KR960006721B1 - Stacked capacitor fabrication process - Google Patents

Stacked capacitor fabrication process Download PDF

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KR960006721B1
KR960006721B1 KR1019930004556A KR930004556A KR960006721B1 KR 960006721 B1 KR960006721 B1 KR 960006721B1 KR 1019930004556 A KR1019930004556 A KR 1019930004556A KR 930004556 A KR930004556 A KR 930004556A KR 960006721 B1 KR960006721 B1 KR 960006721B1
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conductive layer
insulating
layer
storage electrode
insulating layer
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KR1019930004556A
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KR940022842A (en
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금동렬
박철수
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현대전자산업주식회사
김주용
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L28/00Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
    • H01L28/40Capacitors
    • H01L28/60Electrodes
    • H01L28/82Electrodes with an enlarged surface, e.g. formed by texturisation
    • H01L28/90Electrodes with an enlarged surface, e.g. formed by texturisation having vertical extensions
    • H01L28/92Electrodes with an enlarged surface, e.g. formed by texturisation having vertical extensions made by patterning layers, e.g. by etching conductive layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L28/00Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
    • H01L28/40Capacitors
    • H01L28/60Electrodes
    • H01L28/75Electrodes comprising two or more layers, e.g. comprising a barrier layer and a metal layer
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L28/00Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
    • H01L28/40Capacitors
    • H01L28/60Electrodes
    • H01L28/82Electrodes with an enlarged surface, e.g. formed by texturisation
    • H01L28/86Electrodes with an enlarged surface, e.g. formed by texturisation having horizontal extensions
    • H01L28/88Electrodes with an enlarged surface, e.g. formed by texturisation having horizontal extensions made by patterning layers, e.g. by etching conductive layers

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Semiconductor Memories (AREA)
  • Semiconductor Integrated Circuits (AREA)

Abstract

The method includes the steps of forming a MOSFET, first, second and third insulating layers(6,7,8), fourth planarizing insulating layer(9) and fifth insulating layer(10) on the substrate and forming a first conductive layer(12) for a storage node thereon, laminating a sixth insulating layer(13), second conductive layer(14) for the storage node, seventh insulating layer(15) and third conductive layer(16) for the storage node on the first conductive layer(12) and selectively etching the third conductive layer(16) and sixth insulating layer(13), dry-etching predetermined portions of the third conductive layer(16), seventh insulating layer(15), second conductive layer(14) and sixth insulating layer(13) using a storage node mask pattern and wet-etching the sixth and seventh insulating layers to create undercut the lower portion of the edges of the third and second conductive layers(16,14), and forming a fourth conductive layer for the storage node on the substrate and blanket-etching the fourth, third conductive layer and first conductive layer.

Description

스택 캐패시터 제조방법Stack Capacitor Manufacturing Method

제1도는 본 발명에 의해 제조되는 디램셀의 레이아웃도.1 is a layout diagram of a DRAM cell manufactured according to the present invention.

제2A도 내지 제2G도는 제1도의 A-A를 따라 본 발명에 의해 제조하는 단계를 도시한 단면도.2A through 2G are cross-sectional views illustrating the steps produced by the present invention along A-A of FIG.

제3A도 내지 제3G도는 제1도의 B-B를 따라 본 발명에 의해 제조하는 단계를 도시한 단면도.3A through 3G are cross-sectional views illustrating the steps of manufacturing by the present invention along B-B in FIG.

* 도면의 주요 부분에 내한 부호의 설명* Explanation of cold protection symbols in the main parts of the drawings

1 : 실리콘기판 2 : 소자분리(Field)산화막1: Silicon Substrate 2: Device Oxide

3 : 게이트산화막 4 : 워드라인3: gate oxide film 4: word line

5 : 소오스/드레인 6 : 제1절연막5: source / drain 6: first insulating film

7 : 제2절연막 8 : 제3절연막7: second insulating film 8: third insulating film

9 : 제4절연막 10 : 제5절연막9: fourth insulating film 10: fifth insulating film

11 : 비트라인 12 : 제1도전층11: bit line 12: first conductive layer

13 : 제6절연막 14 : 제2도전층13: sixth insulating film 14: second conductive layer

15 : 제7절연막 16 : 비트라인15: seventh insulating film 16: bit line

80,90 : 콘택.80,90: contact.

