KR950008621A - 유기 규소 화합물을 함유하는, 섬유 재료 처리용 조성물 - Google Patents

유기 규소 화합물을 함유하는, 섬유 재료 처리용 조성물 Download PDF

Info

Publication number
KR950008621A
KR950008621A KR1019940022889A KR19940022889A KR950008621A KR 950008621 A KR950008621 A KR 950008621A KR 1019940022889 A KR1019940022889 A KR 1019940022889A KR 19940022889 A KR19940022889 A KR 19940022889A KR 950008621 A KR950008621 A KR 950008621A
Authority
KR
South Korea
Prior art keywords
component
composition
components
weight
radicals
Prior art date
Application number
KR1019940022889A
Other languages
English (en)
Inventor
디르쉴 프란쯔
크로박체크 하랄트
아우가르트 라이너
킨레 한스-루드비히
울 위르겐
Original Assignee
에리히 뢰쓸러·베른하르트 부르크
페르세 케미 게엠베하
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 에리히 뢰쓸러·베른하르트 부르크, 페르세 케미 게엠베하 filed Critical 에리히 뢰쓸러·베른하르트 부르크
Publication of KR950008621A publication Critical patent/KR950008621A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C08L83/06—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04—Polysiloxanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 섬유 재료로 된 시트 재료를 피복하는데 적합한, 디하이드록시 폴리오가노실록산, 아미노-작용성실란 및 사이클릭 올리고실록산 및/또는 이들 성분들의 반응 생성물을 함유하는 수성 분산액 형태의 조성물에 관한 것이다. 이는 시트 재료에 영구성이 우수한 방수 특성, 우수한 저온 가요성(flexibility) 및 탄성(springiness)을 제공한다.

