KR960001191A - 케라틴 섬유의 개질방법 - Google Patents

케라틴 섬유의 개질방법 Download PDF

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KR960001191A
KR960001191A KR1019950015328A KR19950015328A KR960001191A KR 960001191 A KR960001191 A KR 960001191A KR 1019950015328 A KR1019950015328 A KR 1019950015328A KR 19950015328 A KR19950015328 A KR 19950015328A KR 960001191 A KR960001191 A KR 960001191A
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keratin
transition metal
layer
salts
fibers
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KR1019950015328A
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KR100378232B1 (ko
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히로시 호조
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히로시 호조
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/28—Halides of elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
    • D06M11/62—Complexes of metal oxides or complexes of metal salts with ammonia or with organic amines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/45—Shrinking resistance, anti-felting properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Catalysts (AREA)

Abstract

모로 대표되는 케라틴 섬유의 개질방법이 기재되어 있다. 전이금속 염의 수용액 존재하에 기계적 힘을 케라틴 섬유에 인가하여 스케일(표피세포)중의 하부 케라틴 층부분의 구조를 약화 및 파괴하여 전이 금속이 하부 케라틴 층에 고농도로 국부적으로 도입될 수 있게 한다. 이어 케라틴 섬유를 과산화수소 및 일과황산과 같은 산화제를 함유하는 배드에 침적시킨다. 산화제는 전이금속의 촉매적 효과에 의해 분해된다. 분해에 의해 발생한 산소 가스의 압력 때문에, 케라틴 섬유상에 스케일인 케리틴 층이 박리된다. 따라서, 비-케라틴 단백질에 손상을 주지 않으면서 촉감이 좋지 않은 케라틴 부분을 제거할 수 있을 뿐터러 잔류 금속이 없는 개질 섬유를 제공할 수 있다. 높은 방축효과는 통상의 염소 화합물을 산화제로 사용하여서는 얻을 수 없는 것이다.

Description

케라틴 섬유의 개질방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. a) 몰 함량 감소, pH에서의 변화 또는 전이금속 이외의 금속 이온의 부가에 의해 표피세포에서 케라틴층과 비-케라틴 단백질 층의 기계적 특성의 차로 인하여 석출이 용이하게 생길 수 있는 전이금속 염의 수용액 존재하에서 케라틴 섬유에 기계적 힘을 인가하고, 케라틴 층의 내부에 결합된 하부 케라틴 층의 구조를 약화 및 파괴하여 전이금속 염 용액을 하부 케라틴 층에 도입하는 것을 포함하는 전이금속 염 함침 단계; b) 전이금속 염 용액의 물 함량을 감소시키고, 상기 용액의 pH를 변화시키거나, 또는 상이한 종류의 금속염의 이온을 부가하여 하부-케라틴 층에서 산화반응용 촉매를 석출 및 분산시키는 것을 포함하는 촉매 형성 단계; 및 c) 산화제를 전이금속의 촉매 효과하에서 케라틴 섬유와 반응시켜 하부 케란틴 층에서 신속한 반응을 유발하여 케라틴 층이 하부 케라틴 층으로부터 제거될 수 있고 또 비-케라틴 단백질 층이 노출될 수 있게 하는 케라틴층 제거단계를 포함하는 케라틴 섬유의 개질방법.
  2. 제1항에 있어서, 상기 케라틴 섬유가 모인 개질방법.
  3. 제1항에 있어서, Cu, Fe, Ni, Co, Mn, Cr 및 Zn으로 구성된 군으로부터 선정된 한 개 이상의 전이금속으로 사용되는 개질방법.
  4. 제1항에 있어서, 일과황산 및 그의 염, 이과황산 및 그의 염, 과황산 수소, 과산화수소, 과포름산 및 과아세트산 및 그의 염으로 구성된 군으로부터 선정된 한 개 이상의 화합물이 산화제로 사용되는 개질방법.
  5. 제4항에 있어서, 상기 산화반응이 pH 7.5 내지 10.5 범위의 알칼리성 수용액중에서 실시되는 개질방법.
  6. 제4항에 있어서, 과산화 수소 및 산화적 산이 산화제로 사용되는 개질방법.
  7. 제1항에 있어서, 상기 촉매 형성 단계가 고농도의 강한 전기분해 중성염 존재하에서 실행되어 비-케라틴 단백질 부분의 팽윤을 억제하는 개질방법.
  8. 제7항에 있어서, 무기산의 나트륨염 및 칼륨염 중의 한 개가 포화 또는 포화에 가까운 농도로 강한 전기분해 중성 염으로 사용되는 개질방법.
  9. 제1항에 있어서, 상기 전이 금속염의 수용액이 수용액의 방울이 유기 용매에 분산된 형태로 사용되는 개질방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950015328A 1994-06-07 1995-06-07 케라틴섬유의개질방법 KR100378232B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP94-125092 1994-06-07
JP12509294 1994-06-07
JP29350294 1994-11-28
JP94-293502 1994-11-28
JP07863395A JP3338975B2 (ja) 1994-06-07 1995-04-04 ケラチン繊維の改質方法
JP95-78633 1995-04-04

Publications (2)

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KR960001191A true KR960001191A (ko) 1996-01-25
KR100378232B1 KR100378232B1 (ko) 2003-05-27

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US (1) US5824113A (ko)
EP (1) EP0687764A3 (ko)
JP (1) JP3338975B2 (ko)
KR (1) KR100378232B1 (ko)
CN (1) CN1066504C (ko)
AU (1) AU682103B2 (ko)
CA (1) CA2150630A1 (ko)
NZ (1) NZ272252A (ko)

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US6783546B2 (en) 1999-09-13 2004-08-31 Keraplast Technologies, Ltd. Implantable prosthetic or tissue expanding device
CN100352997C (zh) * 2003-12-10 2007-12-05 上海生大针织绒有限公司 易健康、易护理、环保的羊毛的制备方法
RU2008108977A (ru) * 2005-08-10 2009-09-20 Перакем Лимитед (Gb) Усовершенствования, связанные с обработкой шерсти и относящиеся к ней
WO2010132673A1 (en) 2009-05-13 2010-11-18 Keraplast Technologies, Ltd. Biopolymer materials
WO2012007781A1 (en) * 2010-07-15 2012-01-19 Charishma Mohini Wickremesinghe A natural fibre bra cup - solution and method of construction
CN101942734A (zh) * 2010-07-21 2011-01-12 江苏倪家巷集团精毛纺织有限公司 3e-WOOL羊毛涤纶羊绒蚕丝哔叽的生产方法
CN102453993B (zh) * 2010-10-20 2013-12-11 上海中纺物产发展有限公司 Ew纱线的生产方法
CN102453992B (zh) * 2010-10-20 2014-03-26 上海中纺物产发展有限公司 Esta纱线的生产方法
US9162002B2 (en) 2011-08-19 2015-10-20 Empire Technology Development Llc Cationic fibers hosting reactive peroxygenated radicals, and methods of making and using them
CN102995393B (zh) * 2012-11-15 2014-09-17 浙江中新毛纺织有限公司 全面易护理羊毛条的制备方法及其产品
CN103820991B (zh) * 2014-01-23 2015-09-23 浙江神州毛纺织有限公司 一种羊毛表面催化氧化改性方法
CN105646696A (zh) * 2016-01-14 2016-06-08 四川大学 牛毛角蛋白粉剂及其制备方法
CN109092264B (zh) * 2018-08-30 2021-06-15 西安工程大学 一种固体脱色剂的制备方法
CN109355950A (zh) * 2018-10-15 2019-02-19 江苏阳光毛纺服装技术开发有限公司 一种羊毛织物染色前处理方法

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Publication number Priority date Publication date Assignee Title
CA560134A (en) * 1958-07-08 A. Florio Patrick Process for treating keratinaceous fibers
BE473751A (ko) * 1946-07-24
JPS56140164A (en) * 1980-03-27 1981-11-02 Hiroshi Houjiyou Modification of animal fibrous material by scale peeling
JPH0482561A (ja) * 1990-07-26 1992-03-16 Niigata High Supinaa Kk 創傷被覆材

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Publication number Publication date
CN1119229A (zh) 1996-03-27
EP0687764A2 (en) 1995-12-20
KR100378232B1 (ko) 2003-05-27
JPH08209532A (ja) 1996-08-13
AU682103B2 (en) 1997-09-18
EP0687764A3 (en) 1997-10-08
JP3338975B2 (ja) 2002-10-28
CN1066504C (zh) 2001-05-30
AU2049595A (en) 1995-12-14
NZ272252A (en) 1996-07-26
US5824113A (en) 1998-10-20
CA2150630A1 (en) 1995-12-08

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