KR950034940A - 높은 반복 속도의 미드 적외선 레이저 - Google Patents

높은 반복 속도의 미드 적외선 레이저 Download PDF

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KR950034940A
KR950034940A KR1019950011234A KR19950011234A KR950034940A KR 950034940 A KR950034940 A KR 950034940A KR 1019950011234 A KR1019950011234 A KR 1019950011234A KR 19950011234 A KR19950011234 A KR 19950011234A KR 950034940 A KR950034940 A KR 950034940A
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laser
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제이. 프레이버그 로버트
코제안 콜레테
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코제안 콜레테
프리미어 레이저 시스템즈, 인크.
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Abstract

높은 펄스 반복 속도를 갖고 있는 광학적으로 펌프된 미드 적외선 솔리드-스테이트 레이저는 레이저 수술에 사용하기 위해 설명되어 있다. 레이저는 1.7과 4.0㎛ 사이의 파장을 형성하여 광학적으로 펌프된다. 펌프 펄스의 상승 및 하강 시간은 충분히 짧기 때문에, 불안정성으로 유도된 열적 렌싱을 피할 수 있다. 레이저는 펄스 에너지의 증가에 필요없는 조직 절단이 증가된 비율을 제공한다.

Description

높은 반복 속도의 미드 적외선 레이저
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에서 개시된 형태를 대표하는 광학적으로 펌프된 솔리드-스테이트 레이저(solid-state laser)의 개략적인 단면도, 제2도는 펌프 광원 구동 회로의 기능적인 블럭도, 제3도는 본 실시예에 적합한 펄스-형성 네트워크의 기본 개략도.

Claims (18)

