KR950032302A - 올레핀 중합에 유용한 메탈로센- 함유 촉매 시스템의 제조 방법 - Google Patents
올레핀 중합에 유용한 메탈로센- 함유 촉매 시스템의 제조 방법 Download PDFInfo
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- KR950032302A KR950032302A KR1019950011892A KR19950011892A KR950032302A KR 950032302 A KR950032302 A KR 950032302A KR 1019950011892 A KR1019950011892 A KR 1019950011892A KR 19950011892 A KR19950011892 A KR 19950011892A KR 950032302 A KR950032302 A KR 950032302A
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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Abstract
본 발명에 따라서, 촉매 시스템, 및 메탈로센 화합물, 고체 유기알루미녹시 생성물 및 유기금속 화합물을 반응시키는 것으로 구성되는 상기 촉매 시스템을 제조하기 위한 방법을 제공한다. 부가로 촉매 시스템을 사용하여 올레핀을 종합시키기 위한 방법을 제공한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (27)
- 메탈로센 화합물, 고체 유기알루미녹시 생성물, 및 일반식 RmEXn으로 나타내는 유기금속 화합물을 반응시키는 것으로 구성되는 올레핀 중합체 유용한 메틸로센-함유 촉매 시스템을 제조하기 위한 방법으로서, 이때 R은 C1내지 C20히드로카르빌 라디칼이고; E는 Mg, Al, B, Ga, 또는 Zn이고, X는 수소화물, 할로겐화물, R'가 C1-C8알킬 라디칼인 OR', 또는 -NH2이고, m은 1-3이고, n은 0-2이고; m+n의 합은 E의 원자가와 동일하며; 여기서, 상기 고체 유기알루미녹시 생성물은 유기 보록신, 유기 보란, 유기 퍼옥시드, 알킬렌 옥시드, 또는 유기 카르보네이트인 산소-함유 화합물 및 유기알루미녹산을 반응시켜 제조하고; 상기 유기알루미녹산은 하기 일반식으로 나타내는데:이때, 각각의 R1은 C1-C8히드로카르빌 라디칼이고, x는 2-50이고, y는 3-50인 방법.
- 제1항에 있어서, 상기 유기금속 화합물이 유기알루미늄 화합물인 방법.
- 제2항에 있어서, 상기 유기알루미늄 화합물이 각각의 알킬 라디칼이 C1-C10을 함유하는 트리알킬알루미늄 화합물인 방법.
- 제3항에 있어서, 상기 트리알킬알루미늄 화합물이 트리메틸알루미늄 또는 트리에틸알루미늄인 방법.
- 제1-4항 중 어느 한 항에 있어서, 상기 유기금속 화합물이 메탈로센 화합물의 몰당 약 500몰의 범위의 양으로 존재하는 방법.
- 제5항에 있어서, 상기 유기금속 화합물이 메탈로센 화합물의 몰당 약 25몰-약 500몰의 범위의 양으로 존재하는 방법.
- 제6항에 있어서, 상기 유기금속 화합물이 메탈로센 화합물의 몰당 50몰-250몰의 범위의 양으로 존재하는 방법.
- 제1-6항 중 어느 한 항에 있어서, 상기 산소-함유 화합물이 일반식 (R2BO)3로 나타내는 유기 보록신 화합물이며, 여기서 각각의 R2는 C1-C25히드로카르빌 라디칼, R″O-, R″S-, R″2N-, R″2P-, 또는 R″3Si-이며, 이때, 각각의 R″는 C1-C10히드로카르빌 라디칼인 방법.
- 제8항에 있어서, 상기 유기 보록신 화합물이 히드로카르빌 보록신 또는 히드로카르빌옥시 보록신이며, 여기서 각각의 히드로카르빌 라디칼이 C1-C10을 함유하는 방법.
- 제9항에 있어서, 상기 유기 보록신이 트리메틸 보록신, 트리에틸 보록신 또는 트리메톡시 보록신인 방법.
