KR950011469A - 셀루로오즈 기질 강화 방법 - Google Patents

셀루로오즈 기질 강화 방법 Download PDF

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KR950011469A
KR950011469A KR1019940026949A KR19940026949A KR950011469A KR 950011469 A KR950011469 A KR 950011469A KR 1019940026949 A KR1019940026949 A KR 1019940026949A KR 19940026949 A KR19940026949 A KR 19940026949A KR 950011469 A KR950011469 A KR 950011469A
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active hydrogen
anhydride
polyacid
carboxylic acid
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토마스 아켄스 챨스
린드 에골프 스콧트
대비드 글레임 로버트
후시엔-시앙 휴 오스카
죤 위싱거 켄네스
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윌리엄 이. 램버트 3세
롬 앤드 하스 캄파니
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    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
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    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
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    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
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    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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Abstract

본 발명은 기질을 포름알데히드-미함유 경화가능한 수성조성물로 처리하고 그 조성물을 경화시켜 셀루로오즈계 기질을 강화시키는 방법에 관한 것이다. 이 셀루로오즈계 기질은 예를들어 종이 오일- 및 공기- 필터 스톡, 레이욘 부직포 수건, 셀루로오즈계 라미네이팅 스톡, 면직물 및 압밀하여 프레이크 보드로 만들기에 적합한 목재 프레이크를 포함한다.

Description

셀루로오즈 기질 강화 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (21)