  1. 펌프 광원; 상기 펌프광에 의한 펌핑을 위해 배치되고 상기 펌프광에 의한 펌핑에 응답하여 1.7㎛와 4㎛ 사이의 파장을 갖고 있는 광을 방출하는 레이저 매체를 포함하는 공진 캐비티; 및 초당 10펄스 이상의 높은 펄스 반복 속도로 펄스된 광학 펌프 에너지를 발생하도록 상기 펌프 광원에 에너지를 가하는 회로를 포함함으로써, 상기 공진 캐비티가 상기 반복 속도로 레이저 펄스를 발생하고, 상승 및 하강 시간을 갖고 있는 펌프 펄스의 세기가 상기 펄스 반복 속도로 상기 공진 캐비티에서의 상기 레이저 펄스의 열적 렌싱로 인한 불안정성을 부분적으로 제거하도록 충분히 짧은 것을 특징으로 하는 펄스식 광학 펌프 레이저.
  2. 제1항에 있어서, 상기 펄스 반복 속도는 적어도 초당 20펄스인 것을 특징으로 하는 펄스식 광학 펌프 레이저.
  3. 제1항에 있어서, 상기 레이저 펄스의 에너지는 1J 이하인 것을 특징으로 하는 펌프식 광학 펌프 레이저.
  4. 제1항에 있어서, 상기 레이저 펄스의 펄스 지속 기간은 500㎛ 이하인 것을 특징으로 하는 펌프식 광학 펌프 레이저.
  5. 제1항에 있어서, 상기 회로는 상기 레이저 매체를 실질적으로 상기 레이저 매체의 레이저 임계치 이하로 유지할 수 있는 충분한 레벨로 펌프 에너지를 상기 레이저 매체에 공급하기 위해 펄스간 주기 동안 상기 펌프 광원에 에너지를 가하는 것을 특징으로 하는 펄스식 광학 펌프 레이저.
  6. 제4항에 있어서, 상기 펌프 광원 및 상기 레이저 매체는 상기 펌프 광원 및 상기 레이저 매체 각각의 축이 타원형의 다른 촛점과 실질적으로 동일 선상에 놓이도록 타원형의 단면을 가진 반사성 원통성 캐비티내에 설치되는 것을 특징으로 하는 펄스식 광학 펌프 레이저.
  7. 제5항에 있어서, 상기 펌프 광원에 의해 방출된 모든 방사선을 실질적으로 차단하고, 상기 레이저 매체의 펌프 파장에 대응하는 광 파장으로 최대 상대적 스펙트럴 투과율을 갖도록 배치되는 광 필터를 구비하는 것을 특징으로 하는 펄스식 광학 펌프 레이저.
  8. 제1항에 있어서, 상기 공진 캐비티는 상기 레이저 매체의 열적 렌싱 효과를 적어도 부분적으로 보상하도록 구성된 반사기를 포함하는 것을 특징으로 하는 펄스식 광학 펌프 레이저.
  9. 제1항에 있어서, 상기 레이저 매체를 냉각하기 위한 유체 쿨런트를 포함하고, 상기 유체 쿨런트는 유체와 상기 레이저 매체의 상기 표면 사이의 경계부를 제외하고, 상기 레이저 매체의 표면에 평행한 방향으로 실질적으로 층류(laminar flow)를 유지하도록 구성된 흐름 경로를 갖고 있는 것을 특징으로 하는 펄스식 광학 펌프 레이저.
  10. 펌프 광원; 레이저 매체 및 반사기를 포함하는 광학 공진기 캐비티를 포함하는데, 상기 레이저 매체는 상기 펌프광에 의한 펌핑에 응답하여 1.7㎛와 4㎛ 사이의 광을 방출하고, 상기 반사기 중 하나는 레이저 광출력을 발생하도록 부분적으로 투과되며, 상기 반사기 중 적어도 하나는 곡선형 미러를 포함하고, 상기 미러의 곡률은 상기 레이저 매체의 열적 랜싱 효과를 적어도 부분적으로 보상하기 위해 선택되고, 상기 레이저 매체를 냉각하고, 유체와 상기 레이저 매체의 상기 표면 사이의 경계부를 제외하고 상기 레이저 매체의 표면과 평행한 방향으로 상기 레이저 매체를 포함하는 상기 광학 공진기 캐비티의 일부를 통해 실질적으로 층류를 제공하도록 구성된 유체 시스템; 및 상기 펌프원에 에너지를 가하며, 총 에너지에 대한 피크력(peak power)의 비가 500㎲이하인 전기 펄스를 발생하는 전기 회로를 구비하는데, 상기 전기 회로는 펄스간 에너지를 상기 펄스들 사이의 상기 펌프원에 공급하고, 상기 펄스간 에너지는 상기 레이저 매체를 실질적으로 상기 레이저 매체의 레이저 임계값 이하로 유지하도록 충분한 펌프 에너지를 상기 레이저 매체에 공급하도록 상기 펌프원에 에너지를 가하는 것을 특징으로 하는 펄스식 레이저.
  11. 제9항에 있어서, 상기 레니저 광 출력은 1J 이하의 펄스 에너지를 갖고 있는 펄스로 이루어지는 것을 특징으로 하는 펄스식 레이저.
  12. 제9항에 있어서, 펄스 반복 속도는 초당 10펄스 이상인 것을 특징으로 하는 펄스식 레이저.
  13. 제9항에 있어서, 반사성 타원형 원통으로 구성되는 광학 펌프 캐비티를 구비하며, 상기 타원형 원통내에는 이 원통의 서로 다른 촛점 라인에 일직선으로 정렬되는 상기 펌프 광원 및 상기 레이저 매체가 설치되어 있는 것을 특징으로 하는 펄스식 레이저.
  14. 제12항에 있어서, 상기 펌프광원에 의해 방출된 모든 펌프 광을 실질적으로 차단하고, 상기 레이저 매체의 펌프 파장이외의 파장으로 펌프광을 양호하게 흡수되도록 배치하는 광학 필터를 구비하는 것을 특징으로 하는 펄스식 레이저.
  15. 1J 이하인 펄스 에너지와 초당 10펄스 이상의 반복 속도로 1.7 에서 4㎛사이의 파장의 광 펄스를 공급하는 단계; 및 조직을 변형하기 위해 조직에 상기 펄스를 지향하는 단계를 포함하는 것을 특징으로 하는 수술 방법.
  16. 제15항에 있어서, 상기 펄스는 500㎲ 이하의 지속 기간을 갖고 있는 것을 특징으로 하는 수술 방법.
  17. 제15항에 있어서, 광섬유를 통해 펄스를 전달하는 단계를 포함하는 것을 특징으로 하는 수술 방법.
  18. 제15항에 있어서, 상기 조직에 대한 방사선 노출이 2.0J/㎟/펄스 이하인 것을 특징으로 하는 수술 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950011234A 1988-09-28 1995-05-09 높은 반복 속도의 미드 적외선 레이저 KR950034940A (ko)

