarzheide Gmbh | Verfahren zur Herstellung autokatalytisch wirkender Polyetheralkohole |
US5130402A (en) * | 1988-07-01 | 1992-07-14 | Sanyo Chemical Industries, Ltd. | Coating composition and plastisol composition, and articles coated therewith |
EP0376602A3 (en) * | 1988-12-28 | 1990-08-29 | MITSUI TOATSU CHEMICALS, Inc. | Process for producing polyurethane foams |
DE4135588A1 (de) * | 1991-10-29 | 1993-05-06 | Basf Ag, 6700 Ludwigshafen, De | Hochreaktive, tertiaere aminogruppen gebunden enthaltende polyoxyalkylenpolyole, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polyisocyanat-polyadditionsprodukten |
US5336278A (en) * | 1993-05-13 | 1994-08-09 | The Lubrizol Corporation | Fuel composition containing an aromatic amide detergent |
-
1994
- 1994-10-22 DE DE4437878A patent/DE4437878A1/de not_active Withdrawn
-
1995
- 1995-10-14 ES ES95116222T patent/ES2181738T3/es not_active Expired - Lifetime
- 1995-10-14 AT AT95116222T patent/ATE221903T1/de not_active IP Right Cessation
- 1995-10-14 DE DE59510310T patent/DE59510310D1/de not_active Expired - Lifetime
- 1995-10-14 EP EP95116222A patent/EP0708126B1/de not_active Expired - Lifetime
- 1995-10-16 US US08/565,208 patent/US5672636A/en not_active Expired - Lifetime
- 1995-10-19 JP JP7270943A patent/JPH08208797A/ja not_active Withdrawn
- 1995-10-20 CA CA002161064A patent/CA2161064C/en not_active Expired - Fee Related
- 1995-10-20 KR KR1019950036819A patent/KR960014188A/ko not_active Application Discontinuation
- 1995-10-21 CN CN95120289A patent/CN1070506C/zh not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100394710B1 (ko) * | 2000-11-16 | 2003-08-14 | 기아자동차주식회사 | 운전교습차량의 보조 브레이크 장치 |
Also Published As
Publication number | Publication date |
---|---|
CA2161064A1 (en) | 1996-04-23 |
US5672636A (en) | 1997-09-30 |
JPH08208797A (ja) | 1996-08-13 |
ATE221903T1 (de) | 2002-08-15 |
EP0708126A2 (de) | 1996-04-24 |
ES2181738T3 (es) | 2003-03-01 |
CN1070506C (zh) | 2001-09-05 |
DE59510310D1 (de) | 2002-09-12 |
EP0708126A3 (de) | 1997-01-15 |
EP0708126B1 (de) | 2002-08-07 |
DE4437878A1 (de) | 1996-04-25 |
CA2161064C (en) | 2006-09-12 |
CN1130196A (zh) | 1996-09-04 |
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