KR960003800A - 디엔의 수소첨가에 유용한 촉매 조성물 - Google Patents

디엔의 수소첨가에 유용한 촉매 조성물 Download PDF

Info

Publication number
KR960003800A
KR960003800A KR1019950020592A KR19950020592A KR960003800A KR 960003800 A KR960003800 A KR 960003800A KR 1019950020592 A KR1019950020592 A KR 1019950020592A KR 19950020592 A KR19950020592 A KR 19950020592A KR 960003800 A KR960003800 A KR 960003800A
Authority
KR
South Korea
Prior art keywords
pref
composition
feed
alkali metal
monoolefin
Prior art date
Application number
KR1019950020592A
Other languages
English (en)
Other versions
KR100379568B1 (ko
Inventor
피이터 츙 틴-택
엠 존슨 마빈
Original Assignee
제이 이이 휘립프스
휘립프스 피트로오리암 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 제이 이이 휘립프스, 휘립프스 피트로오리암 캄파니 filed Critical 제이 이이 휘립프스
Publication of KR960003800A publication Critical patent/KR960003800A/ko
Application granted granted Critical
Publication of KR100379568B1 publication Critical patent/KR100379568B1/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C07C5/05—Partial hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/66—Silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/12—Fluorides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

디올레핀 수소첨가 촉매로서 효과적인 지지된 촉매 조성물은 팔라듐, 은 및 플루오르화 알칼리 금속으로 구성된다. 상기 촉매 조성물은 수소 기체로 C4－C10디올레핀 (바람직하게 1,3－부타디엔)을 상응하는 모노올레핀으로 선택적으로 수소첨가시키는 데 사용된다.

Description

디엔의 수소첨가에 유용한 촉매 조성물.
내용없음

Claims (21)