본 발명은 고집적 반도체 메모리 소자의 스택 캐패시터 제조방법에 관한 것으로, 특히 캐패시터의 용량을 증가시키기 위하여 소정형태의 저장전극을 형성한 다음, 저장전극 하부, 내부 및 외부표면에 캐패시터 유전체막을 형성한후 플레이트 전극을 형성하는 스택 캐패시터 제조방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of manufacturing a stack capacitor of a highly integrated semiconductor memory device. In particular, a storage electrode of a predetermined type is formed to increase the capacity of a capacitor, and then a capacitor dielectric film is formed on the lower, inner and outer surfaces of the storage electrode, and then a plate. The present invention relates to a stack capacitor manufacturing method for forming an electrode.

디램(DRAM)의 집적도가 증가함에 따라 좁은 면적에서 충분한 캐패시터 용량을 확보하기 위한 캐패시터구조로서 원통형구조와 핀구조등이 개발되었을 뿐만 아니라 실용화가 시도되었으나 이러한 구조들은 제조공정이 어렵고 양산 체제에서 고려되어야할 생산성, 단순성 및 신뢰성등에 문제점이 있었다.As the integration degree of DRAM increases, the cylindrical structure and the fin structure have been developed as well as practical use as a capacitor structure to secure sufficient capacitor capacity in a small area. However, these structures are difficult to manufacture and must be considered in mass production. There were problems in productivity, simplicity and reliability.

따라서, 본 발명은 상기의 문제점을 최소화하면서 동시에 좁은 면적에서 캐패시터 용량을 극대화 시킬 수있는 스택 캐패시터 제조방법을 제공하는데 그 목적이 있다.Accordingly, an object of the present invention is to provide a stack capacitor manufacturing method capable of maximizing a capacitor capacity in a small area while minimizing the above problems.

이하, 첨부된 도면을 참조하여 본 발명을 상세히 설명하기로 한다.Hereinafter, with reference to the accompanying drawings will be described in detail the present invention.

제1도는 본 발명에 의해 제조되는 디램셀의 개략적인 레이아웃도를 도시한 것으로, 세로방향으로 워드라인(50)을 소정간격 이격시켜 배열하고, 가로방향으로 비트라인(60)을 소정간격 이격시켜 배열하고, 예정된 폭을 갖는 저장전극(70)을 비트라인(60) 사이 공간에 배열하고, 저장전극(70)을 실리콘기판에 콘택하는 콘택(80)을 저장전극(70) 중앙에 배열하고, 비트라인(60)을 실리콘 기판에 콘택하는 콘택(90)을 배열한 것으로 각각 영역의 위치를 나타낸 것이다.FIG. 1 is a schematic layout diagram of a DRAM cell manufactured according to the present invention. The word lines 50 are arranged at a predetermined interval in the vertical direction, and the bit lines 60 are spaced at a predetermined interval in the horizontal direction. Arrange a storage electrode 70 having a predetermined width in the space between the bit lines 60, and arrange a contact 80 in the center of the storage electrode 70 to contact the storage electrode 70 to the silicon substrate, Arrangement of the contact 90 which contacts the bit line 60 to a silicon substrate shows the position of each area | region.

제2A도 내지 제2G도는 제1도의 A-A 단면을, 제3A도 내지 제3G도는 제1도의 B-B 단면을 따라 본 발명에 의해 스택 캐패시터를 제조하는 공정단계를 도시한 것으로 편의상 공정단계별로 함께 설명하기로 한다.2A through 2G illustrate the AA cross section of FIG. 1 and FIG. 3A through 3G illustrate the process steps of manufacturing the stack capacitor according to the present invention along the BB cross section of FIG. 1 for convenience. Shall be.