  1. (a) 최소 2개의 카복실산기, 무수물기, 흑은 그염을 함유한 다중산: 및 (b) 인-함유 촉진제을 포함하는 포름알데히드-미함유 경화 가능한 수성 조성물로 기질을 처리하고, 상기 카복실기, 무수물기 혹은 그염은 고정 염기로 약 35% 미만범위가지 중화되는, 셀루로오즈계 기질 강화방법.
  2. 1항에 있어서, 상기 경화가능한 수성조성물은 나아가 최소 하나의 활성 수소화합물을 포함하고, 상기 활성 수소 화합물은 히드록실, 1차 아미노, 2차 아미노 및 그들의 흔합물로 구성되는 그룹에서 선택되며: 상기 활성 수소기의 당량수에 대한 상기 카복실산기, 무수물기 혹은 그염의 당량수의 비는 약 1/0. 01∼1/3 임을 특징으로 하는 방법.
  3. 1항에 있어서, 상기 다중산은 최소 하나의 에틸렌계-불포화 단량체로부터 형성된 부가 중합체임을 특징으로 하는 방법.
  4. 셀루로오즈계 부직포 수건(wipe)을 (a) 최소 2개의 카복실산기, 무수물기 흑은 그염을 포함한 다중산: 및 (b) 인-함유 촉진제를 포함한 포름알데히드-미함유 결화가능 수성조성물로 처리하고, 상기 카복실기, 무수물기, 혹은 그염은 고정염기를 이용하여 약 35%미만 범위까지 중화되는, 셀루로오즈계 부직포 수건의 용매- 및 물-습윤 및 건조강도 증대방법.
  5. 4항에 있어서, 상기 경화가능한 수성 조성물은 나아가 최소 하나의 활성수소화합물을 포함하고, 상기 활성 수소 화합물은 히드록실, 1차 아미노, 2차 아미노 및 이들의 혼합물로 구성되는 그룹으로 부터 선택된 최소 2개의 활성수소기를 포함하며, 상기 활성 수소기의 당량 수에 대한 상기 카복실산기, 무수물기 혹은 그염의 당량수의 비는 약 1/0. 01∼1/3 임을 특징으로 하는 방법.
  6. 4항에 있어서, 상기 다중산은 최소 하나의 에틸렌계 불포화 단량체로 부터 형성된 부가 중합체임을 특징으로하는 방법.
  7. 4항에 있어서, 상기 다중산은 최소 2개의 에틸렌계 불포화 단량체를 에멀션 중합시켜 제조된 공중합체이며: 최소 2개의 카복실산기, 무수물기, 혹은 그 염을 함유하고; 상기 공중합체의 Tg는 60℃∼-50℃ 임을 특징으로 하는 방법.
  8. 스톡(stock)을 (a) 최소 2개의 카복실산기, 무수물기, 혹은 그염을 포함한 다중산; 및 (b) 인-함유 촉진제를 포함하는 포름알데히드-미함유 경화가능수성주성물로 처리하고, 상기 카복실기, 무수물기 혹은 그 염은 고정 염기를 사용하여 약 35%미만의 범위까지 중화시키는, 종이 오일-및 공기-필터 스톡의 용매- 및 수분-습윤 강도 및 건조 강도 중대방법.
  9. 8항에 있어서, 상기 경화가능한 수성 조성물은 나아가 최소 하나의 활성수소화합물을 포함하고, 상기 활성 수소화합물은 히드록실, 1차 아미노, 2차 아미노 및 그 흔합물로 구성되는 그룹으로 부터 선택된 최소 2개의 활성 수소기를 포함하며, 상기 활성수소기의 당량수에 대한 상기 카복실산기, 무수물기, 록은 그염의 당량수의 비는 약 1/0.01∼1/3 임을 특징으로 하는 방법.
  10. 8항에 있어서, 상기 다중산은 치소 하나의 에틸렌계-불포화 단량체로부터 형성된 부가 중합체임을 특징으로 하는 방법.
  11. 8항에 있어서, 상기 다중산은 최소 2개의 에틸렌계 불포화 단량체를 에멀션 중합하여 제조된 공중합체를 포함하며, 최소 2개의 카복실산기, 무수물기 혹은 그염을 함유하며: 상기 공중합체의 Tg는 약 60℃∼-50℃임을 특징으로 하는 방법.
  12. 라미네이팅 스톡을 (a) 히소 2개의 카복실산기, 무수물기 혹은 그염을 갖는 다중산: 및 (b) 인-함유 촉진제를 포함하는 포름알데히드-미함유 경화가능한 수성 조성물로 처리하고, 상기 카복실기, 무수물기, 혹은 그염은 고정 염기를 사용하여 약 35% 미만 범위까지 중화시키는, 라미네이팅 다중 플라이를 포함한 라미네이팅 스톡이나 라미네이트의 내박리성(delamination reststance) 증대방법.
  13. 12항에 있어서, 상기 경화가능한 수성 조성물은 나아가 최소 하나의 활성수소화합물을 포함하고, 상기 활성 수소화합물은 히드록실, 1차 아미노, 2차 아미노 및 그 혼합물로 구성되는 그룹으로 부터 선택된 최소 2개의 활성 수소기를 포함하며, 상기 활성수소기의 당량수에 대한 상기 카복실산기, 무수물기, 혹은 그염의 당량수의 비는 약 1/0. 01∼1/3 임을 특징으로 하는 방법.
  14. 12항에 있어서, 상기 다중산은 최소 2개의 에틸렌계 불포화 단량체를 에멀션 중합하여 제조된 공중합체를 포함하며, 최소 2개의 카복실산기, 무수물기 혹은 그염을 함유하며: 상기 공중합체의 Tg는 약 60℃∼-50℃임을 특징으로 하는 방법.
  15. 12항에 있어서, 상기 다중산은 최소 하나의 에틸렌계-불포화 단량체로부터 형성된 부가 중합체임을 톡징으로 하는 방법.
  16. 직물을 (a) 긱소 2개의 카복실산기, 무수물기 혹은 그염을 갖는 다중산: 및 (b) 인-함유 촉진제를 포함하는 포름알데히드-미함유 경화가능한 수성 조성물로 처리하고, 상기 카복실기, 무수물기, 혹은 그염은 고정염기를 사용하여 약 35% 미만 범위가지 중화시키는, 셀루로오즈계 직물의 퍼먼넌트-프레스 성의 개선방법.
  17. 16항에 있어서, 상기 경화가능한 수성 조성물은 나아가 최소 하나의 활성수소화합물을 포함하고, 상기 활성 수소화합물은 히드록실, 1차 아미노, 2차 아미노 및 그 혼합물로 구성되는 그룹으로 부터 선택된 최소 2개의 활성 수소기를 포함하며, 상기 활성수소기의 당량수에 대한 상기 카복실산기, 무수물기, 혹은 그염의 당량수의 비는 약 1/0.01∼1/3 임을 특징으로 하는 방법.
  18. 16항에 있어서, 상기 다중산은 최소 하나의 에틸렌계-불포화 단량체로부터 형성된 부가 중합체임을 특징으로 하는 방법.
  19. 목재제품 성분을, 압밀하기 전에, (a) 최소 2개의 카복실산기, 무수물기 혹은 그염율 갖는 다중산: 및 (b)인 -함유 촉진제 틀 포함하는 포틈알데히드-미함유 경 화가능한 수성 조성물로 처리하고, 상기 카복실기, 무수물기, 혹은 그염은 고정염기를 사용하여 약 35%미만 범위까지 중화시키는, 압밀된 목재 제품의 내수성 개선방법.
  20. 19항에 있어서, 상기 경화가능한 수성 조성물은 나아가 최소 하나의 활성수소화합물을 포함하고, 상기 활성 수소화합물은 히드록실, 1차 아미노, 2차 아미노 및 그 혼합물로 구성되는 그룹으로 부터 선택된 최소 2개의 활성 수소기를 포함하며, 상기 활성수소기의 당량수에 대한 상기 카복실산기, 무수물기, 혹은 그염의 당량수의 비는 약 1/0.01∼1/3 임을 특징으로 하는 방법.
  21. 19항에 있어서, 상기 다중산은 최소 하나의 에틸렌계-불포화 단량체로부터 헝성된 부가 중합체임을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940026949A 1993-10-22 1994-10-21 셀루로오즈 기질 강화 방법 KR950011469A (ko)

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AU7594694A (en) 1995-05-11
US5427587A (en) 1995-06-27
MX201070B (en) 2001-03-14
JPH07189131A (ja) 1995-07-25
EP0651088A1 (en) 1995-05-03
DE69432095D1 (de) 2003-03-13
FI944955A0 (fi) 1994-10-21
US5718728A (en) 1998-02-17
TW269716B (ko) 1996-02-01
BR9404180A (pt) 1995-06-27
CA2118298A1 (en) 1995-04-23
DE69432095T2 (de) 2003-11-20
FI944955A (fi) 1995-04-23
CN1109931A (zh) 1995-10-11
EP0651088B1 (en) 2003-02-05
AU694136B2 (en) 1998-07-16
US6241780B1 (en) 2001-06-05
ID20923A (id) 1999-03-25

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