GB967834A - Cellular articles of hydrophilic character and their production - Google Patents

Cellular articles of hydrophilic character and their production

Info

Publication number
GB967834A
GB967834A GB13388/62A GB1338862A GB967834A GB 967834 A GB967834 A GB 967834A GB 13388/62 A GB13388/62 A GB 13388/62A GB 1338862 A GB1338862 A GB 1338862A GB 967834 A GB967834 A GB 967834A
Authority
GB
United Kingdom
Prior art keywords
tertiary
polyester
isocyanate
nitrogen
polyesters
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB13388/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc SA
Original Assignee
Rhone Poulenc SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc SA filed Critical Rhone Poulenc SA
Publication of GB967834A publication Critical patent/GB967834A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4202—Two or more polyesters of different physical or chemical nature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0809—Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups
    • C08G18/0814—Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups containing ammonium groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
    • C08G18/4615—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

Quaternary ammonium polyester polyurethanes hydrophilic foams are produced by a process which comprises reacting polyesters containing tertiary nitrogen atoms and at least two free hydroxyl groups per molecule with organic, di-isocyanates in the presence of water and a monohalohydrocarbon. The straight or branched chain nitrogen-containing polyester is preferably used in conjunction with a straight or branched chain nitrogen-free polyester. Lists of reactants for the preparation of suitable polyesters are given; the tertiary nitrogen atoms being introduced by means of tertiary alkanolamines containing at least two hydroxyl groups per molecule. A mixture of 2,4-tolylene di-isocyanate and 2,6-tolylene di-isocyanate is used as the organic di-isocyanate in the examples. Monohalohydrocarbons specified are alkyl chloride, benzyl chloride and cyclohexyl chloride. A tertiary amine catalyst may be present as also a non-ionic surface-active agent such as an addition product of ethylene oxide with esters of hydroxy fatty acids. Examples are given of the preparation of quaternary ammonium polyester polyurethane foams which are compared with similar foams prepared by omitting the tertiary-nitrogen-containing polyester and/or the monohalohydrocarbon from the reaction mixture. In Example I polyesters are prepared from (a) adipic acid, methyldiethanolamine and trimethylolpropane, and (b) adipic acid, diethylene glycol and trimethylolpropane.
GB13388/62A 1961-04-24 1962-04-06 Cellular articles of hydrophilic character and their production Expired GB967834A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR859675A FR1295437A (en) 1961-04-24 1961-04-24 Cellular objects of a hydrophilic nature and their manufacturing process

Publications (1)

Publication Number Publication Date
GB967834A true GB967834A (en) 1964-08-26

Family

ID=8753704

Family Applications (1)

Application Number Title Priority Date Filing Date
GB13388/62A Expired GB967834A (en) 1961-04-24 1962-04-06 Cellular articles of hydrophilic character and their production

Country Status (5)

Country Link
BE (1) BE616672A (en)
DE (1) DE1168070B (en)
FR (1) FR1295437A (en)
GB (1) GB967834A (en)
NL (1) NL276934A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112175164A (en) * 2020-10-14 2021-01-05 浙江理工大学桐乡研究院有限公司 Preparation method of flame-retardant polyurethane foam

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3988268A (en) * 1972-02-17 1976-10-26 Bayer Aktiengesellschaft Polyurethane foam plastics which contain ionic groups

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2950262A (en) * 1955-08-03 1960-08-23 Pittsburgh Plate Glass Co Preparation of foamed polyurethane using salt of mannich base as catalyst
GB790089A (en) * 1955-12-30 1958-02-05 Ici Ltd Improvements in or relating to the manufacture of polymeric materials

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112175164A (en) * 2020-10-14 2021-01-05 浙江理工大学桐乡研究院有限公司 Preparation method of flame-retardant polyurethane foam

Also Published As

Publication number Publication date
BE616672A (en)
FR1295437A (en) 1962-06-08
DE1168070B (en) 1964-04-16
NL276934A (en)

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