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US08/240,225 US5571870A (en) 1988-09-28 1994-05-10 Liquid phase fluorination
US8/240225 1994-05-10

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Families Citing this family (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5506309A (en) * 1988-09-28 1996-04-09 Exfluor Research Corporation Perfluorinates polyethers
US5093432A (en) * 1988-09-28 1992-03-03 Exfluor Research Corporation Liquid phase fluorination
US5332790A (en) * 1988-09-28 1994-07-26 Exfluor Research Corporation Liquid-phase fluorination
US5539059A (en) * 1988-09-28 1996-07-23 Exfluor Research Corporation Perfluorinated polyethers
US5322904A (en) * 1988-09-28 1994-06-21 Exfluor Research Corporation Liquid-phase fluorination
WO1990006296A1 (en) * 1988-12-02 1990-06-14 Minnesota Mining And Manufacturing Company Direct fluorination process for making perfluorinated organic substances
US5362919A (en) * 1988-12-02 1994-11-08 Minnesota Mining And Manufacturing Company Direct fluorination process for making perfluorinated organic substances
US5403575A (en) * 1991-12-12 1995-04-04 Hemagen/Pfc Highly fluorinated, chloro-substituted organic compound-containing emulsions and methods of using them
US5420359A (en) * 1992-12-11 1995-05-30 Minnesota Mining And Manufacturing Company Chlorofluoroether compositions and preparation thereof
US5352785A (en) * 1993-03-30 1994-10-04 Minnesota Mining And Manufacturing Company Continuous process for purifying perfluorochemical compositions
US5422404A (en) * 1993-08-20 1995-06-06 Polymod Technologies, Inc. Polymer modified gums
US5488142A (en) * 1993-10-04 1996-01-30 Minnesota Mining And Manufacturing Company Fluorination in tubular reactor system
US5466877A (en) * 1994-03-15 1995-11-14 Minnesota Mining And Manufacturing Company Process for converting perfluorinated esters to perfluorinated acyl fluorides and/or ketones
US5658962A (en) * 1994-05-20 1997-08-19 Minnesota Mining And Manufacturing Company Omega-hydrofluoroalkyl ethers, precursor carboxylic acids and derivatives thereof, and their preparation and application
US5476974A (en) * 1994-05-20 1995-12-19 Minnesota Mining And Manufacturing Company Omega-hydrofluoroalkyl ethers, precursor carboxylic acids and derivatives thereof, and their preparation and application
EP0937019A1 (en) * 1996-09-18 1999-08-25 Exfluor Research Corporation Method for preparing perfluorocarbon-substituted methanols
US5741950A (en) * 1996-12-16 1998-04-21 Minnesota Mining And Manufacturing Company Method of preparing nonafluoroisobutyl methyl ether
US5823455A (en) * 1996-12-20 1998-10-20 Imation Corp. Belt-driven data storage device with corner roller assemblies preselected to have different drag force profiles
