KR950014238A - 분체 도료 조성물 및 이의 내열성 기판 피복 용도 - Google Patents

분체 도료 조성물 및 이의 내열성 기판 피복 용도 Download PDF

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KR950014238A
KR950014238A KR1019940028872A KR19940028872A KR950014238A KR 950014238 A KR950014238 A KR 950014238A KR 1019940028872 A KR1019940028872 A KR 1019940028872A KR 19940028872 A KR19940028872 A KR 19940028872A KR 950014238 A KR950014238 A KR 950014238A
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밤프레흐트 크리스티안
라스 한스-요셉
복크 만프레드
마이어-베스투에스 한스-울리히
슐츠 볼프강
칼 로타르
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게르하르트 뮐러, 로타르 스타일링
바이엘 악티엔게젤샤프트
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Abstract

본 발명은 A) 올레핀계 불포화 단량체로부터 제조되며 에폭시기 및 임의로 히드록실기를 함유하는 1종 이상의 공중합체, B) 카르복실산기 또는 카르복실산 무술무기를 함유하는 1종 이상의 경화제, 및 C) 우레트디온기를 함유하고 융점이 40℃ 내지 120℃이며 지방족(지환족) 디이소시아네이트로부터 제조되는 1종 이상의 중부가 화합물을 함유하는, 120 내지 150℃에서 경화되는 분체 도료 조성물 및 내열성 기판, 특히 자용 기판을 피복시키기 위한 이의 용도에 관한 것이다.

