KR950700121A - 배위 촉매 시스템(coordination catalyst system) - Google Patents

배위 촉매 시스템(coordination catalyst system)

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Publication number
KR950700121A
KR950700121A KR1019940702647A KR19940702647A KR950700121A KR 950700121 A KR950700121 A KR 950700121A KR 1019940702647 A KR1019940702647 A KR 1019940702647A KR 19940702647 A KR19940702647 A KR 19940702647A KR 950700121 A KR950700121 A KR 950700121A
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South Korea
Prior art keywords
catalyst system
coordination catalyst
coordination
independently
metathesis
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KR1019940702647A
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English (en)
Other versions
KR100240533B1 (ko
Inventor
폴 루드비히
포이츠 에이케
히르쉬 한스-루드비히
슈만 헤르베르트
바이스 카린
티엘레 칼-하인즈
Original Assignee
위르겐 호이만·라인하르트 슈틀러
메르크 파텐트 게젤샤프트 미트 베쉬랭크터 하프퉁
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Priority claimed from DE4240294A external-priority patent/DE4240294A1/de
Priority claimed from DE4306569A external-priority patent/DE4306569A1/de
Application filed by 위르겐 호이만·라인하르트 슈틀러, 메르크 파텐트 게젤샤프트 미트 베쉬랭크터 하프퉁 filed Critical 위르겐 호이만·라인하르트 슈틀러
Publication of KR950700121A publication Critical patent/KR950700121A/ko
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Publication of KR100240533B1 publication Critical patent/KR100240533B1/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0252—Nitrogen containing compounds with a metal-nitrogen link, e.g. metal amides, metal guanidides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
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    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/062—Al linked exclusively to C
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    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F38/00—Homopolymers and copolymers of compounds having one or more carbon-to-carbon triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
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    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/546—Metathesis reactions, e.g. olefin metathesis alkyne metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
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    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 배위 촉매 시스템중의 성분으로서 환상 유기금속 화합물의 용도, 상응하는 배위 촉매 시스템 및, 이러한 배위 촉매 시스템을 사용하는 알켄 및 알킨의 배위 중합체 의한 중합체의 제조방법 및 알켄 및 알킨의 접촉 복분해에 의한 불포화 탄화수소의 제조방법에 관한 것이다.

Description

배위 촉매 시스템(COORDINATION CATALYST SYSTEM)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 배위 촉매 시스템중의 성분으로서 하기 일반식(Ⅰ) 또는 (Ⅱ)의 환상 유기금속 화합물의 용도 :
    상기식에서, M은 B, Al, Ga 또는 In이고, X1, X2및 X3는 서로 독립적으로 CHR1, NR2, O, S이고, Y1및 Y2는 서로 독립적으로 -(CH2)m-,o-(CH|2)p-C6H4-(CH2)q-,o-(CH|2)p-C6H6-(CH2)q-,o-(CH2)p-C6H8-(CH|2)q-,o-(CH2)p-C6H10-(CH|2)q-,o-(CH2)p-C5H4-(CH|2)q-,o-(CH2)p-C5H6-(CH2)q-,o-(CH|2)p-C5H8-(CH2)q-, 또는 -(CH2)|p-CH=CH-(CH2)q-이고, Z는 NR3R4, PR3R4, OR5또는 SR5이고, R1은 H, OH, 할로겐, C1-6알킬 또는 C1-6-알콕시, C5-7-사이클로알킬 또는 페닐이고, R2, R3, R4및 R5는 서로 독립적으로 H 또는 C1-6알킬, C5-7-사이클로알킬 또는 페닐이거나, 또는 R3및 R4는 함께 C4-6-알킬렌 브릿지이고, m은 1내지 6이고, p 및 q는 각각의 경우에 서로 독립적으로 0 내지 2이고, Z'는 N 또는 P이고, a는 2 내지 4이고, b 및 c는 0또는 1이며, 단 b와 c의 합은 1이다.
  2. 제1항에 있어서, 알켄 및 알킨의 배위 중합 및 복분해를 위한 배위 촉매 시스템중에서의 용도.
  3. 하나이상의 일반식(Ⅰ) 또는 (Ⅱ)의 화합물을 함유함을 특징으로 하는 원소 주기율 표의 주그룹(Ⅲ)의 유기금속 화합물 및 부그룹(Ⅳ) 내지 (Ⅷ)의 전이금속 화합물을 기초로 하는 배위 촉매 시스템.
  4. 제3항에 따른 배위 촉매 시스템을 사용함을 특징으로 하는 알켄 및/또는 알킨의 배위 중합에 의해 중합체들을 제조하는 방법.
  5. 제3항에 따른 배위 촉매 시스템을 복분해 촉매로서 사용함을 특징으로 하는 알켄 또는 알킨의 접촉 복분해 반응에 의해 불포화 탄화수소 화합물을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940702647A 1992-12-01 1993-11-16 배위촉매시스템 KR100240533B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DEP4240294.8 1992-12-01
DE4240294A DE4240294A1 (de) 1992-12-01 1992-12-01 Koordinations-Katalysatorsysteme
DE4306569A DE4306569A1 (de) 1993-03-03 1993-03-03 Koordinations-Katalysatorsysteme
DEP4306569.4 1993-03-03
PCT/EP1993/003204 WO1994012278A1 (de) 1992-12-01 1993-11-16 Koordinations-katalysatorsysteme

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KR950700121A true KR950700121A (ko) 1995-01-16
KR100240533B1 KR100240533B1 (ko) 2000-01-15

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US (2) US5468707A (ko)
EP (1) EP0625928B1 (ko)
JP (1) JP3553937B2 (ko)
KR (1) KR100240533B1 (ko)
AT (1) ATE162957T1 (ko)
DE (1) DE59308118D1 (ko)
WO (1) WO1994012278A1 (ko)

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DE59308118D1 (de) 1998-03-12
WO1994012278A1 (de) 1994-06-09
ATE162957T1 (de) 1998-02-15
US5468707A (en) 1995-11-21
EP0625928B1 (de) 1998-02-04
US5698761A (en) 1997-12-16
EP0625928A1 (de) 1994-11-30
KR100240533B1 (ko) 2000-01-15
JP3553937B2 (ja) 2004-08-11
JPH07503660A (ja) 1995-04-20

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