KR940013606A - 신규한 다성분계 혼합산화물 촉매 조성물 및 그의 제조방법 - Google Patents

신규한 다성분계 혼합산화물 촉매 조성물 및 그의 제조방법 Download PDF

Info

Publication number
KR940013606A
KR940013606A KR1019920027095A KR920027095A KR940013606A KR 940013606 A KR940013606 A KR 940013606A KR 1019920027095 A KR1019920027095 A KR 1019920027095A KR 920027095 A KR920027095 A KR 920027095A KR 940013606 A KR940013606 A KR 940013606A
Authority
KR
South Korea
Prior art keywords
catalyst composition
preparation
mixed oxide
oxide catalyst
multicomponent mixed
Prior art date
Application number
KR1019920027095A
Other languages
English (en)
Other versions
KR960003792B1 (ko
Inventor
김종섭
우성일
Original Assignee
천성순
한국과학기술원
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 천성순, 한국과학기술원 filed Critical 천성순
Priority to KR1019920027095A priority Critical patent/KR960003792B1/ko
Priority to US08/175,286 priority patent/US5470815A/en
Publication of KR940013606A publication Critical patent/KR940013606A/ko
Application granted granted Critical
Publication of KR960003792B1 publication Critical patent/KR960003792B1/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00—General constructional features
    • F25D23/02—Doors; Covers
    • F25D23/04—Doors; Covers with special compartments, e.g. butter conditioners
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2325/00—Charging, supporting or discharging the articles to be cooled, not provided for in other groups of this subclass
    • F25D2325/021—Shelves with several possible configurations
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2331/00—Details or arrangements of other cooling or freezing apparatus not provided for in other groups of this subclass
    • F25D2331/80—Type of cooled receptacles
    • F25D2331/807—Eggs
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

본 발명은 신규한 다성분계 혼합산화물 촉매 조성물 및 그의 제조방법에 관한 것이다. 좀 더 구체적으로, 본 발명은 파라핀계 탄화수소를 암모니아 및 산소와 반응시켜 불포화 나이트릴(unsaturated nitrile) 화합물을 제조할 수 있는 고활성, 고선택성 촉매 조성물 및 그의 제조방법에 관한 것이다.

Description

신규한 다성분계 혼합산화물 촉매 조성물 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 프로판 암목시데이션 반응에 의한 아크릴로나이트릴 제조용 촉매 조성물 :
    AaBbCcDdIneGafBigMolOx
    상기에서, A는 알칼리 금속, 알칼리 토금속, 은 또는 구리; B는 니켈, 코발트, 철, 크롬, 루테늄, 팔라듐 또는 망간 ; C는 아연, 카드뮴, 세륨, 주석, 인, 비소, 안티몬, 납, 탤륨, 게르마늄 또는 알루미늄, 및, D는 티타늄, 지르코늄. 바나듐, 노븀, 탠탤륨, 란타늄, 네오듐, 가돌리늄 또는 텅스텐이며, a,b,c,d,e,f,g 및 i는 각 성분의 몰수이고, 단, a는 0 내지 10 ; b는 0 내지 5 ; c는 0 내지 15 ; d는 0 내지 14 ; e는 0 내지 14 ; e는 0 내지 2 ; f는 0 내지 7 ; g는 1 내지 25 ; 및, i는 12 내지 40이고, 12≤a+b+c+d+e+f+g≤40 이다.
  2. 제1항에 있어서, 촉매 조성물에 5 내지 99중량%의 Al2O3,SiO2, TiO2, MgO, SiC의 담지체를 사용하는 촉매 조성물.
  3. 제1항의 조성물을 공기나 산소중에서 소성온도 320 내지 650℃, 소성온도까지의 승온속도 15℃/분 이하의 조건으로 소성시킨 촉매 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920027095A 1992-12-31 1992-12-31 신규한 다성분계 혼합산화물 촉매 조성물 및 그의 제조방법 KR960003792B1 (ko)