제2A도 및 제3A도는 공지의 기술로 폴드비트라인 디램셀 구조의 MOSFET를 형성하고, 저장전극용 제1도전층을 MOSFET의 드레인에 콘택하기까지를 도시한 단면도로서, 실리콘기판(1)에 소자분리 산화막(2), 게이트 산화막(3), 워드라인(4), 절연 스페이서(6A) 및 소오스/드레인(5)으로 구비되는 MOSFET를 형성하는 동시에 소자분리 산화막(2) 상부에도 워드라인(4)과 절연 스페이서(6A)를 형성한 다음, 전체구조상부에 제 1절연막(6), 평탄화용 제 2절연막(7)을 적층하고, 비트라인(11)을 소오스/드레인(5)에 콘택시킨다음, 전체구조상부에 제 3 절연막(8)과 평탄화용 제 4 절연막(9), 제 5 절연막(10)을 적층한 다음, 저장전극용 제1도전충(12)을 증착하여 콘택홀을 통해 소오스/드레인(5)에 콘택시킨 상태의 단면도이다.2A and 3A are cross-sectional views illustrating the formation of a MOSFET having a fold bit line DRAM cell structure by a known technique and contacting the first conductive layer for storage electrodes to the drain of the MOSFET. A MOSFET including the device isolation oxide film 2, the gate oxide film 3, the word line 4, the insulating spacer 6A, and the source / drain 5 is formed, and at the same time, the word line is formed on the device isolation oxide film 2. 4) and an insulating spacer 6A are formed, and then a first insulating film 6 and a planarizing second insulating film 7 are laminated on the entire structure, and the bit line 11 is contacted to the source / drain 5. Then, the third insulating film 8, the planarizing fourth insulating film 9, and the fifth insulating film 10 are laminated on the entire structure, and then the first conductive charge 12 for the storage electrode is deposited to form a contact hole. It is sectional drawing of the state which contacted the source / drain 5 via.

상기의 제4절연막(9)과 제5절연막(10)은 예정된 습식 에찬트에서 식각선택비가 다른 물질이어야 한다. 제2B도 및 제3B도는 상기 저장전극용 제1도전충(12) 상부에 제6절연막(13), 저장전극용 제2도전층(14), 제 7절연막(15), 저장전극용 제 3도전층(16)을 순차적으로 증착한 다음, 저장전극 콘택마스크용 제 1감광막패턴(20)을 형성한 단면도이다. 상기한 제6절연막(13)과 제7절연막(15)은 옥사이드로 형성할 수 있고, 상기 저장전극용 제1, 제2, 제3도전층(12,14,16)은 폴리실리콘으로 형성할 수 있다.The fourth insulating film 9 and the fifth insulating film 10 should be made of a material having a different etching selectivity from a predetermined wet etchant. 2B and 3B show a sixth insulating layer 13, a second conductive layer 14 for a storage electrode 14, a seventh insulating layer 15, and a third for a storage electrode on the first conductive charge 12 for the storage electrode. After the conductive layer 16 is sequentially deposited, the cross-sectional view of forming the first photoresist layer pattern 20 for the storage electrode contact mask is performed. The sixth insulating layer 13 and the seventh insulating layer 15 may be formed of oxide, and the first, second, and third conductive layers 12, 14, and 16 for the storage electrode may be formed of polysilicon. Can be.

제2C도 및 제3C도는 제1감광막패턴(20)을 마스크로 하여 저장전극용 제3도전층(16)과 제7절연막(15)을 순차적으로 건식식각한 다음, 제1감광막패턴(20)을 제거하고, 다시 저장전극 마스크용 제2감광막패턴(22)을 형성한 단면도이다.2C and 3C sequentially dry-etch the third conductive layer 16 and the seventh insulating layer 15 for the storage electrode using the first photoresist pattern 20 as a mask, and then the first photoresist pattern 20 Is a cross-sectional view of removing the second photoresist film pattern 22 for the storage electrode mask.