  1. (a) 팔라듐 금속 또는 팔라듐 화합물인 하나 이상의 팔라듐－함유물질, (b)은 금속 또는 은 화합물인 하나 이상의 은－함유 물질, (c) 하나 이상의 플루오르화 알칼리 금속, 및 (d) 하나 이상의 무기 지지 물질로 구성된 디엔의 수소첨가제 유용한 촉매 조성물.
  2. 제1항에 있어서, 상기 하나 이상의 무기 지지 물질이 알루미나, 실라카, 티타니아, 지르코니아, 알루미노규산염, 알루민산 아연, 티탄산 아연, 또는 상기 무기 지지 물질의 임의의 2개 이상의 혼합물인 조성물.
  3. 제2항에 있어서, 상기 하나 이상의 무기 지지 물질이 알루미나인 조성물.
  4. 제1항에 있어서, 상기 알칼리 금속이 칼륨인 조성물.
  5. 제1－4항 중 임의의 한 항에 있어서, 약 0.01－2중량% 팔라듐, 약 0.02－10중량% 은, 및 약 0.05－10중량% 알칼리 금속을 포함한 조성물.
  6. 제5항에 있어서, 약 0.05－0.6중량% 팔라듐, 약 0.1－5중량% 은, 및 약 0.2－5중량% 알칼리 금속을 포함한 조성물.
  7. 제1－4항 중 임의의 한 항에 있어서, 은 대 팔라듐의 중량－비가 약 2:1－약 10:1인 조성물.
  8. 제1－4항 중 임의의 한 항에 있어서, 상기 조성물이 약 1－10㎜의 입자 크기 및 약 1－200㎡/g의 표면적을 갖는 조성물.
  9. (i) (a), (b) 및 (d) 성분으로 구성된 고체 물질에 하나 이상의 플루오르화 알칼리 금속으로 구성된 용액을 상기 물질에 상기 하나 이상의 플루오르화 알칼리 금속 약 0.05－10을 혼입시키도록 하는 주입 조건하에 주입시키고, (ⅱ) 이렇게 주입된 고체 물질을 건조시키고, (ⅲ) 약 300－600℃의 온도에서 건조된 고체 물질을 하소시켜 제조한 조성물.
  10. 제9항에 있어서, (a), (b) 및 (d) 성분으로 구성된 상기 고체 물질이 약 0.01－2중량% Pd 및 약 0.02－10중량% Ag를 함유하고, 표면적 약 1－200㎡/g을 갖는 조성물.
  11. 수소 기체로 분자 당 4－10개의 탄소원자를 함유한 디올레핀을 분자당 4－10개의 탄소원자를 함유한 모노올레핀으로 선택적으로 수소 첨가시키는 방법으로서, 적합한 반응 조건하에서, 제1－4항 중 임의의 한 항에 따른 촉매 조성물과, 하나 이상의 디올레핀으로 구성된 탄화수소 공급물을 접촉시켜, 하나 이상의 모노올레핀을 생성하는 것으로 구성되는 방법.
  12. 제11항에 있어서, 하나 이상의 디올레핀이 분자당 4－6개의 탄소원자를 함유하고, 하나 이상의 모노올레핀이 분자당 4－6개의 탄소원자를 함유하는 방법.
  13. 제11항에 있어서, 디올레핀이 약 0.01－70몰%의 농도로 공급물 내 존재하는 방법.
  14. 제11항에 있어서, 상기 공급물이 부가로 하나 이상의 모노올레핀을 포함하는 액체 공급물인 방법.
  15. 제14항에 있어서, 상기 액체 공급물내 상기 모노올레핀이 분자당 4－6개의 탄소원자를 함유하는 방법.
  16. 제15항에 있어서, 상기 모노올레핀이 부텐인 방법.
  17. 제14항에 있어서, 상기 공ㄱ브물이 주로 상기 모노올레핀 및 약 0.01－10중량% 상기 디올레핀을 함유하는 방법.
  18. 제11항에 있어서, 상기 하나 이상의 디올레핀이 1,3－부타디엔인 방법.
  19. 제18항에 있어서, 상기 공급물 내 존재하는 1,3－부타디엔 각각 몰 당 약 1－2 몰의 수소를 사용하는 방법.
  20. 제11항에 있어서, 상기 적합한 반응 조건이 약 35－100℃ 범위내 온도, 및 50－100psig 범위내 압력을 포함하는 방법.
  21. 제11항에 있어서, 상기 공급물이 시간당 촉매 조성물 리터 당 약 3－100 리터인 시간당 액체 공간 속도를 갖는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950020592A 1994-07-19 1995-07-13 디엔의수소첨가반응에유용한촉매조성물 KR100379568B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/277,056 US5475173A (en) 1994-07-19 1994-07-19 Hydrogenation process and catalyst therefor
US08/277056 1994-07-19
US08/277,056 1994-07-19

Publications (2)

Publication Number Publication Date
KR960003800A true KR960003800A (ko) 1996-02-23
KR100379568B1 KR100379568B1 (ko) 2003-08-06

Family

ID=23059220

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950020592A KR100379568B1 (ko) 1994-07-19 1995-07-13 디엔의수소첨가반응에유용한촉매조성물

Country Status (10)

Country Link
US (2) US5475173A (ko)
EP (1) EP0693315B1 (ko)
JP (1) JP3866309B2 (ko)
KR (1) KR100379568B1 (ko)
AT (1) ATE306321T1 (ko)
AU (1) AU669316B2 (ko)
CA (1) CA2152194C (ko)
DE (1) DE69534507T2 (ko)
ES (1) ES2248794T3 (ko)
MY (1) MY129216A (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100754010B1 (ko) * 2005-11-16 2007-09-03 한국광기술원 발광다이오드 어레이의 광학 및 열 특성 측정 시스템과 이를 이용한 제어방법