US5780691A (en) * 1996-12-23 1998-07-14 Allied Signal Inc. Process for producing 1,1,1,2,3,3,3,-heptafluoroprane
JP2000007593A (ja) * 1998-06-24 2000-01-11 Asahi Glass Co Ltd ペルフルオロ(n−ペンタン)の製造方法
JP4802367B2 (ja) * 1999-03-23 2011-10-26 旭硝子株式会社 液相フッ素化による含フッ素化合物の製造方法
DE60004993T2 (de) 1999-05-20 2004-07-22 The South African Nuclear Energy Corp. Ltd. Fluorierung
CA2381351C (en) 1999-08-31 2009-11-17 Asahi Glass Company, Limited Process for producing a vic-dichloro acid fluoride
WO2001046093A2 (en) * 1999-12-20 2001-06-28 Asahi Glass Company, Limited Process for producing a fluoride compound
US6482979B1 (en) * 1999-12-22 2002-11-19 Dyneon Llc Perfluorinated acid fluorides and preparation thereof
CN1246281C (zh) * 2000-07-11 2006-03-22 旭硝子株式会社 含氟化合物的制造方法
AU2001271079A1 (en) * 2000-07-27 2002-02-13 Asahi Glass Company, Limited Process for producing fluorinated secondary alcohol and fluorinated ester through transesterification
KR100758163B1 (ko) * 2000-07-28 2007-09-12 아사히 가라스 가부시키가이샤 불소 함유 아실플루오라이드의 제조방법 및 불소 함유비닐에테르의 제조방법
JP4934939B2 (ja) * 2000-08-30 2012-05-23 旭硝子株式会社 含フッ素ケトンの製造方法
ES2294032T3 (es) * 2000-09-27 2008-04-01 Asahi Glass Company Ltd. Procedimiento de produccion de una composicion ester fluorado.
KR100816697B1 (ko) 2000-09-27 2008-03-27 아사히 가라스 가부시키가이샤 함불소 다가 카르보닐 화합물의 제조방법
WO2002026686A1 (fr) * 2000-09-27 2002-04-04 Asahi Glass Company, Limited Processus de production de fluorure acyle et de sel d'acide carboxylique
RU2278854C2 (ru) 2000-11-28 2006-06-27 Асахи Гласс Компани Лтд. Способ получения содержащего атом фтора сульфонилфторидного соединения
EP1352892B1 (en) * 2001-01-16 2010-06-09 Asahi Glass Company Ltd. Processes for producing fluorinated ester, fluorinated acyl fluoride, and fluorinated vinyl ether
DE10159940B4 (de) * 2001-12-06 2007-02-08 Air Liquide Deutschland Gmbh Vorrichtung und Verfahren zur Fluorierung von Formteilen aus Kunststoff mit einem fluorhaltigen Gasgemisch
US7435774B2 (en) * 2002-09-11 2008-10-14 Peach State Labs, Inc. Fluoromonomers, fluoropolymers, methods of preparing them, and their application to various surfaces and substrates
JP4501111B2 (ja) * 2002-10-18 2010-07-14 旭硝子株式会社 ペルフルオロポリエーテル誘導体
US20050164522A1 (en) * 2003-03-24 2005-07-28 Kunz Roderick R. Optical fluids, and systems and methods of making and using the same
JP4792972B2 (ja) * 2003-07-02 2011-10-12 旭硝子株式会社 含フッ素スルホニルフルオリド化合物
WO2005003082A1 (ja) * 2003-07-04 2005-01-13 Asahi Glass Company, Limited 含フッ素スルホニルフルオリドの製造方法
US20070023740A1 (en) * 2005-07-29 2007-02-01 Ansul, Inc. Use of fluorinated esters in fire extinguishing compositions
US7247759B1 (en) * 2006-01-04 2007-07-24 Honeywell International Inc. Fluorination reactor
US20070186459A1 (en) * 2006-02-14 2007-08-16 Horton John W Front interfacing detachable scope mount
US7265247B1 (en) 2006-07-28 2007-09-04 Im&T Research, Inc. Substituted phenylsulfur trifluoride and other like fluorinating agents
JP2008255097A (ja) * 2007-03-09 2008-10-23 Sumitomo Chemical Co Ltd 含フッ素多環芳香族化合物、含フッ素重合体、有機薄膜及び有機薄膜素子
EP2468720B1 (en) * 2007-03-23 2013-11-27 UBE Industries, Ltd. Process for producing arylsulfur pentafluorides
US8399720B2 (en) * 2007-03-23 2013-03-19 Ube Industries, Ltd. Methods for producing fluorinated phenylsulfur pentafluorides
JP5077350B2 (ja) * 2007-07-24 2012-11-21 ダイキン工業株式会社 新規化合物、その製造方法及びフルオロポリマーの製造方法
US8030516B2 (en) * 2007-10-19 2011-10-04 Ube Industries, Ltd. Methods for producing perfluoroalkanedi(sulfonyl chloride)
US8350082B2 (en) * 2007-11-28 2013-01-08 Mitsubishi Materials Corporation Process for producing fluorine-containing compounds
KR20100099225A (ko) * 2007-11-30 2010-09-10 고꾸리쯔 다이가꾸 호우징 오사까 다이가꾸 공액계 화합물, 질소 함유 축합환 화합물, 질소 함유 축합환 중합체, 유기 박막 및 유기 박막 소자
JP2011518765A (ja) * 2007-12-11 2011-06-30 宇部興産株式会社 ジフルオロメチレン−及びトリフルオロメチル−含有化合物を製造するための方法及び組成物
TW201006787A (en) * 2008-03-07 2010-02-16 Im & T Res Inc Fluorination processes with arylsulfur halotetrafluorides
WO2010022001A1 (en) * 2008-08-18 2010-02-25 Im&T Research, Inc. Methods for preparing fluoroalkyl arylsulfinyl compounds and fluorinated compounds thereto
US8653302B2 (en) * 2008-09-22 2014-02-18 Ube Industries, Ltd. Processes for preparing poly(pentafluorosulfanyl)aromatic compounds
US20100174096A1 (en) * 2009-01-05 2010-07-08 Im&T Research, Inc. Methods for Production of Optically Active Fluoropyrrolidine Derivatives
US8203003B2 (en) 2009-01-09 2012-06-19 Ube Industries, Ltd. 4-fluoropyrrolidine-2-carbonyl fluoride compounds and their preparative methods
US8552124B2 (en) 2009-12-30 2013-10-08 3M Innovative Properties Company Copolymers with perfluoropolyether segment and polydiorganosiloxane segment
WO2011082046A1 (en) 2009-12-30 2011-07-07 3M Innovative Properties Company Copolymers with perfluorpolyether segment and multiple aminooxalylamino groups
JP5745540B2 (ja) 2009-12-30 2015-07-08 スリーエム イノベイティブ プロパティズ カンパニー オキサリルアミノ基を有するペルフルオロポリエーテル含有化合物
CN102712758B (zh) 2009-12-30 2014-05-07 3M创新有限公司 制备聚二有机硅氧烷-聚乙二酰胺共聚物的方法
EP2643289B1 (en) 2010-11-22 2018-01-24 Solvay Specialty Polymers Italy S.p.A. Process for producing perfluorinated organic compounds
JP2014509302A (ja) 2010-12-21 2014-04-17 ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア フッ素化有機化合物の製造方法
US8946487B2 (en) * 2011-02-17 2015-02-03 Basf Se Process for preparing divinyl ethers
CN103145561B (zh) * 2013-03-01 2014-07-16 上海华捷视医疗设备有限公司 全氟三丙胺的连续生产方法
WO2022160762A1 (en) 2021-02-01 2022-08-04 Fujian Yongjing Technology Co., Ltd New industrial process for manufacturing of perfluoropentane (pfp)
CN114210288B (zh) * 2021-12-28 2023-09-05 科莱博(江苏)科技股份有限公司 1,1-二氟丙酮生产装置及其生产方法

