KR950702215A - 폴리옥시알킬렌 및 치환 숙신산 무수물로부터 유도된 계면활성제(surfactants derived from polylxyalkylenes and substituted succinic anhydrides) - Google Patents
폴리옥시알킬렌 및 치환 숙신산 무수물로부터 유도된 계면활성제(surfactants derived from polylxyalkylenes and substituted succinic anhydrides)Info
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- KR950702215A KR950702215A KR1019940704735A KR19940704735A KR950702215A KR 950702215 A KR950702215 A KR 950702215A KR 1019940704735 A KR1019940704735 A KR 1019940704735A KR 19940704735 A KR19940704735 A KR 19940704735A KR 950702215 A KR950702215 A KR 950702215A
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- hydrogen
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- 239000004094 surface-active agent Substances 0.000 title abstract 3
- 150000008064 anhydrides Chemical class 0.000 title 1
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical class O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 title 1
- 125000003342 alkenyl group Chemical group 0.000 claims abstract 7
- 125000000217 alkyl group Chemical group 0.000 claims abstract 6
- 210000002268 wool Anatomy 0.000 claims abstract 3
- 239000000839 emulsion Substances 0.000 claims abstract 2
- -1 succinic anhydride Amides Chemical class 0.000 claims abstract 2
- 150000001875 compounds Chemical class 0.000 claims 14
- 229910052739 hydrogen Inorganic materials 0.000 claims 7
- 239000001257 hydrogen Substances 0.000 claims 7
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 4
- 150000001768 cations Chemical class 0.000 claims 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- 239000004166 Lanolin Substances 0.000 claims 2
- 235000019388 lanolin Nutrition 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 239000007762 w/o emulsion Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 239000008346 aqueous phase Substances 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 238000007865 diluting Methods 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229920002401 polyacrylamide Polymers 0.000 abstract 1
- 238000009991 scouring Methods 0.000 abstract 1
- 229940014800 succinic anhydride Drugs 0.000 abstract 1
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- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/22—Amides or hydrazides
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- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F20/56—Acrylamide; Methacrylamide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
- C08G65/332—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/333—Polymers modified by chemical after-treatment with organic compounds containing nitrogen
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/16—Amines or polyamines
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/34—Higher-molecular-weight carboxylic acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B11/00—Recovery or refining of other fatty substances, e.g. lanolin or waxes
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/08—Polycarboxylic acids containing no nitrogen or sulfur
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/528—Carboxylic amides (R1-CO-NR2R3), where at least one of the chains R1, R2 or R3 is interrupted by a functional group, e.g. a -NH-, -NR-, -CO-, or -CON- group
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01C—CHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
- D01C3/00—Treatment of animal material, e.g. chemical scouring of wool
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- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
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- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/24—Homopolymers or copolymers of amides or imides
- C08J2333/26—Homopolymers or copolymers of acrylamide or methacrylamide
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- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
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Abstract
본 발명은 식중, R, R1, A, A1, Y, R2,m,n, 및p는 정의된 바와같고, 특히 알킬(알케닐) 그룹이 C14-C22그룹인 하기식 (Ⅰ) Y.A1.OC.(HR)C.C(HR1).CO.A.(CmH2mO)n.R2및 (Ⅱ) Y.A1.OC.(HR)C.C(HR1).CO.A.(CmH2mO)n.CpH2p.A.CO.(HR1)C.C(HR)CO.A1.Y의 폴리옥시알킬렌 에스테르와 알킬(알케닐) 숙신산 무수물의 아미드는 효과적인 계면활성제이다. 이들은 특히 놀랍게도 알킬(알케닐) 그룹 쇄 길이가 증가할 수록 운점이 상승하기 때문에 특히 주목할만하다. 당해 계면활성제는 울 정련과 폴리아크릴아미드를 유중수 에멀션을 물로 전화시키는데 효과적이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- 하기식 (Ⅰ) 또는 (Ⅱ)의 화합물.Y.A1.OC.(HR)C.C(HR1).CO.A.(CmH2mO)n.R2(I)식중, R과 R1중 하나는 C6-C22알케닐 또는 알킬이고 다른 하나는 수소; A는 -0- 또는 -NR4- (R4는 수소 또는 C1-C6알킬);n은 2내지 100;m은 2 또는 3(폴리옥시알킬렌 쇄에 따라 다양할 수 있음); R2는 수소 또는 C1-C6알킬; A1은 -0-, -O- 또는 -NR4- (R4는 수소 또는 C1-C5알킬); A1이 -0- 인 경우 : Y는 양이온; 및 A1이 -0- 또는 -NR4- 인 경우 : Y는 C1내지 C6알킬 그(R3) 또는 식(CmH2mO)n.R2의 그룹(m,n및 독립적으로 상술한 바와같음); 단, A가 -0-이거나 A1이 -0-인 경우 그룹 R, R1및 임의의 그룹 R2및 R3내의 총 탄소원자수는 최소한 13임.또는 Y.A1.OC.(HR)C.C(HR1).CO.A.(CmH2mO)n.CpH2p.A.CO.(HR1)C.C(HR)CO.A1.Y (Ⅱ)식중,m,n및 각각의 R, R1, A, A1및 Y는 독립적으로 상술한 바와같고;p는 2도는 3임.
