KR940005560A - 치환 옥심 에테르, 그의 제법 및 해충 및 진균을 방제하기 위한 그의 용도 - Google Patents

치환 옥심 에테르, 그의 제법 및 해충 및 진균을 방제하기 위한 그의 용도 Download PDF

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KR940005560A
KR940005560A KR1019930013189A KR930013189A KR940005560A KR 940005560 A KR940005560 A KR 940005560A KR 1019930013189 A KR1019930013189 A KR 1019930013189A KR 930013189 A KR930013189 A KR 930013189A KR 940005560 A KR940005560 A KR 940005560A
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group
alkyl
hydrogen atom
haloalkyl
methyl group
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KR1019930013189A
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오베르도르프 클라우스
자우터 후베르트
그래멘노스 와실리오스
키르쉬트겐 라인하르트
하리이스 폴커
로렌츠 기젤라
암메르만 에베르하르트
에반 골드 랜덜
지이겔 볼프강
하로이스 알브레크트
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방게르트, 바르츠
바스프 악티엔게젤샤프트
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Publication of KR940005560A publication Critical patent/KR940005560A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C07C251/50—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals
    • C07C251/52—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals of hydrocarbon radicals substituted by halogen atoms or by nitro or nitroso groups
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C07C251/34—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C251/48—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atom of at least one of the oxyimino groups bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C07C251/50—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals
    • C07C251/54—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals of hydrocarbon radicals substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C07C251/50—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals
    • C07C251/60—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals of hydrocarbon radicals substituted by carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/62—Carboxylic acid nitriles containing cyano groups and oxygen atoms being part of oxyimino groups bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Abstract

본 발명은 하기 일반식(I)의 치환 옥심 에테르 및 이들 화합물을 함유하는 살진균제 및 살충제에 관한 것이다.
(Ⅰ)
상기 식에서, R1은 알킬, 알케닐, 알키닐, 할로알킬, 할로알케닐, 알록시알킬, 시클로알킬, 시클로알킬알킬, 시아노알킬, 알콕시카르보닐알킬, 아릴알킬, 헤타릴알킬, 아릴알케닐 또는 아릴옥시알킬기(여기에서, 방향족 또는 헤테로방향족 고리는 치환되어 있거나 치환되어 있지 않음)이고, R2및 R3는 수소 원자, 알킬, 할로알킬, 알콕시, 할로알콕시기, 할로겐원자, 시아노 또는 니트로기이며, R4는 수소 원자, 알킬, 시클로알킬, 할로알킬 또는 아릴기(여기에서, 방향족 고리는 치환되어 있거나 치환되어 있지 않음)이고, R5및 R6는 동일하거나 상이하고, 각각 수소 원자 또는 알킬기이며, X는 CH 또는 N이다.