- 제1-6항 중 어느 한 항에 있어서, 상기 유기 보란 화합물이 하기 일반식으로 표현되는 관능기를 함유하며:(여기서, Z는 (CR3 2)q, 아릴렌, 또는 (YB3 S)q인 가교 단위이며, 이때 각각의 R3는 개별적으로 수소 또는 C1-C20히드로카르빌 라디칼이고;s 및 q는 1-10 범위의 정수이고; 각각의 Y는 개별적으로 C, Si, Ge, Sn, B, Ga,In, P, As, 또는 Sb로부터 선택되며, 이때 하나 이상의 Y는 C가 아님); 상기 유기 퍼옥시드 일반식 R4OOR5(여기서 R4및 R5는 개별적으로 수소, 히드로카르빌, 및 C1-C24를 함유하는 알킬, 시클로알킬, 아릴, 알케닐, 및 알키닐 라디칼인 히드로카르보닐 라디칼이며, 이때, R4및 R5중 적어도 하나는 히드로카르빌 또는 히드로카르보닐 라디칼임)로 나타내고; 상기 산화 알킬렌은 C2-C16을 함유하고 하기 관능기를 함유하고; 그리고 상기 유기 카르보네이트는 하기 관능기를 함유하는 방법.
- 제1-6항 중 어느 한 항에 있어서, 상기 고체 유기알루미녹시 화합물을, 메틸알루미녹산 및 트리메틸보록신 또는 트리메록시 보록신을 반응시켜 제조하는 방법.
- 제1-6항 중 어느 한 항에 있어서, 상기 고체 유기알루미녹시 생성물이 메탈로센 화합물 몰당 약 50몰-약 10,000몰의 범위의 양으로 존재하는 방법.
- 제13항에 있어서, 상기 고체 유기알루미녹시 생성물이 메탈로센 화합물 몰당 약 100몰- 약 10,000몰의 범위의 양으로 존재하는 방법.
- 제14항에 있어서, 상기 고체 유기알루미녹시 생성물이 메탈로센 화합물 몰당 100몰- 7,500몰의 범위의 양으로 존재하는 방법.
- 제1-6항 중 어느 한 항에 있어서, 상기 메탈로센 화합물이 이염화 비스(시클로펜타디에닐) 지르코늄, 이 염화 비스(n-부틸시틀로펜타디에닐) 지르코늄, 이 염화 (시클로펜타디에닐)(플루오레닐)메탄 지르코늄, 또는 이 염화 비스(플루오레닐)에탄 지르코늄인 방법.
- 제1-6항 중 어느 한 항에 있어서, 상기 메탈로센 화합물 및 상기 고체 유기알루미녹시 생성물을 약 0℃-약 200℃ 범위의 온도에서 접촉시키는 방법.
- 제17항에 있어서, 상기 메탈로센 화합물 및 상기 고체 유기알루미녹시 생성물을 35℃- 200℃ 범위의 온도에서 접촉시키는 방법.
- 제18항에 있어서, 상기 메탈로센 화합물 및 상기 고체 유기알루미녹시 생성물을 40℃- 125℃ 범위의 온도에서 접촉시키는 방법.
- 제1-6항 중 어느 한 항에 있어서, 상기 메탈로센 화합물 및 상기 고체 유기알루미녹시 생성물을, 상기 유기금속 화합물과 접촉시키기 전에 접촉시키는 방법.
- 제1-6항 중 어느 한 항에 있어서, 이렇게 생성된 촉매 시스템이 본질적으로 상기 메탈로센 화합물.
- 제 1-6항 중 어느 한 항에 따른 방법으로 제조된 촉매 시스템과, 중합 조건하에서 상기 올레핀을 접촉시키는 것으로 구성되는 올레핀 중합 방법.
- 제22항에 있어서, 상기 중합 조건이 약 20℃- 약 200℃ 범위의 온도를 포함하는 방법.
- 제23항에 있어서, 상기 중합 조건이 약 60℃- 약 100℃ 범위의 온도를 포함하는 방법.
- 제22항에 있어서, 상기 중합을 입자 형성 조건하에서 실시하는 방법.
- 제22항에 있어서, 상기 올레핀이 에틸렌으로 구성되는 방법.