- 제1항에 있어서, R과 R1중 하나는 C14-C22알케닐 또는 알킬이고 나머지 하나는 수소인 화합물.
- 제1항에 있어서, 하기식(Ia)의 화합물.(Ia) Y.-OOC.(HR)C.C(HR1).COO.(CmH2mO)n,R2식중,m, n는 제1항에서 정의한 바와같고; Y는 양이온이며; R과 R1중 하나는 C14내지 C22알케닐 또는 알킬 그룹이고 나머지는 수소임.
- 제1항에 있어서, 하기식 (Ib)의 화합물.(Ib) Y.-OOC.(HR)C.C(HR1).COO.(CmH2mO)n,R2식중, R, R1,m, n는 제1항에서 정의한 바와같고; Y는 C1-C6알킬 그룹 또는 식((CHmH2mO)n.R2의 그룹(식m, n및 R2는 독립적으로 제1항에서 정의한 바와같음.
- 제1항에 있어서, 하기식(Ic)의 화합물.(Ic) Y.-OOC.(HR)C.C(HR1).CO.NH.(CmH2mO)n,R2식중, R, R1,m, n및 R2는 제1항에서 정의한 바와같고; Y는 양이온임.
- 제1항에 있어서, 하기식(Id)의 화합물.(Id) Y.-OOC.(HR)C.C(HR1).CO.NH.(CmH2mO)n,R2식중, R 및 R1과 각각의m, n및 R2는 독립적으로제1항에서 정의한 바와 같음.
- 제4항 내지 제6항중 어느 한 항에 있어서, R과 R1중 하나는 C14-C22알케닐 그룹이고 나머지 하나는 수소인 화합물.
- 제1항 내지 제7항중 어느 한 항에 있어서,m은 2;p는 만일 존재한다면 2;n은 3내지 50 이고; Y는 H+, 알칼리금속 양이온, 또는 암모늄 양이온인 양이온이거나 메틸, 에틸 또는 부틸 그룹인 화합물.
- 제1항 내지 제8항중 어는 한 항에 정의된 바와같은 식(I) 또는 (Ⅱ)의 화합물을 유효량 포함하고있는 수성 믹스로 울왁스를 함유한 울을 세척하는 단계로 구성되는, 울 왁스를 제거하기위한 울 처리방법.
- 제9항에 있어서, 화합물은m은 2,n은 3내지 10, R2는 C1-C6알킬 그룹인 식(Ia)의 화합물인 방법.
- 제1항 내지 제8항중 어느 하나에 정의된 식(I) 또는 (Ⅱ)의 화합물을 유중수 에멀션에 포함시키는 단계 및 후속적으로 유증수 에멀션을 물로 희석시켜 전환시키는 단계로 구성되는, 폴리아크릴아미드를 수성상에 함유한 유중수 에멀션을 전화시키는 방법.