Description

유기 규소 화합물을 함유하는, 섬유 재료 처리용 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 물 및 성분들 a) 하기 일반식(Ⅰ)의 오가노폴리실록산 또는 이들 혼합물, b) 하기 일반식(Ⅱ)의 사이클릭오가노실록산 또는 이들의 혼합물, c) 하기 일반식(Ⅲ)의 실란 또는 이들의 혼합물, d) 분산제 또는 바람직하게는 하나 이상의 양이온성 분산제가 존재하는 분산제 혼합물 및 필요한 경우 e) 하기 일반식(Ⅳ)의 실란 또는 이들의 혼합물 또는 물의 존재하에 가수분해시킨 다음 물을 제거하여 축합시켜 실란 또는 이들의 혼합물로부터 생성된 생성물을 함유하는 수성 분산액 형태의 조성물〔단, 조성물은 성분 c) 또는 e) 하나 이상을 함유하고, 하나 이상의 Si 원자가 존재하여 일반식또는 일반식의 3개 또는 4개의 라디칼이 결합되며, 성분 a), b), C) 및 e)에 존재하는 모든 라디칼 R은 서로 독립적으로 탄소수 1 내지 4의 알킬 라디칼, 또는 페닐 라디칼이고, 조성물은 성분 a), b), c) 및, 필용한 경우 e)를 그 자체들로서만 함유하거나 또는 이러한 형태와 함께 또는 배타적으로, 상기한 성분들중 둘 이상 상호간의 부분적 또는 완전한 반응에 의해 생성된 생성물 형태로서 함유한다〕.
    상기 식에서, 라디칼 R'는 서로 독립적으로 R 또는Si(R)2-R＂이고, 라디칼 R＂는 서로 독립적으로 R, OH 또는 OR이며, 존재하는 모든 라디칼 R＂중 2개 이상이 OH 또는 OR이고, n1 및 n2는 성분 a)의 점도가 20℃에서 100 내지 100,000mPa.s 바람직하게는 1,000 내지 10,000mPa.s가 되도록 하는 값이며, x는 3 내지 8, 바람직하게는 3 또는 4의 수이고, P는 2 내지 6의 수이며, 9는 0내지 7, 바람직하게는 1 내지 3의 수이고, W는 2내지 6의 수이며, X는 모두 서로 독립적으로 라디칼또는 라디칼 R 또는(여기서, t는 0 내지 8의 수이다)이고, Z는 H 또는 CH3이며 Y는 X 또는이고, R＂는 H 또는 R이다.
  2. 제1항에 있어서, 성분 a), b), c) 및 e)의 존재하는 모든 라디칼 R이 메틸 라디칼 또는 에틸 라디칼인 조성물.
  3. 제1항 또는 제2항에 있어서, 성분 a), b), c) 및 e)의 함량이 물을 제외한 조성물에 존재하는 모든 생성물의 75 내지 95중량%인 조성물.
  4. 제1항 내지 제3항중 어느 한 항에 있어서, 성분 a) 내지 e)를 다음의 상대적 정량비로 포함하는 조성물. 성분a) 10 내지 70중량부, 바람직하게는 40 내지 70중량부, 성분b) 10 내지 70중량부, 바람직하게는 25 내지 60중량부, 성분 c) 0.1 내지 10중량부, 바람직하게는 0.2 내지 3중량부, 성분 d) 0.1 내지 10 중량부, 바람직하게는 0.5 내지 3중량부 및 성분 e) 0 내지 10중량부.
  5. 제1항 내지 제4항 중 어느 한 항에 청구한 조성물을 섬유 재료에 적용함을 포함하여, 특히 직물 또는 편직물형태의 섬유 재료를 처리하는 , 특히 피복하는 방법.
  6. 제5항에 있어서, 성분 a) 및 분산제 또는 분산제 혼합물은 함유하지만 성분 b), c) 및 e)는 함유하지 않거나 이들을 미량만 함유하는 수성 분산액 A와 성분 b) 및 c), 분산제 또는 분산제 혼합물 및 경우에 따라 성분 e)는 함유하지만 성분 a)는 함유하지 않거나 이를 미량만 함유하는 수성 분산액 B〔분산액 B는 성분 b) 및 c) 및 경우에 따라 성분 e)를 이들 자체로서 및/또는 상기한 성분들중 2개 또는 3개 상호간의 부분적 또는 완전한 반응에 의해 생성되는 생성물 형태로서 함유할 수 있다〕를 개별적으로 제조한 다음, 이들을 혼합하고 이렇게 수득한 조성물을 함유하는 피복물을 섬유재료에 적용하는 방법.
  7. 제5항 또는 제6항에 있어서, 조성물을 함유하는 피복물 이외에, 각각 하나의 규소원자에 결합된 2개 이상의 수소원자를 함유하는 오가노폴리실록산을 섬유 재료에 적용하는 방법.
  8. 제5항 내지 제7항 중 어느 한 항에 있어서, 사용되는 섬유 재료가 천연, 부분적 합성 또는 완전한 합성 유기 중합체로 이루어진 부직포, 직포 또는 편직물의 형태인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940022889A 1993-09-13 1994-09-12 유기 규소 화합물을 함유하는, 섬유 재료 처리용 조성물 KR950008621A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4330967A DE4330967A1 (de) 1993-09-13 1993-09-13 Organische Siliciumverbindungen enthaltende Zusammensetzungen für die Behandlung von Fasermaterialien
DEP4330967.4 1993-09-13

Publications (1)

Publication Number Publication Date
KR950008621A true KR950008621A (ko) 1995-04-19

Family

ID=6497546

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940022889A KR950008621A (ko) 1993-09-13 1994-09-12 유기 규소 화합물을 함유하는, 섬유 재료 처리용 조성물

Country Status (5)