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2186916A (en) * 1934-01-11 1940-01-09 Standard Oil Dev Co Fluorinated compound and method of producing same
US3242218A (en) * 1961-03-29 1966-03-22 Du Pont Process for preparing fluorocarbon polyethers
US3415847A (en) * 1965-10-18 1968-12-10 Minnesota Mining & Mfg Fluorocarbon orthoesters
US3455954A (en) * 1966-03-31 1969-07-15 Minnesota Mining & Mfg Cyclic fluorocarbonates
US3665041A (en) * 1967-04-04 1972-05-23 Montedison Spa Perfluorinated polyethers and process for their preparation
US3654369A (en) * 1967-09-11 1972-04-04 Minnesota Mining & Mfg Fluorination process for preparing certain difluoramino compounds
US3897502A (en) * 1971-10-22 1975-07-29 Airco Inc Process for making fluorinated ethers
US4144374A (en) * 1974-12-12 1979-03-13 Massachusetts Institute Of Technology Perfluorinated functionalized materials
US4076916A (en) * 1975-11-03 1978-02-28 Massachusetts Institute Of Technology Fluorinated functionalized polymers
JPS606339B2 (ja) * 1979-04-28 1985-02-18 ダイキン工業株式会社 フツ素化方法
US4523039A (en) * 1980-04-11 1985-06-11 The University Of Texas Method for forming perfluorocarbon ethers
US4943595A (en) * 1981-09-08 1990-07-24 The Green Cross Corporation Perfluorochemicals and process for preparing the same
US4686024A (en) * 1985-02-01 1987-08-11 The Green Cross Corporation Novel perfluoro chemicals and polyfluorinated compounds and process for production of the same
IT1200806B (it) * 1985-10-21 1989-01-27 Ausimont Spa Procedimento per la preparazione di idroalofluoroalcani
US4755567A (en) * 1985-11-08 1988-07-05 Exfluor Research Corporation Perfluorination of ethers in the presence of hydrogen fluoride scavengers
IT1213537B (it) * 1986-11-21 1989-12-20 Ausimont Spa Procedimento per la preparazione di perfluoroeteri mediannte fluorurazione con fluoro elementare.
IT213155Z2 (it) * 1987-12-10 1989-10-27 Grassi Enrico Ronchi Daniela Morsetto a chiusura rapida, automatica, con potenza progressiva al crescere del carico, per i cavi di sospensione.
AU607579B2 (en) * 1988-01-29 1991-03-07 Monsanto Company Novel perfluorinated polyethers and process for their preparation
EP0344935A3 (en) * 1988-05-19 1991-04-17 E.I. Du Pont De Nemours And Company Photo-assisted solution phase direct fluorination process improvement
WO1990003357A1 (en) * 1988-09-28 1990-04-05 Minnesota Mining And Manufacturing Company Perfluoroacetal and perfluoroketal compounds and use thereof in thermal shock testing
US5093432A (en) * 1988-09-28 1992-03-03 Exfluor Research Corporation Liquid phase fluorination
WO1990006296A1 (en) * 1988-12-02 1990-06-14 Minnesota Mining And Manufacturing Company Direct fluorination process for making perfluorinated organic substances
US5076949A (en) * 1989-01-29 1991-12-31 Monsanto Company Novel perfluorinated polyethers and process for their preparation
US4996369A (en) * 1989-01-29 1991-02-26 Monsanto Company Novel perfluorinated polyethers and process for their preparation
US5120459A (en) * 1989-01-29 1992-06-09 Monsanto Company Perfluorinated polyethers and process for their preparation
US5488142A (en) * 1993-10-04 1996-01-30 Minnesota Mining And Manufacturing Company Fluorination in tubular reactor system

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