Priority Applications (2)

Application Number Priority Date Filing Date Title
KR1019920027095A KR960003792B1 (ko) 1992-12-31 1992-12-31 신규한 다성분계 혼합산화물 촉매 조성물 및 그의 제조방법
US08/175,286 US5470815A (en) 1992-12-31 1993-12-29 Multicomponent oxide catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019920027095A KR960003792B1 (ko) 1992-12-31 1992-12-31 신규한 다성분계 혼합산화물 촉매 조성물 및 그의 제조방법

Publications (2)

Publication Number Publication Date
KR940013606A true KR940013606A (ko) 1994-07-15
KR960003792B1 KR960003792B1 (ko) 1996-03-22

Family

ID=19348242

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920027095A KR960003792B1 (ko) 1992-12-31 1992-12-31 신규한 다성분계 혼합산화물 촉매 조성물 및 그의 제조방법

Country Status (2)

Country Link
US (1) US5470815A (ko)
KR (1) KR960003792B1 (ko)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5658842A (en) * 1993-08-10 1997-08-19 Asahi Kasei Kogyo Kabushiki Kaisha Ammoxidation catalyst composition, and process for producing acrylonitrile or methacrylonitrile using the same
AU676940B2 (en) * 1993-10-22 1997-03-27 Nippon Shokubai Co., Ltd. Catalyst for production of pyromellitic anhydride and methodfor production of pyromellitic anhydride
JP3214975B2 (ja) * 1994-04-25 2001-10-02 旭化成株式会社 アンモ酸化触媒組成物および製造方法
US6136998A (en) * 1996-10-15 2000-10-24 Mitsubishi Rayon Co., Ltd. Retention of activity of molybdenum-containing metallic oxide catalyst
US5994259A (en) * 1998-07-29 1999-11-30 The Standard Oil Company Catalysts for the ammoxidation of alkanes
US6129774A (en) * 1998-09-24 2000-10-10 Clean Air Flow, Inc. Clean air flow catalyst
US6114278A (en) * 1998-11-16 2000-09-05 Saudi Basic Industries Corporation Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same
IT1312340B1 (it) * 1999-06-03 2002-04-15 Enichem Spa Sistema catalitico e procedimento per la deidrogenazione ossidativa dialchilaromatici o paraffine ai corrispondenti alchenilaromatici o alle
US20040102318A1 (en) * 2002-11-27 2004-05-27 Brazdil James F. Method for enhancing the productivity of vanadium antimony oxide catalysts
US7449426B2 (en) 2005-11-29 2008-11-11 Saudi Basic Industries Corporation Catalyst composition without antimony or molybdenum for ammoxidation of alkanes, a process of making and a process of using thereof
KR100888133B1 (ko) * 2007-10-02 2009-03-13 에스케이에너지 주식회사 4종의 금속성분으로 구성된 다성분계 비스무스몰리브데이트 촉매 제조방법 및 상기촉매를 이용하여1,3-부타디엔을 제조하는 방법
JP4639247B2 (ja) * 2008-07-23 2011-02-23 石油資源開発株式会社 炭化水素リフォーミング用触媒およびその製造方法ならびにこれを用いた合成ガスの製法
KR101937872B1 (ko) * 2016-09-07 2019-01-11 에쓰대시오일 주식회사 프로판 암모산화 반응용 촉매, 이의 제조방법 및 이를 이용한 아크릴로니트릴의 제조방법
CN107555450A (zh) * 2017-09-12 2018-01-09 潍坊滨海石油化工有限公司 氢氰酸的清洁生产工艺
CN107720777A (zh) * 2017-09-12 2018-02-23 潍坊滨海石油化工有限公司 氢氰酸的清洁生产方法