- 제26항에 있어서, 부가로 상기 올레핀이 1-헥센으로 구성되는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/242,901 US5496781A (en) | 1994-05-16 | 1994-05-16 | Metallocene catalyst systems, preparation, and use |
US8/242,901 | 1994-05-16 |
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Publication Number | Publication Date |
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KR950032302A true KR950032302A (ko) | 1995-12-20 |
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Application Number | Title | Priority Date | Filing Date |
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KR1019950011892A KR950032302A (ko) | 1994-05-16 | 1995-05-15 | 올레핀 중합에 유용한 메탈로센- 함유 촉매 시스템의 제조 방법 |
Country Status (16)
Country | Link |
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US (2) | US5496781A (ko) |
EP (1) | EP0683179A1 (ko) |
JP (1) | JPH0841119A (ko) |
KR (1) | KR950032302A (ko) |
CN (1) | CN1112937A (ko) |
AU (1) | AU668334B2 (ko) |
BG (1) | BG99631A (ko) |
BR (1) | BR9502044A (ko) |
CA (1) | CA2146033A1 (ko) |
CZ (1) | CZ122295A3 (ko) |
FI (1) | FI952359A (ko) |
HU (1) | HUT72714A (ko) |
NO (1) | NO951920L (ko) |
PL (1) | PL308608A1 (ko) |
SK (1) | SK63795A3 (ko) |
ZA (1) | ZA953654B (ko) |
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JP2023523494A (ja) | 2020-01-27 | 2023-06-06 | フォルモサ プラスティクス コーポレイション, ユーエスエー | 触媒および触媒組成物の調製プロセス |
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-
1994
- 1994-05-16 US US08/242,901 patent/US5496781A/en not_active Expired - Fee Related
-
1995
- 1995-03-31 CA CA002146033A patent/CA2146033A1/en not_active Abandoned
- 1995-05-03 AU AU17819/95A patent/AU668334B2/en not_active Expired - Fee Related
- 1995-05-05 ZA ZA953654A patent/ZA953654B/xx unknown
- 1995-05-10 CN CN95105705A patent/CN1112937A/zh active Pending
- 1995-05-11 CZ CZ951222A patent/CZ122295A3/cs unknown
- 1995-05-15 EP EP95107347A patent/EP0683179A1/en not_active Withdrawn
- 1995-05-15 PL PL95308608A patent/PL308608A1/xx unknown
- 1995-05-15 KR KR1019950011892A patent/KR950032302A/ko not_active Application Discontinuation
- 1995-05-15 BR BR9502044A patent/BR9502044A/pt not_active Application Discontinuation
- 1995-05-15 NO NO951920A patent/NO951920L/no unknown
- 1995-05-15 HU HU9501422A patent/HUT72714A/hu unknown
- 1995-05-15 FI FI952359A patent/FI952359A/fi not_active Application Discontinuation
- 1995-05-15 BG BG99631A patent/BG99631A/xx unknown
- 1995-05-16 SK SK637-95A patent/SK63795A3/sk unknown
- 1995-05-16 JP JP7117398A patent/JPH0841119A/ja active Pending
- 1995-05-16 US US08/441,912 patent/US5583189A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
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NO951920L (no) | 1995-11-17 |
FI952359A (fi) | 1995-11-17 |
US5496781A (en) | 1996-03-05 |
SK63795A3 (en) | 1995-12-06 |
ZA953654B (en) | 1996-01-02 |
CZ122295A3 (en) | 1995-12-13 |
AU1781995A (en) | 1995-11-23 |
HUT72714A (en) | 1996-05-28 |
BG99631A (en) | 1996-05-31 |
AU668334B2 (en) | 1996-04-26 |
FI952359A0 (fi) | 1995-05-15 |
US5583189A (en) | 1996-12-10 |
CN1112937A (zh) | 1995-12-06 |
BR9502044A (pt) | 1996-04-30 |
EP0683179A1 (en) | 1995-11-22 |
CA2146033A1 (en) | 1995-11-17 |
PL308608A1 (en) | 1995-11-27 |
NO951920D0 (no) | 1995-05-15 |
JPH0841119A (ja) | 1996-02-13 |
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