Description

치환 옥심 에테르, 그의 제법 및 해충 및 진균을 방제하기 위한 그의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기 일반식(Ⅰ)의 치환 옥심 에테르.
    (Ⅰ)
    상기 식에서. C1-C6-알킬, C3-C6-알케닐, C3-C4-알키닐, C1-C6-할로알킬, C3-C6-할로알케닐, C1-C4-알콕시알킬-C1-C6-알킬, C3-C6-시클로알킬, C3-C6-시클로알킬-C1-C4-알킬, 시아노-C1-C6-알킬, C1-C6-알콕시카르보닐알킬-C1-C6-알킬, 아릴-C1-C6-알킬, 헤타릴-C1-C6-알킬, 아릴-C3-C6-알케닐 또는 아릴옥시 -C1-C6-알킬기(여기에서, 방향족 또는 헤테로방향족 고리는 C1-C4-알킬, C1- 또는 C2-할로알킬, C3-C6-시클로알킬, C1-C4-알콕시, C1- 또는 C2-할로알콕시기, 할로겐원자, 아릴 또는 아릴옥시기 중에서 선택된 1개 이상의 기로 치환되어 있거나 치환되어 있지 않음)이고, R2및 R3는 동일하거나 상이하고, 각각 수소 원자, C1-C4-알킬, C1- 또는 C2-할로알킬, C1-C4-알콕시, C1- 또는 C2-할로알콕시기, 할로겐원자 시아노 또는 니트로기이며, R4는 수소 원자, C1-C6-알킬 또는 아릴기(여기에서 방향족 고리는 C1-C4-알킬, C1- 또는 C2-할로알킬 C1-C4-알콕시, C1- 또는 C2-할로알콕시기, 할로겐 원자, 시아노 또는 니트로기 중에서 선택된 1개 이상의 기로 치환되어 있거나 치환되어 있지 않음)이고, R5및 R6는 동일하거나 상이하고, 각각 수소 원자 또는 C1-C4-알킬기이며, X는 CH 또는 N이다.
  2. 살진균 유효량의 제1항에서 청구한 일반식(I)의 치환 옥심 에테르 및 불활성 담체를 함유하는 살진균제.
  3. 진균, 진균에 감염된 개체, 식물 또는 종자, 또는 토양을 살진균 유효랑의 제1항에서 청구한 일반식(I)의 치환 옥심 에테르로 처리하는 진균 방제 방법.
  4. 살충 유효량의 제1항에서 청구한 일반식(I)의 화합물 및 불활성 첨가제를 함유하는 살충제.
  5. 해충 또는 그의 서식지를 하기 일반식(ⅠA)의 화합물 유효량으로 처리하는 진균 방제 방법.
    (ⅠA)
    상기식에서, R1, R2, R3, R4및 X는 제1항에서 정의한 바와 같고, Z는 NR5R6또는 OR7기(여기에서, R5및 R6는 동일하거나 상이하고, 각각 수소 원자 또는 C1-C4-알킬기이며, R7은 C1-C4-알킬기임)이다.
  6. 제1항에서 있어서, R1, R2(2-위치), R4및 R6가 각각 메틸기이고, R3및 R5가 각각 수소 원자이며, X가 N이고, 옥시이미노에틸기가 4-위치인 일반식(I)의 화합물.
  7. 제1항에서 있어서, R1, R2(2-위치), R4및 R6가 각각 메틸기이고, R3및 R5가 각각 수소 원자이며, X가 CH이고, 옥시이미노에틸기가 4-위치인 일반식(I)의 화합물.
  8. 제1항에 있어서, R1이 메틸기이고, 2-위치의 R2가 메틸기이며, R4가 시클로프로필기이고, R6가 메틸기이며, R3및 R5가 각각 수소 원자이고, X가 N이며, 옥시이미노기가 4-위치인 일반식(I)의 화합물.
  9. 제1항에 있어서, R1이 메틸기이고, 2-위치의 R2가 메틸기이며, R4가 트리플루오로메틸기이고, R6가 메틸기이며, R3및 R5가 각각 수소 원자이고, X가 N이며, 옥시이미노기가 4-위치인 일반식(I)의 화합물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930013189A 1992-07-15 1993-07-14 치환 옥심 에테르, 그의 제법 및 해충 및 진균을 방제하기 위한 그의 용도 KR940005560A (ko)

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DE4223210 1992-07-15
DEP4223210.4 1992-07-15
DE4232816 1992-09-30
DEP4232816.0 1992-09-30
DEP4310495.9 1993-03-31
DE4310495 1993-03-31

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EP (2) EP0579124B1 (ko)
JP (1) JP3325343B2 (ko)
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AT (2) ATE172597T1 (ko)
AU (1) AU669176B2 (ko)
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ATE172597T1 (de) 1998-11-15
US5358968A (en) 1994-10-25
US5556884A (en) 1996-09-17
EP0672347A1 (de) 1995-09-20
DE59304170D1 (de) 1996-11-21
ES2093327T3 (es) 1996-12-16
IL106321A (en) 1999-12-22
NZ248155A (en) 1994-09-27
TW235902B (ko) 1994-12-11
EP0579124A1 (de) 1994-01-19
ATE144246T1 (de) 1996-11-15
AU669176B2 (en) 1996-05-30
EP0579124B1 (de) 1996-10-16
GR3021583T3 (en) 1997-02-28
HU9302023D0 (en) 1993-11-29
EP0672347B1 (de) 1998-10-28
CZ140193A3 (en) 1994-10-19
IL106321A0 (en) 1993-11-15
AU4197593A (en) 1994-01-20
HUT67361A (en) 1995-03-28
EE03098B1 (et) 1998-06-15
JP3325343B2 (ja) 2002-09-17
DE59309100D1 (de) 1998-12-03
CA2100386A1 (en) 1994-01-16
HU213452B (en) 1997-06-30
DK0579124T3 (da) 1996-11-18

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