제2D도 및 제3D도는 제2감광막패턴(22)을 마스크로 하여 저장전극용 제3도전층(16), 제7절연막(15),저장전극용 제2도전층(14) 및 제6절연막(13)을 순차적으로 건식식각한 다음, 제2감광막패턴(22)을 제거하고, 제7절연막(15)과 제6절연막(13)을 습식식각하여 저장전극용 제2 및 제3도전층(14,16)의 가장자리에 언더컷이 발생되도록 한 것이다.2D and 3D show a third conductive layer 16 for a storage electrode, a seventh insulating layer 15, a second conductive layer 14 for a storage electrode 14 and a sixth insulating layer using the second photoresist pattern 22 as a mask. After sequentially etching (13), the second photoresist layer pattern 22 is removed, and the seventh insulating layer 15 and the sixth insulating layer 13 are wet-etched to form second and third conductive layers for storage electrodes ( 14, 16) undercut is generated on the edge.

제2E도 및 제3E도는 전체구조 상부에 저장전극용 제4도전층(17)을 증착하고, 블랜겟 건식식각(Blanket Etch Back)으로 제7절연막(15)이 노출되기까지 저장전극용 제4 및 제3도전층(17,14)을 건식식각하여 저장전극용 제4도전층 스페이서(17A)를 형성한 것으로 저장전극용 제2 및 제1도전층(14,12)이 저장전극용 제4도전층 스페이서(17A)에 의해 상호접속되고, 저장전극용 제4도전층 스페이서(17A)가 저장전극용 제2도전층(14) 상부에도 일부분 형성된 저장전극 패턴을 형성한 것이다.2E and 3E show the fourth conductive layer 17 for the storage electrode on the entire structure, and the fourth electrode for the storage electrode until the seventh insulating layer 15 is exposed by the blanket etch back. And dry etching the third conductive layers 17 and 14 to form a fourth conductive layer spacer 17A for the storage electrode, wherein the second and first conductive layers 14 and 12 for the storage electrode are the fourth for the storage electrode. The storage electrode pattern is interconnected by the conductive layer spacers 17A, and the fourth conductive layer spacers 17A for the storage electrodes are partially formed on the second conductive layer 14 for the storage electrodes.

제2F도 및 제3F도는 제5, 제6, 제7절연막(10,13,15)을 습식식각으로 완전히 제거하여, 저장전극(30) 표면을 노출시킨 것이다.2F and 3F completely remove the fifth, sixth, and seventh insulating layers 10, 13, and 15 by wet etching to expose the surface of the storage electrode 30.

제2G도 및 제3G도는 저장전극(30)의 표면에 캐패시터 유전체막(18)을 형성하고, 플레이트 전극용 도전층(19)을 형성한 것이다.2G and 3G show that a capacitor dielectric film 18 is formed on the surface of the storage electrode 30, and a conductive layer 19 for plate electrodes is formed.

상기한 본 발명에 의하면 디바이스의 집적도가 높아지고 단위셀의 면적이 축소됨에 따라서 64Mega디램급 이상의 고집적도 실현에 필수적인 0.4㎛ 이하로 사진식각 할 수 있는 기술과 더불어 좁은 면적에서 충분한 값의 용량을 확보할 수 있는 기술이다.According to the present invention, as the degree of integration of the device is increased and the unit cell area is reduced, the technology capable of photo-etching to 0.4 μm or less, which is essential for realizing high integration of 64 Mega DRAM or more, can secure sufficient capacity in a small area. It is a technology that can.

Claims (5)