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3125538A (en) * 1964-03-17 Thallium
US3118928A (en) * 1961-08-16 1964-01-21 Du Pont Acrylonitrile production
US3816506A (en) * 1968-12-27 1974-06-11 Monsanto Co Ammoxidation of saturated hydrocarbons
US3670006A (en) * 1969-11-17 1972-06-13 Monsanto Co Ammoxidation of saturated hydrocarbons
US3686267A (en) * 1969-11-17 1972-08-22 Monsanto Co Ammoxidation of saturated hydrocarbons
US3678090A (en) * 1970-12-17 1972-07-18 Monsanto Co Ammoxidation of saturated hydrocarbons
US3833638A (en) * 1970-12-21 1974-09-03 Monsanto Co Ammoxidation of saturated hydrocarbons
US3670008A (en) * 1970-12-21 1972-06-13 Monsanto Co Ammoxidation of saturated hydrocarbons
US3670009A (en) * 1970-12-21 1972-06-13 Monsanto Co Ammoxidation of saturated hydrocarbons
US3746737A (en) * 1971-02-01 1973-07-17 Monsanto Co Ammoxidation of saturated hydrocarbons
US3860534A (en) * 1971-03-24 1975-01-14 Power Gas Ltd Method of making an antimony-vanadium catalyst
BE785663A (fr) * 1971-07-02 1973-01-02 American Cyanamid Co Oxydation du propane en presence d'ammoniac
DE2249922C2 (de) * 1972-10-12 1982-05-27 Basf Ag, 6700 Ludwigshafen Verfahren zur katalytischen Oxidation von Propylen oder Isobutylen zu Acrolein oder Methacrolein in der Gasphase mit molekularem Sauerstoff
US4000178A (en) * 1975-09-19 1976-12-28 Monsanto Company Paraffin ammoxidation process
US4736054A (en) * 1983-12-27 1988-04-05 The Standard Oil Company Ammoxidation of paraffins to acrylonitrile in the presence of zeolite catalysts
US4746641A (en) * 1984-08-22 1988-05-24 Standard Oil Company Ammoxidation of paraffins and catalysts therefor
US4609502A (en) * 1985-02-14 1986-09-02 The Halcon Sd Group, Inc. Process for preparing unsaturated nitriles from alkanes
US4783545A (en) * 1985-12-20 1988-11-08 The Standard Oil Company Method for ammoxidation of paraffins and catalyst system therefor
US4880764A (en) * 1986-06-06 1989-11-14 Uop Dehydrogenation catalyst and process
US4760159A (en) * 1987-03-13 1988-07-26 The Standard Oil Company Method for ammoxidation of paraffins and catalyst therefor
US4767739A (en) * 1987-04-20 1988-08-30 The Standard Oil Company Catalyst system for ammoxidation of paraffins
US4877764A (en) * 1987-04-20 1989-10-31 The Standard Oil Company Catalyst system for ammoxidation of paraffins
US4769355A (en) * 1987-04-20 1988-09-06 The Standard Oil Company Catalyst system for ammoxidation of paraffins
US4797381A (en) * 1987-07-30 1989-01-10 The Standard Oil Company Preparation of abrasion resistant alumina-supported vanadium-antimony oxidic catalysts
US4801568A (en) * 1987-10-22 1989-01-31 The Standard Oil Company Catalyst for ammoxidation of paraffins
US4784979A (en) * 1987-12-07 1988-11-15 The Standard Oil Company Catalyst and catalyst precursor containing vanadium and antimony
US4871706A (en) * 1987-12-16 1989-10-03 The Standard Oil Company Catalyst for the ammoxidation of paraffins
US4849537A (en) * 1988-02-09 1989-07-18 The Boc Group, Inc. Process for the production of nitriles
US4849538A (en) * 1988-03-23 1989-07-18 The Boc Group, Inc. Process for the production of nitriles
US4837191A (en) * 1988-05-16 1989-06-06 The Standard Oil Company Catalytic mixture for the ammoxidation of paraffins
US4843055A (en) * 1988-05-16 1989-06-27 The Standard Oil Company Catalyst system for ammoxidation of paraffins
US4835125A (en) * 1988-05-31 1989-05-30 The Standard Oil Company Catalyst system for ammoxidation of paraffins
US4874738A (en) * 1988-09-09 1989-10-17 The Standard Oil Company Catalyst for ammoxidation of paraffins
US4866024A (en) * 1988-09-29 1989-09-12 The Standard Oil Company Catalysts for ammoxidation of paraffins
US4879264A (en) * 1988-11-14 1989-11-07 The Standard Oil Company Method of making catalyst and catalyst precursor containing vanadium and antimony
US4870201A (en) * 1988-12-08 1989-09-26 The Boc Group, Inc. Process for the production of nitriles
US5212137A (en) * 1990-01-09 1993-05-18 Standard Oil Company Catalyst for the manufacture of acrylonitrile and methacrylonitrile
CN1025551C (zh) * 1990-11-05 1994-08-03 中国石油化工总公司 保持丙烯腈流化床钼系催化剂活性稳定的补加催化剂