- 제11항에 있어서, 화합물인m은 2,n은 8내지 25, R2는 H 또는 C1-C6알킬 그룹인 화합물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB929213571A GB9213571D0 (en) | 1992-06-26 | 1992-06-26 | Surfactants |
GB9213571.4 | 1992-06-26 | ||
PCT/GB1993/001335 WO1994000508A1 (en) | 1992-06-26 | 1993-06-25 | Surfactants derived from polyoxyalkylenes and substituted succinic anhydrides |
Publications (1)
Publication Number | Publication Date |
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KR950702215A true KR950702215A (ko) | 1995-06-19 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR1019940704735A KR950702215A (ko) | 1992-06-26 | 1993-06-25 | 폴리옥시알킬렌 및 치환 숙신산 무수물로부터 유도된 계면활성제(surfactants derived from polylxyalkylenes and substituted succinic anhydrides) |
Country Status (15)
Country | Link |
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EP (1) | EP0647248A1 (ko) |
JP (1) | JPH07508546A (ko) |
KR (1) | KR950702215A (ko) |
AU (1) | AU679918B2 (ko) |
CA (1) | CA2139003A1 (ko) |
CZ (1) | CZ328094A3 (ko) |
FI (1) | FI946075A0 (ko) |
GB (2) | GB9213571D0 (ko) |
HU (1) | HUT68780A (ko) |
NZ (1) | NZ253297A (ko) |
RU (1) | RU2118641C1 (ko) |
SK (1) | SK159694A3 (ko) |
TW (1) | TW256854B (ko) |
WO (1) | WO1994000508A1 (ko) |
ZA (1) | ZA934479B (ko) |
Families Citing this family (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9317478D0 (en) * | 1993-08-23 | 1993-10-06 | Ici Plc | Surfactants |
GB9317476D0 (en) * | 1993-08-23 | 1993-10-06 | Ici Plc | Surfactants |
WO1995022896A1 (en) * | 1994-02-24 | 1995-08-31 | Imperial Chemical Industries Plc | Adjuvant compositions |
GB9424353D0 (en) * | 1994-12-02 | 1995-01-18 | Ici Plc | Surfactants |
DE19505100A1 (de) * | 1995-02-15 | 1996-08-22 | Basf Ag | Alk(en)yldicarbonsäurebisester, deren Verwendung sowie Verfahren zu deren Herstellung |
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RU2749613C2 (ru) | 2016-07-01 | 2021-06-16 | Крода, Инк. | Уменьшение сноса при опрыскивании |
JP6841610B2 (ja) * | 2016-07-15 | 2021-03-10 | 松本油脂製薬株式会社 | 洗浄剤組成物及び洗浄方法 |
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HU184618B (en) * | 1979-10-26 | 1984-09-28 | Chinoin Gyogyszer Es Vegyeszet | Surface active materials containing carboxyl group stable in hard water |
IL70368A (en) * | 1982-12-13 | 1987-11-30 | Chevron Res | Nonionic emulsifier and substituted succinic anhydride compositions therewith |
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US4968321A (en) * | 1989-02-06 | 1990-11-06 | Texaco Inc. | ORI-inhibited motor fuel composition |
-
1992
- 1992-06-26 GB GB929213571A patent/GB9213571D0/en active Pending
-
1993
- 1993-06-22 ZA ZA934479A patent/ZA934479B/xx unknown
- 1993-06-24 GB GB939313096A patent/GB9313096D0/en active Pending
- 1993-06-25 WO PCT/GB1993/001335 patent/WO1994000508A1/en not_active Application Discontinuation
- 1993-06-25 AU AU43505/93A patent/AU679918B2/en not_active Ceased
- 1993-06-25 SK SK1596-94A patent/SK159694A3/sk unknown
- 1993-06-25 NZ NZ253297A patent/NZ253297A/en unknown
- 1993-06-25 HU HU9403701A patent/HUT68780A/hu unknown
- 1993-06-25 EP EP93913432A patent/EP0647248A1/en not_active Withdrawn
- 1993-06-25 JP JP6502165A patent/JPH07508546A/ja active Pending
- 1993-06-25 CZ CZ943280A patent/CZ328094A3/cs unknown
- 1993-06-25 RU RU94046395A patent/RU2118641C1/ru active
- 1993-06-25 KR KR1019940704735A patent/KR950702215A/ko not_active IP Right Cessation
- 1993-06-25 CA CA002139003A patent/CA2139003A1/en not_active Abandoned
- 1993-06-26 TW TW082105101A patent/TW256854B/zh active
-
1994
- 1994-12-23 FI FI946075A patent/FI946075A0/fi unknown
Also Published As
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RU2118641C1 (ru) | 1998-09-10 |
WO1994000508A1 (en) | 1994-01-06 |
ZA934479B (en) | 1995-03-22 |
HUT68780A (en) | 1995-07-28 |
RU94046395A (ru) | 1996-11-20 |
JPH07508546A (ja) | 1995-09-21 |
GB9313096D0 (en) | 1993-08-11 |
AU4350593A (en) | 1994-01-24 |
NZ253297A (en) | 1997-02-24 |
TW256854B (ko) | 1995-09-11 |
SK159694A3 (en) | 1995-06-07 |
CZ328094A3 (en) | 1995-06-14 |
EP0647248A1 (en) | 1995-04-12 |
CA2139003A1 (en) | 1994-01-06 |
FI946075A (fi) | 1994-12-23 |
AU679918B2 (en) | 1997-07-17 |
FI946075A0 (fi) | 1994-12-23 |
GB9213571D0 (en) | 1992-08-12 |
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