Description

분체 도료 조성물 및 이의 내열성 기판 피복 용도.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. A) 올레핀계 불포화 단량체로부터 제조되고, 에폭시기 및 임의로 히드록실기를 함유하며, 365 내지 2,840의 에폭시 당량, 20 내지 100℃의 유리 전이 온도(Tg) 및 1,500 내지 30,000의 질량 평균 분자량을 갖는 공중합체를 1종 이상 함유하는 결합제 성분. B) i) 탄소수 4 내지 20의 지방족(지환족) 디카르복실산, ii) 상기 디카르복실산의 단량체성 무수물 및/또는 중합체성 무수물, iii) 상기 디카르복실산의 폴리올 개질된 중합체성 무수물, 및 iv) 탄소수 4 내지 18의 지방족 히드록시카르복실산 중에서 선택된 화합물을 1종 이상 함유하는 융점이 40 내지 130℃인 경화 성분, 및 C) 우레트디온기를 함유하고 융점이 40 내지 125℃이며 지방족(지환족) 디이소시아네이트로부터 제조된 중부가 화합물 1종 이상을 함유하며, 단 상기 성분 A),B) 및 C)는 성분 A)의 에폭시기 1개 당 성분 B)의 카르복실기 및/또는 무수물기가 0.5 내지 1.5개이고 성분 C)의 우레트디온 기가 0.1 내지 1.2개가 되는 비율로 존재하는, 120 내지 150℃의 온도에서 경화되어 황변되지 않고 탄성이며 내용매성 및 내약품성인 피복을 제공할 수 있는 분체 도료 조성물.
  2. 제1항에 있어서, 성분 C)가, a) 유리 이소시아네이트기의 함량(NCO로서 환산, 분자량=42)이 0 내지 2중량%이고, b) 우레트디온기의 함량(C2N2O2로서 환산, 분자량=8)이 3 내지 16중량%이고, c) 우레탄기의 함량(CHNO2로서 환산, 분자량=59)이 10 내지 22중량%이고, 카르복실산 에스테르기의 함량(CO2)로서 환산, 분자량=44)이 0 내지 20중량%이고 카르보네이트기의 함량(CO3로서 환산, 분자량=60)이 0 내지 25중량%인 중부가 화합물을 1종 이상 함유하며, 이때 중부가 화합물 중의 카르복실산 에스테르기 및 카르보네이트기의 총 함량은 1중량% 이상인 것인 분체 도료 조성물.
  3. 제1항에 있어서, 상고 공중합체가 i) 글리시딜 아크릴레이트 및/또는 글리시딜 메타크릴레이트 5 내지 35중량부, ii) 알킬기에 2 내지 4개의 탄소수를 갖는 히드록시알킬 아크릴레이트 및/또는 메타크릴레이트, 및/또는 이들과 ε-카프롤락톤 또는 모노에폭시드와의 반응 생성물 중 1종 이상 0 내지 20 중량부 및 iii) 비관능성 올레핀계 불포화 화합물 45 내지 95 중량부(이때, 성분 i) 내지 iii)의 합은 100이다)의 반응 생성물인 것인 분체 도료 조성물.
  4. 제2항에 있어서, 상기 공중합체가 i) 글리시딜 아크릴레이트 및/또는 글리시딜 메타크릴레이트 5 내지 35중량부, ii) 알킬기에 2 내지 4개의 탄소수를 갖는 히드록시알킬 아크릴레이트 및/또는 메타크릴레이트, 및/또는 이들과 ε-카프롤락톤 또는 모노에폭시드와의 반응 생성물 중 1종 이상 0 내지 20 중량부 및 iii) 비관능성 올레핀계 불포화 화합물 45 내지 95 중량부(이때, 성분 i) 내지 iii)의 합은 100이다)의 반응 생성물인 것인 분체 도료 조성물.
  5. 제1항에 있어서, 성분 b)가 탄소수 4 내지 12의 포화 지방족 디카르복실산을 1종 이상 함유하는 것인 분체 도료 조성물.
  6. 제2항에 있어서, 성분 b)가 탄소 4 내지 12의 포화 지방족 디카르복실산을 1종 이상 함유하는 것인 분체 도료 조성물.
  7. 제3항에 있어서, 성분 b)가 탄소수 4 내지 12의 포화 지방족 디카르복실산을 1종 이상 함유하는 것인 분체 도료 조성물.
  8. 제4항에 있어서, 성분 b)가 탄소수 4 내지 12의 포화 지방족 디카르복실산을 1종 이상 함유하는 것인 분체 도료 조성물.
  9. 제1항에 있어서, 성분 B)가 탄소수 4 내지 12의 지방족 디카르복실산의 단량체성 무수물 및/또는 중합체성 무수물을 1종 이상 함유하는 것인 분체 도료 조성물.
  10. 제2항에 있어서, 성분 B)가 탄소수 4 내지 12의 지방족 디카르복실산의 단량체성 무수물 및/또는 중합체성 무수물을 1종 이상 함유하는 것인 분체 도료 조성물.
  11. 제3항에 있어서, 성분 B)가 탄소수 4 내지 12의 지방족 디카르복실산의 단량체성 무수물 및/또는 중합체성 무수물을 1종 이상 함유하는 것인 분체 도료 조성물.
  12. 제4항에 있어서, 성분 B)가 탄소수 4 내지 12의 지방족 디카르복실산의 단량체성 무수물 및/또는 중합체성 무수물을 1종 이상 함유하는 것인 분체 도료 조성물.
  13. 제1항에 있어서, 성분 B)가 산 무수물기와 카르복실기를 1:1 내지 3:1의 몰비로 함유하는 탄소수 4 내지 12의 지방족 디카르복실산의 폴리올 개질된 다가 무수물을 1종 이상 함유하는 것인 분체 도료 조성물.
  14. 제2항에 있어서, 성분 B)가 산 무수물기와 카르복실기를 1:1 내지 3:1의 몰비로 함유하는 탄소수 4 내지 12의 지방족 디카르복실산의 폴리올 개질된 다가 무수물을 1종 이상 함유하는 것인 분체 도료 조성물.
  15. 제3항에 있어서, 성분 B)가 산 무수물기와 카르복실기를 1:1 내지 3:1의 몰비로 함유하는 탄소수 4 내지 12의 지방족 디카르복실산의 폴리올 개질된 다가 무수물을 1종 이상 함유하는 것인 분체 도료 조성물.
  16. 제4항에 있어서, 성분 B)가 산 무수물기와 카르복실기를 1:1 내지 3:1의 몰비로 함유하는 탄소수 4 내지 12의 지방족 디카르복실산의 폴리올 개질된 다가 무수물을 1종 이상 함유하는 것인 분체 도료 조성물.
  17. 제1항의 분체 도료 조성물로 피복시킨 내열성 기판.
  18. 제1항의 분체 도료 조성물로 피복시킨 내열성 자동차 기판.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940028872A 1993-11-05 1994-11-04 분체도료조성물및이의내열성기판피복용도 KR100356885B1 (ko)

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DE4337855A DE4337855A1 (de) 1993-11-05 1993-11-05 Pulverlack und seine Verwendung

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US5492955A (en) 1996-02-20
JPH07188589A (ja) 1995-07-25
DE59401465D1 (de) 1997-02-13
CA2134809C (en) 2006-03-14
ES2096397T3 (es) 1997-03-01
EP0652263B1 (de) 1997-01-02
EP0652263A1 (de) 1995-05-10

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