Also Published As

Publication number Publication date
US5470815A (en) 1995-11-28
KR960003792B1 (ko) 1996-03-22

Similar Documents

Publication Publication Date Title
KR940013606A (ko) 신규한 다성분계 혼합산화물 촉매 조성물 및 그의 제조방법
US3642930A (en) Process for the manufacture of isoprene from isoamylenes and methyl butanols and catalyst therefor
KR860000233A (ko) 에탄올 에틸렌으로 옥시탈수소화시키는 방법
JP5610975B2 (ja) オレフィンのアクリロニトリル及びメタクリロニトリルへの転化用の触媒組成物およびその転化方法
US7071140B2 (en) Catalyst for the manufacture of acrylonitrile
JPS6118435A (ja) 酸化触媒
RU2012143494A (ru) Высокоэффективный способ аммоксидирования и катализаторы на основе смешанных оксидов металлов
KR860000234A (ko) 에탄올 에틸렌으로 산화탈수소화하는 방법
MY124766A (en) Complex oxide catalysts and process for producing (meth)acrolein and (meth)acrylic acid
GB1523141A (en) Process for the oxidation of olefins using catalysts containing various promoter elements
RU2012143840A (ru) Усовершенствованные катализаторы аммоксидирования на основе смешанных оксидов металлов
RU2012143495A (ru) Способ получения усовершенствованных катализаторов аммоксидирования на основе смешанных оксидов металлов
RU2217232C2 (ru) Катализатор для получения нитрила акриловой кислоты и цианистого водорода
JPH05245383A (ja) 固体酸アルキル化触媒組成物及びこれを使用するアルキル化方法
KR830003931A (ko) 개량된 Sb-함유 촉매의 제조방법
US4467046A (en) Dehydrogenation catalyst
US10406508B2 (en) Binder-free high strength, low steam-to-oil ratio ethylbenzene dehydrogenation catalyst
US4059628A (en) Preparation of aromatic amines
CN105597766A (zh) 一种用于低碳烷烃脱氢的催化剂及其制备方法
SA98190054B1 (ar) تحضير حفازات أساسها انتيمونات الفاناديوم vanadium antimonate بأستخدام sno2 xh2o
BE1006455A3 (nl) Werkwijze voor het bereiden van (meth)acrylonitril.
Erdöhelyi et al. Partial oxidation of ethane over K 2 MoO 4/SiO 2 and potassium promoted MoO 3/SiO 2 catalyst
SA99200394B1 (ar) حفازات انتقائية عالية الفعالية لإنتاج نيتريلات nitriles غير مشبعة unsaturated وطرق لعملها واستخدامها
GB1358867A (en) Catalytic oxidation process
US5260497A (en) Catalytic system for converting methane into higher hydrocarbons

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20020227

Year of fee payment: 7

LAPS Lapse due to unpaid annual fee