Country Link
US (1) US5562761A (ko)
EP (1) EP0643090A3 (ko)
JP (1) JPH07166064A (ko)
KR (1) KR950008621A (ko)
DE (1) DE4330967A1 (ko)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI956324A (fi) * 1995-02-01 1996-08-02 Goldschmidt Ag Th Organofunktionaalisten polysiloksaanien käyttö hienojakoisten hiukkasten pintojen modifioimiseksi
US6294608B1 (en) * 1995-05-11 2001-09-25 Wacker-Chemie Gmbh Emulsions of organosilicon compounds for imparting water repellency to building materials
JP3350334B2 (ja) * 1996-01-12 2002-11-25 信越化学工業株式会社 新規なオルガノポリシロキサンおよびそれを主成分とする繊維処理剤組成物
US6054020A (en) * 1998-01-23 2000-04-25 Kimberly-Clark Worldwide, Inc. Soft absorbent tissue products having delayed moisture penetration
US6605123B1 (en) 1999-04-16 2003-08-12 General Electric Company Silicone finishing compositions and processes
GB9911840D0 (en) * 1999-05-21 1999-07-21 Dow Corning Sa Siloxane emulsions
FR2801907B1 (fr) * 1999-12-06 2002-03-01 Snecma Carbonisation de materiaux fibreux cellulosiques en presence d'un compose organosilicie
EP1148080A1 (de) * 2000-04-19 2001-10-24 Ciba Spezialitätenchemie Pfersee GmbH Polyorganosiloxangemische für die Behandlung von Fasermaterialien
DE10049153A1 (de) * 2000-09-27 2002-04-11 Degussa Farbe, Lack, Schadstoffe, Bioorganismen, Öl, Wasser, und/oder Schmutz abweisende Beschichtung
DE10115476A1 (de) * 2001-03-29 2002-10-10 Wacker Chemie Gmbh Verfahren zur Behandlung von organischen Fasern
FR2833623B1 (fr) * 2001-12-14 2004-04-02 Rhodia Chimie Sa Composition pour le traitement de fibres textiles
US20030175438A1 (en) * 2002-01-17 2003-09-18 Reeve John A. Treatments of solid substrates to enhance durability of treatments placed thereon
EP1388571A1 (de) * 2002-08-08 2004-02-11 Ciba Spezialitätenchemie Pfersee GmbH Polyorganosiloxanzusammensetzung enthaltend quaternäre Ammoniumgruppen
US20060068118A1 (en) * 2003-08-13 2006-03-30 Reeve John A Silicon-containing treatments for solid substrates
EP1690885A1 (de) * 2005-02-09 2006-08-16 Ciba Spezialitätenchemie Pfersee GmbH Acrylatofunktionelle Polysiloxane
CN102219551B (zh) * 2011-04-27 2012-10-03 河南省交通科学技术研究院有限公司 一种具有呼吸功能的有机硅防水剂及其制备方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3398017A (en) * 1964-09-14 1968-08-20 Dow Corning Water repellent treatment
GB1485769A (en) * 1973-12-18 1977-09-14 Dow Corning Ltd Process for treating fibres
DE2616797C3 (de) * 1976-04-15 1981-03-12 Chemische Fabrik Pfersee Gmbh, 8900 Augsburg Verfahren zum Imprägnieren und Beschichten von Textilien mit Polymeren, die reaktive Gruppen enthalten
US4277382A (en) * 1979-10-09 1981-07-07 Owens-Corning Fiberglas Corporation Stable aqueous emulsion of reactive polysiloxane and curing agent
DE3035824A1 (de) * 1980-09-23 1982-05-06 Chemische Fabrik Pfersee Gmbh, 8900 Augsburg Verfahren zum hydrphobieren von fasermaterial
FR2501805A1 (fr) * 1981-03-10 1982-09-17 Haeusler Roland Nouveau systeme d'assemblage du genre a tenon et mortaise et articles mobiliers incorporant ledit systeme
US4509981A (en) * 1983-06-13 1985-04-09 Sws Silicones Corporation Coating compositions
DE3343575A1 (de) * 1983-12-01 1985-10-03 Wacker-Chemie GmbH, 8000 München Verfahren zur herstellung von waessrigen emulsionen
JPS61296184A (ja) * 1985-06-20 1986-12-26 信越化学工業株式会社 繊維処理剤
DE3723697A1 (de) * 1987-04-24 1988-11-17 Pfersee Chem Fab Waessrige, feinteilige bis optisch klare, thermisch und mechanisch stabile silikonemulsionen, verfahren zu deren herstellung und deren verwendung
DE3730780A1 (de) * 1987-09-12 1989-03-23 Stockhausen Chem Fab Gmbh Waessrige loesungen und dispersionen von polysiloxanhaltigen polyurethan-ionomeren, ein verfahren zu ihrer herstellung sowie verwendung zur herstellung von ueberzuegen
US4844888A (en) * 1987-11-13 1989-07-04 The Gillette Company Polysiloxane cosmetic composition
JPH01221580A (ja) * 1988-02-27 1989-09-05 Shin Etsu Chem Co Ltd 繊維処理剤
JPH07122222B2 (ja) * 1988-05-30 1995-12-25 東レ・ダウコーニング・シリコーン株式会社 繊維用処理剤組成物
US5196260A (en) * 1988-11-19 1993-03-23 Ciba-Geigy Corporation Process for the treatment of fibrous materials with modified organopolysiloxanes and the materials
DE3839136A1 (de) * 1988-11-19 1990-05-23 Pfersee Chem Fab Verfahren zur behandlung von faserigen materialien mit modifizierten organopolysiloxanen und die so behandelten materialien
US5110684A (en) * 1990-11-07 1992-05-05 Dow Corning Corporation Masonry water repellent
US5411585A (en) * 1991-02-15 1995-05-02 S. C. Johnson & Son, Inc. Production of stable hydrolyzable organosilane solutions
DE4117864A1 (de) * 1991-05-31 1992-12-03 Pfersee Chem Fab Waessrige dispersionen von polysiloxanen
US5205860A (en) * 1992-01-23 1993-04-27 Dow Corning Corporation Water repellents containing organosilicon compounds
US5209775A (en) * 1992-01-23 1993-05-11 Dow Corning Corporation Water repellents containing organosilicon compounds
US5300327A (en) * 1993-03-22 1994-04-05 Dow Corning Corporation Water repellent organosilicon compositions
US5409620A (en) * 1993-12-30 1995-04-25 Dow Corning Corporation Fiber treatment compositions containing organofunctional siloxanes and methods for the preparation thereof