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5583274A (en) * 1995-01-20 1996-12-10 Phillips Petroleum Company Alkyne hydrogenation process
US5587348A (en) * 1995-04-19 1996-12-24 Phillips Petroleum Company Alkyne hydrogenation catalyst and process
US6054409A (en) * 1995-06-06 2000-04-25 Institut Francais Du Petrole Selective hydrogenation catalyst and a process using that catalyst
DE19535402A1 (de) * 1995-09-23 1997-03-27 Basf Ag Palladium-haltiger Trägerkatalysator zur selektiven katalytischen Hydrierung von Acetylen in Kohlenwasserstoffströmen
AU692723B2 (en) * 1996-02-01 1998-06-11 Phillips Petroleum Company Catalyst composition and process for selecting hydrogenation of diolefins
US6096933A (en) * 1996-02-01 2000-08-01 Phillips Petroleum Company Hydrocarbon hydrogenation and catalyst therefor
DE19636064A1 (de) * 1996-09-05 1998-03-12 Basf Ag Verfahren zur Hydrierung
AU696631B2 (en) * 1996-10-30 1998-09-17 Phillips Petroleum Company Catalyst composition useful for hydrogenating unsaturated hydrocarbons
US6127310A (en) * 1997-02-27 2000-10-03 Phillips Petroleum Company Palladium containing hydrogenation catalysts
US5914433A (en) * 1997-07-22 1999-06-22 Uop Lll Process for producing polymer grade olefins
DE19839459A1 (de) 1998-08-29 2000-03-02 Basf Ag Katalysator und Verfahren zur Selektivhydrierung ungesättigter Verbindungen in Kohlenwasserstoffströmen
DE19840372A1 (de) * 1998-09-04 2000-03-09 Basf Ag Katalysator und Verfahren zur Reinigung von Stoffströmen
US6127588A (en) * 1998-10-21 2000-10-03 Phillips Petroleum Company Hydrocarbon hydrogenation catalyst and process
US6417136B2 (en) * 1999-09-17 2002-07-09 Phillips Petroleum Company Hydrocarbon hydrogenation catalyst and process
US6369000B1 (en) 1999-09-17 2002-04-09 Phillips Petroleum Company Process for producing a metal aluminate catalyst support
DE19959064A1 (de) * 1999-12-08 2001-06-13 Basf Ag Trägerkatalysator zur Selektivhydrierung von Alkinen und Dienen
DE10048219A1 (de) * 2000-02-10 2002-04-11 Sued Chemie Ag Katalysator für die Hydrierung von ungesättigten Kohlenwasserstoffen
US6303839B1 (en) 2000-06-14 2001-10-16 Uop Llc Process for producing polymer grade olefins
US6465391B1 (en) * 2000-08-22 2002-10-15 Phillips Petroleum Company Selective hydrogenation catalyst and processes therefor and therewith
JP3798949B2 (ja) 2001-03-06 2006-07-19 エヌ・イーケムキャット株式会社 水素化分解用触媒
US6509292B1 (en) 2001-03-30 2003-01-21 Sud-Chemie Inc. Process for selective hydrogenation of acetylene in an ethylene purification process
US6734130B2 (en) 2001-09-07 2004-05-11 Chvron Phillips Chemical Company Lp Hydrocarbon hydrogenation catalyst composition, a process of treating such catalyst composition, and a process of using such catalyst composition
EP1323700B1 (en) * 2001-12-28 2007-08-22 Mitsubishi Gas Chemical Company, Inc. process for producing hydrogenated aromatic polycarboxylic acid and process for producing hydrogenated aromatic polycarboxylic anhydride
MY137042A (en) * 2002-06-14 2008-12-31 Chevron Phillips Chemical Co Hydrogenation palladium-silver catalyst and methods
US20040192983A1 (en) * 2003-02-18 2004-09-30 Chevron Phillips Chemical Co. Acetylene hydrogenation catalyst with segregated palladium skin
US20040260131A1 (en) * 2003-06-23 2004-12-23 Chevron Phillips Chemical Company ("Cpchem") Selective hydrocarbon hydrogenation catalyst and process
US20050096217A1 (en) * 2003-10-29 2005-05-05 Sud-Chemie, Inc. Selective hydrogenation catalyst
US7141709B2 (en) * 2003-11-13 2006-11-28 Chevron Phillips Chemical Company Lp Methods and systems of producing monoolefins by the extraction-hydrogenation of highly unsaturated hydrocarbons
US7199076B2 (en) * 2003-12-19 2007-04-03 Chevron Phillips Chemical Company Lp Methods of making and using a selective hydrogenation catalyst
US7745372B2 (en) 2003-12-22 2010-06-29 China Petroleum & Chemical Corporation Catalyst for selective hydrogenation of olefins and its preparation as well as use
US20060166816A1 (en) * 2004-06-23 2006-07-27 Catalytic Solutions, Inc. Catalysts and processes for selective hydrogenation of acetylene and dienes in light olefin feedstreams
US7521393B2 (en) * 2004-07-27 2009-04-21 Süd-Chemie Inc Selective hydrogenation catalyst designed for raw gas feed streams
DE102004049940A1 (de) * 2004-10-13 2006-04-20 Basf Ag Verfahren zur Herstellung eines C4-Olefin-Gemisches durch Selektivhydrierung und Metatheseverfahren zur Verwendung dieses Stroms
CN101146614A (zh) * 2005-01-20 2008-03-19 苏德-化学公司 加氢催化剂
SG164387A1 (en) 2005-07-27 2010-09-29 Chevron Phillips Chemical Co A selective hydrogenation catalyst and methods of making and using same
US8173574B2 (en) * 2006-09-20 2012-05-08 Basf Corporation Catalysts to reduce NOx in an exhaust gas stream and methods of preparation
US7759280B2 (en) * 2006-09-20 2010-07-20 Basf Corporation Catalysts, systems and methods to reduce NOX in an exhaust gas stream
US7943548B2 (en) * 2006-09-20 2011-05-17 Basf Corporation Catalysts to reduce NOx in an exhaust gas stream and methods of preparation
FR2909571B1 (fr) * 2006-12-11 2009-10-02 Inst Francais Du Petrole Catalyseur prepare par impregnation d'une solution aqueuse contenant des particules oxy(hydroxy)de d'un cation en interaction avec une espece moleculaire d'un metal du groupe viii
JP2010013363A (ja) * 2008-07-01 2010-01-21 Uop Llc 層状触媒組成物を使用する選択的水素化法および前記触媒の調製
EP2140935A1 (en) * 2008-07-04 2010-01-06 Uop Llc Selective hydrogenation process using layered catalyst composition and preparation of said catalyst
SG10201400330QA (en) 2009-03-04 2014-05-29 Chevron Phillips Chemical Co Selective hydrogenation catalyst and methods of making and using same
US20110054227A1 (en) * 2009-08-26 2011-03-03 Chevron Phillips Chemical Company Lp Process to Protect Hydrogenation and Isomerization Catalysts Using a Guard Bed
CN102728351B (zh) * 2011-04-11 2014-12-17 中国石油化工股份有限公司 用于裂解汽油或其馏分选择性加氢的钯-银/氧化铝-氧化钛催化剂及其制备方法
WO2012141783A1 (en) * 2011-04-13 2012-10-18 Amyris, Inc. Olefins and methods for making the same
US9511359B2 (en) * 2014-11-14 2016-12-06 Chevron Phillips Chemical Company Lp Selective hydrogenation catalyst and methods of making and using same
CN105709786B (zh) * 2014-12-04 2018-02-09 中国石油化工股份有限公司 一种丁二烯选择性加氢、1‑丁烯异构催化剂及其制备方法和应用
US9758446B2 (en) 2015-11-16 2017-09-12 Chevron Phillips Chemical Company Lp Selective hydrogenation using a flow index
US20240034699A1 (en) 2022-07-28 2024-02-01 Chevron Phillips Chemical Company, Lp Flexible Benzene Production Via Selective-Higher-Olefin Oligomerization of Ethylene

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3932548A (en) * 1972-10-26 1976-01-13 Universal Oil Products Company Dehydrogenation method and multimetallic catalytic composite for use therein
FR2366950A1 (fr) * 1976-03-01 1978-05-05 Peugeot Dispositif de commande d'accessoires entraines par le moteur d'un vehicule a direction assistee
FR2416210A1 (fr) * 1978-02-03 1979-08-31 Inst Francais Du Petrole Procede de desalkylation a la vapeur d'eau d'hydrocarbures alkylaromatiques
FR2482953A1 (fr) * 1980-05-22 1981-11-27 Inst Francais Du Petrole Procede d'hydrogenation selective d'une di-olefine dans un melange d'hydrocarbures renfermant au moins 4 atomes de carbone et contenant une olefine -a
FR2619391B1 (fr) * 1987-08-14 1990-01-12 Eurecat Europ Retrait Catalys Procede de reduction d'un catalyseur de raffinage avant sa mise en oeuvre
FR2642670B1 (fr) * 1989-02-07 1991-05-24 Eurecat Europ Retrait Catalys Procede de reduction d'un catalyseur de raffinage avant sa mise en oeuvr
US5208405A (en) * 1992-03-03 1993-05-04 Phillips Petroleum Company Selective hydrogenation of diolefins
US5488024A (en) * 1994-07-01 1996-01-30 Phillips Petroleum Company Selective acetylene hydrogenation

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100754010B1 (ko) * 2005-11-16 2007-09-03 한국광기술원 발광다이오드 어레이의 광학 및 열 특성 측정 시스템과 이를 이용한 제어방법

Also Published As

Publication number Publication date
CA2152194C (en) 1999-03-02
DE69534507T2 (de) 2006-07-27
MY129216A (en) 2007-03-30
US5489565A (en) 1996-02-06
CA2152194A1 (en) 1996-01-18
DE69534507D1 (de) 2006-02-23
ES2248794T3 (es) 2006-03-16
EP0693315B1 (en) 2005-10-12
US5475173A (en) 1995-12-12
EP0693315A1 (en) 1996-01-24
JP3866309B2 (ja) 2007-01-10
KR100379568B1 (ko) 2003-08-06
JPH0866633A (ja) 1996-03-12
ATE306321T1 (de) 2005-10-15
AU2176895A (en) 1996-02-01
AU669316B2 (en) 1996-05-30

Similar Documents

Publication Publication Date Title
KR960003800A (ko) 디엔의 수소첨가에 유용한 촉매 조성물
AU692723B2 (en) Catalyst composition and process for selecting hydrogenation of diolefins
US6096933A (en) Hydrocarbon hydrogenation and catalyst therefor
KR101039453B1 (ko) 수소화 반응 팔라듐-은 촉매 및 그 제조 방법
US7038096B2 (en) Hydrocarbon hydrogenation catalyst composition, a process of treating such catalyst composition, and a process of using such catalyst composition
KR970014834A (ko) 탄화수소 스트림 내 아세틸렌의 선택적 접촉 수소화에 사용되는 지지된 팔라듐 촉매
KR830006148A (ko) 디 올레핀을 선택적으로 수소화하는 방법
WO2001023087A8 (en) Hydrocarbon hydrogenation catalyst and process
CA2529940A1 (en) Selective hydrocarbon hydrogenation catalyst and process
AU3969301A (en) Hydrocarbon hydrogenation catalyst and process
KR970009880A (ko) 탈수소화 반응용 복합 금속 촉매 조성물 및 이의 제조방법
WO2000064846A1 (en) Hydrocarbon hydrogenation catalyst and process
TH20891B (th) สารผสมตัวเร่งปฏิกิริยาที่มีประโยชน์สำหรับการเติมไฮโดรเจนของไออีน
TH21830A (th) สารผสมตัวเร่งปฏิกิริยาที่มีประโยชน์สำหรับการเติมไฮโดรเจนของไออีน
MXPA96005852A (en) Catalytic composition and process to select the hydrogenation of diolefi
RU95100227A (ru) Катализатор для селективного гидрирования ацетиленовых и/или диеновых углеводородов и позиционной изомеризации олефинов и способ его приготовления

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20130312

Year of fee payment: 11

FPAY Annual fee payment

Payment date: 20140312

Year of fee payment: 12

EXPY Expiration of term