디램의 스택 캐패시터 제조방법에 있어서, 실리콘기판에 MOSFET를 형성하고, 전체구조 상부에 제1, 제2, 제3절연막과 평탄화용 제4절연막을 형성하고 그 상부에 제5절연막을 형성하고, 그 상부에 저장전극용 제1도전층을 소오스/드레인에 콘택시켜 형성하는 단계와, 제1도전층 상부에 제6절연막, 저장전극용 제2도전층, 제7절연막 및 저장전극용 제3도전층을 적층하고, 저장전극 콘택상부의 제3도전층과 그하부의 제6절연막의 일정부분을 식각하는 단계와, 저장전극 마스크용 감광막 패턴을 이용하여 예정된 부분의 제3도전층, 제7절연막, 제2도전층, 제6절연막을 순차적으로 건식식각하여 패턴을 형성하고, 다시 제6, 제7절연층을 습식식각하여 제3 및 제2도전층의 가장자리 저부에 언더컷이 발생하도록 하는 단계와, 전체구조 상부에 저장전극용 제4도전층을 증착한 다음, 제7절연막과 제5절연막이 노출되기까지 블랜켓 건식식각으토 제4도전층과 노출되는 제3도전층을 식각하는 동시에 제1도전층을 식각하여 패턴을 형성하므로써 제4도전층 스페이서가 제1도전층 패턴과 제2도전층 패턴을 접속하고, 제2도전층패턴 상부에 제4도전층 스페이서가 형성된 저장전극 패턴을 형성하는 단계와, 제7절연막, 제6절연막을 완전히 습식식각하고, 제1도전층 하부의 제5절연막을 습식식각하여 저장전극의 표면을 노출시키는 단계와, 저장전극의 표면에 캐패시터 유전체막을 헝성하고, 그 상부에 플레이트 전극용 도전층을 증착하는 단계를 포함하는 스택 캐패시터 제조방법.In the DRAM stack capacitor manufacturing method, a MOSFET is formed on a silicon substrate, first, second and third insulating films and a fourth insulating film for planarization are formed on the entire structure, and a fifth insulating film is formed thereon. Forming a first conductive layer for the storage electrode by contacting the source / drain on the upper portion, a sixth insulating layer, a second conductive layer for the storage electrode, a seventh insulating layer, and a third conductive layer for the storage electrode on the first conductive layer Stacking and etching a predetermined portion of the third conductive layer on the storage electrode contact portion and the sixth insulating film on the lower portion thereof, and using the photosensitive film pattern for the storage electrode mask, the third conductive layer, the seventh insulating film, Dry etching the second conductive layer and the sixth insulating layer sequentially to form a pattern, and then wet etching the sixth and seventh insulating layers to undercut the edges of the third and second conductive layers; A fourth conductive layer for storage electrodes is placed on the entire structure Then, the fourth conductive layer spacer is formed by etching the fourth conductive layer and the third conductive layer exposed through the blanket dry etching to form the pattern by etching the first conductive layer until the seventh insulating layer and the fifth insulating layer are exposed. (A) connecting the first conductive layer pattern to the second conductive layer pattern, forming a storage electrode pattern having a fourth conductive layer spacer formed on the second conductive layer pattern, and completely wet etching the seventh insulating layer and the sixth insulating layer. And wet etching the fifth insulating layer under the first conductive layer to expose the surface of the storage electrode, forming a capacitor dielectric layer on the surface of the storage electrode, and depositing a conductive layer for a plate electrode thereon. Stack capacitor manufacturing method. 제1항에 있어서, 상기 평탄화용 절연막과 제5절연막을 식각 선택비가 다른 물질로 형성되는 것을 특징으로 하는 스택 캐패시터 제조방법.The method of claim 1, wherein the planarization insulating layer and the fifth insulating layer are formed of a material having a different etching selectivity. 제1항에 있어서, 상기 저장전극 콘택상부의 제3도전층과 제6절연막의 일정부분을 제거하기 위해서 저장전극 콘택 마스크용 제1감광막 패턴을 이용하는 것을 특징으로 하는 스택 캐패시터 제조방법.The method of claim 1, wherein the first photoresist pattern for the storage electrode contact mask is used to remove a portion of the third conductive layer and the sixth insulating layer on the storage electrode contact. 제1항에 있어서, 상기 제5, 제6, 제 7절연막은 산화막으로 형성하는 것을 특징으로 하는 스택 캐패시터 제조방법.The method of claim 1, wherein the fifth, sixth, and seventh insulating layers are formed of an oxide film. 제1항에 있어서, 상기 저장전극용 제1, 제2, 제3도전층은 폴리실리콘으로 형성하는 것을 특징으로 하는 스택 캐패시터 제조방법.The method of claim 1, wherein the first, second, and third conductive layers for the storage electrodes are formed of polysilicon.
KR1019930004556A 1993-03-24 1993-03-24 Stacked capacitor fabrication process KR960006721B1 (en)

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