Also Published As

Publication number Publication date
JPH07166064A (ja) 1995-06-27
EP0643090A3 (de) 1996-01-10
EP0643090A2 (de) 1995-03-15
US5562761A (en) 1996-10-08
DE4330967A1 (de) 1995-03-16

Similar Documents

Publication Publication Date Title
KR950008621A (ko) 유기 규소 화합물을 함유하는, 섬유 재료 처리용 조성물
EP0055606B1 (en) Amino-functional silicone emulsions
US4743474A (en) Coating process and moisture-curable organopolysiloxane compositions therefor
AU687113B2 (en) Non-yellowing textile softening process in which a composition comprising a polyorganosiloxane is used
EP0342830B1 (en) Organosilicon compounds
EP0563961B1 (de) Vernetzbare Zusammensetzung auf Aminosiliconbasis
KR940005643A (ko) 질소 함유 라디칼과 에테르 그룹 함유 라디칼을 갖는 유기 실록산
CA1055637A (en) Heat curable organopolysiloxane-organoepoxysilicon compound-organic peroxide composition
KR940005848A (ko) 아미 함량이 적은 고분자량 아미노실록산을 사용하여 아민에 의한 바와 같은 유연성과 저황변성을 텍스타일에 부여하는 벙법
KR910021447A (ko) 고분산성 오르가노실록산에멀죤
KR970061941A (ko) 투명한 실리콘 겔
EP0510631B1 (en) Siloxane modified polyester for fibre treatment
KR910018445A (ko) 필름 형성 공중합체 및 수증기 침투성 피복물에서의 이의 용도
ATE185364T1 (de) Aliphatisch ungesättigte reste aufweisende organopolysiloxane, deren herstellung und deren verwendung in vernetzbaren massen
FI105338B (fi) Silikonihartsipohjaiset päällysteet
KR960011276B1 (ko) 오르가노폴리실록산 조성물
US4421783A (en) Process for coating substrates
KR0152308B1 (ko) 친수기함유 오르가노폴리실록산 및 그 제조방법
JPH0853547A (ja) アミノ官能性オルガノポリシロキサン、その水性エマルジョン、その製法及び有機繊維及び織物の仕上剤
CA1335779C (en) Emulsions for treating fibrous materials
EP0439778A2 (de) Alkenylgruppen aufweisende Siloxancopolymere, deren Herstellung und Verwendung
KR950003854B1 (ko) 유기섬유의 함침방법
TW479091B (en) Method for finishing treatment of a fabric material
WO2001081454A1 (en) Polyorganosiloxane mixtures for treating fiber materials
JPS63113022A (ja) 有機ポリシロキサン油

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid