KR940001312A - 실리콘 산화 반응 및 노 튜브 세척시 사용하기 위한 저-오존 파괴성 유기 염화물 - Google Patents
실리콘 산화 반응 및 노 튜브 세척시 사용하기 위한 저-오존 파괴성 유기 염화물 Download PDFInfo
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- KR940001312A KR940001312A KR1019930010390A KR930010390A KR940001312A KR 940001312 A KR940001312 A KR 940001312A KR 1019930010390 A KR1019930010390 A KR 1019930010390A KR 930010390 A KR930010390 A KR 930010390A KR 940001312 A KR940001312 A KR 940001312A
- Authority
- KR
- South Korea
- Prior art keywords
- dichloroethylene
- chlorohydrocarbon
- cis
- trans
- furnace tube
- Prior art date
Links
- 229910052710 silicon Inorganic materials 0.000 title claims abstract 6
- 239000010703 silicon Substances 0.000 title claims abstract 6
- 238000004140 cleaning Methods 0.000 title claims abstract 3
- 238000007254 oxidation reaction Methods 0.000 title claims 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims 3
- 230000003647 oxidation Effects 0.000 title claims 2
- 150000001805 chlorine compounds Chemical class 0.000 title 1
- 230000001066 destructive effect Effects 0.000 title 1
- 238000000034 method Methods 0.000 claims abstract 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000012159 carrier gas Substances 0.000 claims abstract 3
- 238000010438 heat treatment Methods 0.000 claims abstract 3
- 239000001301 oxygen Substances 0.000 claims abstract 3
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 3
- 238000004519 manufacturing process Methods 0.000 claims abstract 2
- 239000004065 semiconductor Substances 0.000 claims abstract 2
- LGXVIGDEPROXKC-UHFFFAOYSA-N 1,1-dichloroethene Chemical group ClC(Cl)=C LGXVIGDEPROXKC-UHFFFAOYSA-N 0.000 claims 4
- KFUSEUYYWQURPO-UPHRSURJSA-N cis-1,2-dichloroethene Chemical group Cl\C=C/Cl KFUSEUYYWQURPO-UPHRSURJSA-N 0.000 claims 4
- KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical group Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 claims 4
- 239000008246 gaseous mixture Substances 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 238000005229 chemical vapour deposition Methods 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 3
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/304—Mechanical treatment, e.g. grinding, polishing, cutting
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/02227—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process
- H01L21/0223—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate
- H01L21/02233—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate of the semiconductor substrate or a semiconductor layer
- H01L21/02236—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate of the semiconductor substrate or a semiconductor layer group IV semiconductor
- H01L21/02238—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate of the semiconductor substrate or a semiconductor layer group IV semiconductor silicon in uncombined form, i.e. pure silicon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/4401—Means for minimising impurities, e.g. dust, moisture or residual gas, in the reaction chamber
- C23C16/4405—Cleaning of reactor or parts inside the reactor by using reactive gases
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/02227—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process
- H01L21/02255—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by thermal treatment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/314—Inorganic layers
- H01L21/316—Inorganic layers composed of oxides or glassy oxides or oxide based glass
- H01L21/3165—Inorganic layers composed of oxides or glassy oxides or oxide based glass formed by oxidation
- H01L21/31654—Inorganic layers composed of oxides or glassy oxides or oxide based glass formed by oxidation of semiconductor materials, e.g. the body itself
- H01L21/31658—Inorganic layers composed of oxides or glassy oxides or oxide based glass formed by oxidation of semiconductor materials, e.g. the body itself by thermal oxidation, e.g. of SiGe
- H01L21/31662—Inorganic layers composed of oxides or glassy oxides or oxide based glass formed by oxidation of semiconductor materials, e.g. the body itself by thermal oxidation, e.g. of SiGe of silicon in uncombined form
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Formation Of Insulating Films (AREA)
Abstract
본 발명은 실리콘 또는 튜브를 700℃이상의 온도로 가열하면서 일반식 CXHXClX(식중, X는 2,3 또는 4임)의 클로로탄화수소와 산소를 함유한 담체가스를 실리콘 또는 튜브 상으로 유동시킴으로써, 반도체 제조시 사용된 노 튜브를 세척하거나 실리콘을 열산화하는 방법에 관한 것이다. 클로로탄화수소는 일정온도에서 즉시 완전 산화되는 것으로 선택된다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 800℃ TCA/O2반응 동안 원자질량 단위에 대한 상대적 진폭의 로그값을 나타낸 것이다.
제2도는 800℃ DCM/O2반응 동안 원자질량 단위에 대한 상대적 진폭의 로그값을 나타낸 것이다.
제3도는 800℃ TDCE/O2반응 동안 원자질량 단위에 대한 상대적 진폭의 로그값을 나타낸 것이다.
Claims (10)
- 실리콘 제품을 반응기 내에서 700℃ 이상으로 가열하는 단계; 일정한 조건하에서 즉시 완전 산화되는 것을 기준하여 선택된 일반식 CXHXClX(식중, X는 2,3 또는 4임)의 클로로탄화수소와 산소의 가스상 혼합물을 상기 반응기내로 유입시키는 단계; 및 상기 산화반응이 완료될 때까지 상기 실리콘 제품을 상기 가스상 혼합물에 계속적으로 노출시키는 단계를 포함하는, 실리콘 제품을 열산화시키는 방법.
- 제1항에 있어서, 상기 클로로탄화수소가 트랜스-디클로로에틸렌인 방법.
- 제1항에 있어서, 상기 클로로탄화수소가 시스-디클로로에틸렌인 방법.
- 제1항에 있어서, 상기 클로로탄화수소가 1,1-디클로로에틸렌인 방법.
- 제1항에 있어서, 상기 클로로탄화수소가 트랜스-디클로로에틸렌, 시스-디클로로에틸렌, 1,1-디클로로에틸렌 및 이들의 혼합물인 군중에서 선택되는 방법.
- 노 튜브를 800℃이상의 온도로 가열하는 단계; 일정한 조건하에서 즉시 완전산화되는 것을 기준하여 선택된 일반식 CXHXClX(식중, X는 2,3 또는 4임)의 클로로탄화수소와 산소의 담체가스중의 가스상 혼합물을 상기 튜브에 통과시키는 단계; 및 상기 튜브가 충분히 깨끗해질 때까지 상기 튜브를 상기 담체가스 중의 상기 혼합물과 접한 상태로 상기 온도에서 유지하는 단계를 포함하는, 화학증기 증착법를 사용하여 반도체 장치의 제조에 사용된 노 튜브를 세척하는 방법.
- 제6항에 있어서, 상기 클로로탄화수소가 트랜스-디클로로에틸렌인 방법.
- 제6항에 있어서, 상기 클로로탄화수소가 시스-디클로로에틸렌인 방법.
- 제6항에 있어서, 상기 클로로탄화수소가 1,1-디클로로에틸렌인 방법.
- 제6항에 있어서, 상기 클로로탄화수소가 트랜스-디클로로에틸렌, 시스-디클로로에틸렌, 1,1-디클로로에틸렌 및 이들의 혼합물로 이루어진 군중에서 선택되는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US7/898,857 | 1992-06-15 | ||
US07/898,857 US5288662A (en) | 1992-06-15 | 1992-06-15 | Low ozone depleting organic chlorides for use during silicon oxidation and furnace tube cleaning |
Publications (2)
Publication Number | Publication Date |
---|---|
KR940001312A true KR940001312A (ko) | 1994-01-11 |
KR970000421B1 KR970000421B1 (ko) | 1997-01-09 |
Family
ID=25410134
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019930010390A KR970000421B1 (ko) | 1992-06-15 | 1993-06-09 | 실리콘 산화 반응 및 노(爐) 튜브 세척시 사용하기 위한 저-오존 파괴성 유기 염화물 |
Country Status (7)
Country | Link |
---|---|
US (2) | US5288662A (ko) |
EP (1) | EP0574809B1 (ko) |
JP (1) | JPH0799743B2 (ko) |
KR (1) | KR970000421B1 (ko) |
DE (1) | DE69300544T2 (ko) |
HK (1) | HK1002325A1 (ko) |
TW (1) | TW224446B (ko) |
Families Citing this family (43)
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CN1244891C (zh) * | 1992-08-27 | 2006-03-08 | 株式会社半导体能源研究所 | 有源矩阵显示器 |
JP3497198B2 (ja) | 1993-02-03 | 2004-02-16 | 株式会社半導体エネルギー研究所 | 半導体装置および薄膜トランジスタの作製方法 |
US5843225A (en) * | 1993-02-03 | 1998-12-01 | Semiconductor Energy Laboratory Co., Ltd. | Process for fabricating semiconductor and process for fabricating semiconductor device |
US6997985B1 (en) | 1993-02-15 | 2006-02-14 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor, semiconductor device, and method for fabricating the same |
EP0612102B1 (en) * | 1993-02-15 | 2001-09-26 | Semiconductor Energy Laboratory Co., Ltd. | Process for the fabrication of a crystallised semiconductor layer |
US5985741A (en) | 1993-02-15 | 1999-11-16 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device and method of fabricating the same |
US6413805B1 (en) | 1993-03-12 | 2002-07-02 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device forming method |
US6875628B1 (en) | 1993-05-26 | 2005-04-05 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device and fabrication method of the same |
JP3450376B2 (ja) | 1993-06-12 | 2003-09-22 | 株式会社半導体エネルギー研究所 | 半導体装置の作製方法 |
JPH06349735A (ja) | 1993-06-12 | 1994-12-22 | Semiconductor Energy Lab Co Ltd | 半導体装置 |
US5488000A (en) | 1993-06-22 | 1996-01-30 | Semiconductor Energy Laboratory Co., Ltd. | Method of fabricating a thin film transistor using a nickel silicide layer to promote crystallization of the amorphous silicon layer |
US6713330B1 (en) | 1993-06-22 | 2004-03-30 | Semiconductor Energy Laboratory Co., Ltd. | Method of fabricating a thin film transistor |
US5529937A (en) * | 1993-07-27 | 1996-06-25 | Semiconductor Energy Laboratory Co., Ltd. | Process for fabricating thin film transistor |
JP3417665B2 (ja) * | 1994-07-07 | 2003-06-16 | 株式会社東芝 | 半導体装置の製造方法 |
US5915174A (en) * | 1994-09-30 | 1999-06-22 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device and method for producing the same |
US5599425A (en) * | 1995-02-06 | 1997-02-04 | Air Products And Chemicals, Inc. | Predecomposition of organic chlorides for silicon processing |
US5704986A (en) * | 1995-09-18 | 1998-01-06 | Taiwan Semiconductor Manufacturing Company Ltd | Semiconductor substrate dry cleaning method |
JP3645380B2 (ja) | 1996-01-19 | 2005-05-11 | 株式会社半導体エネルギー研究所 | 半導体装置の作製方法、情報端末、ヘッドマウントディスプレイ、ナビゲーションシステム、携帯電話、ビデオカメラ、投射型表示装置 |
JP3645379B2 (ja) * | 1996-01-19 | 2005-05-11 | 株式会社半導体エネルギー研究所 | 半導体装置の作製方法 |
US6478263B1 (en) | 1997-01-17 | 2002-11-12 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device and its manufacturing method |
US5985740A (en) | 1996-01-19 | 1999-11-16 | Semiconductor Energy Laboratory Co., Ltd. | Method of manufacturing a semiconductor device including reduction of a catalyst |
JP3729955B2 (ja) | 1996-01-19 | 2005-12-21 | 株式会社半導体エネルギー研究所 | 半導体装置の作製方法 |
JP3645378B2 (ja) | 1996-01-19 | 2005-05-11 | 株式会社半導体エネルギー研究所 | 半導体装置の作製方法 |
US5888858A (en) | 1996-01-20 | 1999-03-30 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device and fabrication method thereof |
US6180439B1 (en) * | 1996-01-26 | 2001-01-30 | Semiconductor Energy Laboratory Co., Ltd. | Method for fabricating a semiconductor device |
US7056381B1 (en) | 1996-01-26 | 2006-06-06 | Semiconductor Energy Laboratory Co., Ltd. | Fabrication method of semiconductor device |
US6465287B1 (en) | 1996-01-27 | 2002-10-15 | Semiconductor Energy Laboratory Co., Ltd. | Method for fabricating a semiconductor device using a metal catalyst and high temperature crystallization |
US6100562A (en) | 1996-03-17 | 2000-08-08 | Semiconductor Energy Laboratory Co., Ltd. | Method of manufacturing a semiconductor device |
KR100398621B1 (ko) * | 1996-12-31 | 2003-12-31 | 주식회사 하이닉스반도체 | 반도체소자의 게이트산화막 제조방법 |
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US6387827B1 (en) | 1997-03-28 | 2002-05-14 | Imec (Vzw) | Method for growing thin silicon oxides on a silicon substrate using chlorine precursors |
US6501094B1 (en) | 1997-06-11 | 2002-12-31 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device comprising a bottom gate type thin film transistor |
US6303522B1 (en) | 1997-11-19 | 2001-10-16 | Imec Vzw | Oxidation in an ambient comprising ozone and the reaction products of an organic chloro-carbon precursor |
US5990014A (en) * | 1998-01-07 | 1999-11-23 | Memc Electronic Materials, Inc. | In situ wafer cleaning process |
US6271153B1 (en) * | 1998-07-22 | 2001-08-07 | Micron Technology, Inc. | Semiconductor processing method and trench isolation method |
WO2002003438A1 (en) * | 2000-07-06 | 2002-01-10 | Mattson Thermal Products Inc. | Method and apparatus for rapid thermal processing (rtp) of semiconductor wafers |
JP3967199B2 (ja) * | 2002-06-04 | 2007-08-29 | シャープ株式会社 | 半導体装置及びその製造方法 |
US7357138B2 (en) * | 2002-07-18 | 2008-04-15 | Air Products And Chemicals, Inc. | Method for etching high dielectric constant materials and for cleaning deposition chambers for high dielectric constant materials |
US20040014327A1 (en) * | 2002-07-18 | 2004-01-22 | Bing Ji | Method for etching high dielectric constant materials and for cleaning deposition chambers for high dielectric constant materials |
US20040011380A1 (en) * | 2002-07-18 | 2004-01-22 | Bing Ji | Method for etching high dielectric constant materials and for cleaning deposition chambers for high dielectric constant materials |
US7055263B2 (en) * | 2003-11-25 | 2006-06-06 | Air Products And Chemicals, Inc. | Method for cleaning deposition chambers for high dielectric constant materials |
US7531464B2 (en) * | 2005-12-20 | 2009-05-12 | Texas Instruments Incorporated | Semiconductive device fabricated using a substantially disassociated chlorohydrocarbon |
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US3837905A (en) * | 1971-09-22 | 1974-09-24 | Gen Motors Corp | Thermal oxidation of silicon |
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-
1992
- 1992-06-15 US US07/898,857 patent/US5288662A/en not_active Expired - Lifetime
-
1993
- 1993-05-28 TW TW082104244A patent/TW224446B/zh not_active IP Right Cessation
- 1993-06-08 EP EP93109191A patent/EP0574809B1/en not_active Expired - Lifetime
- 1993-06-08 JP JP5164044A patent/JPH0799743B2/ja not_active Expired - Lifetime
- 1993-06-08 DE DE69300544T patent/DE69300544T2/de not_active Expired - Lifetime
- 1993-06-09 KR KR1019930010390A patent/KR970000421B1/ko not_active IP Right Cessation
- 1993-07-28 US US08/098,496 patent/US5298075A/en not_active Expired - Lifetime
-
1998
- 1998-02-20 HK HK98101336A patent/HK1002325A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0574809A1 (en) | 1993-12-22 |
HK1002325A1 (en) | 1998-08-14 |
JPH0799743B2 (ja) | 1995-10-25 |
EP0574809B1 (en) | 1995-09-27 |
DE69300544T2 (de) | 1996-03-21 |
US5288662A (en) | 1994-02-22 |
TW224446B (ko) | 1994-06-01 |
JPH0669194A (ja) | 1994-03-11 |
DE69300544D1 (de) | 1995-11-02 |
US5298075A (en) | 1994-03-29 |
KR970000421B1 (ko) | 1997-01-09 |
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