KR940000528A - 섬유-반응성 포르마잔 염료의 제조방법 및 아미노페놀 - Google Patents

섬유-반응성 포르마잔 염료의 제조방법 및 아미노페놀 Download PDF

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Publication number
KR940000528A
KR940000528A KR1019930010606A KR930010606A KR940000528A KR 940000528 A KR940000528 A KR 940000528A KR 1019930010606 A KR1019930010606 A KR 1019930010606A KR 930010606 A KR930010606 A KR 930010606A KR 940000528 A KR940000528 A KR 940000528A
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KR
South Korea
Prior art keywords
amino
substituted
alkyl
phenyl
aminophenol
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KR1019930010606A
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English (en)
Inventor
마르셔 클라우즈
파취 만프레드
Original Assignee
랑핑어, 방에르트
바스프 악티엔게젤샤프트
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Application filed by 랑핑어, 방에르트, 바스프 악티엔게젤샤프트 filed Critical 랑핑어, 방에르트
Publication of KR940000528A publication Critical patent/KR940000528A/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/02—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
    • C09B62/04—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a triazine ring
    • C09B62/046—Specific dyes not provided for in group C09B62/06 - C09B62/10
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/34—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by amino groups
    • C07C233/42—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by amino groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
    • C07C233/43—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by amino groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of a saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/4401—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system
    • C09B62/4403—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system the heterocyclic system being a triazine ring
    • C09B62/4407—Formazane dyes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/55—Design of synthesis routes, e.g. reducing the use of auxiliary or protecting groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

본 발명은 섬유-반웅성 포르마잔 염료에 관한 것이다.
상기 염료는 보호적으로 포르밀화된 히드록시패 닐렌디아민을 디 아조화시키고, 히드라존 화합물과 커플링시키고, 금속화시키고, 보호기를 제거하고, 할로트리아진과 반옹시킨후, 임의적으로 아민 또는 히드록시 화합물과 반응시킴으로써, 신극의 아미노팰놀 증간생성물을 경유하여 제조된다.

Description

섬유-반응성 포르마잔 염료의 제조방법 및 아미노페놀
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. (a)단계 1로서 할기 일반식(Ir)의 아미노페놀을 터아조화시키고. 하기 일방시(I(I)의 커플릴 성분과 커플링 시키고, 커플링 반응전. 도중 또는 훈에 구리 또는 니켈염을 첨가하고. (b)단계 2로서 산 또는 염기촉매하에 하기 일반식 (7)의 합성 포르마잔 화합물을 가수분해신키고, (c)단계 3으로서 합성 아미노화합물을 하기일반식 (Va) 또는 (Vb)의 할로트리아진과 반옹시괴는 것으로 이루어지는 유리산의 헝태로 굻기일반식(I)에 따르는 섬유-반응성 포르마잔 염료률 제고하기 위한 방법:
    상기식에서 cat7는 1당량의 양이온이고, n은 1또는 2이고, X는 산소, 또는 CO-0또는 S02-0의 라디칼이고, Me는 구리 또는 니켈이고, Y는 할로겐이고, 고리 A,5및 C는 추가의 치환기로 치환될수 있고, z는 n=1인 경우, 할로진, C1-C4-알콕시, 아미노, 모노(C1-C4-알킬)아미노, 디(C1-C4-알킬)아미노, 치환된 C2-C4-알킬아미노 또는 페닐- 또는 N-(C1-C4-알킬) -N-페닐-아미노 (여기에서, 페닐기는 각각의 경우에 치환될 수 있음)이거나, 또는 n=2일 경우, 하기일반식(1)의 라디칼띠고, Z1는 C1-C4-알콕시, 아미노, 모노(C1-C4-알킬)-아미노, 디C1-C4-알킬)아미노, 치환된 C2-C4-알킬아미노, 페닐-또는 N-(C1-C4-알킬)-N-페닐-아미노(여기에서, 페닐기는 각각의 경우에 치환될 수 있음), 또는 하기일반식 (2)의 라디칼이다 :
    상기식에서, L은 C2-C6-알킬렌, 또는 비치환 또는 히드록시술포닐-치환된 페닐렌이고, Y는 상기 정의된 바와같다.
  2. 제1항에 있어서, 일반시(I)에서 고리 A,B및 C중 2개가 각각 히드록시 술포닐에 의해 치환됨을 특징으로 하는 방법.
  3. 제1항에 있어서, Me가 구리임을 특징으로 하는 방법.
  4. 하기일반식(7)의 아미노페놀 :
    상기식에서 고리 C는 치환될 수 있다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930010606A 1992-06-13 1993-06-11 섬유-반응성 포르마잔 염료의 제조방법 및 아미노페놀 KR940000528A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4219421.0 1992-06-13
DE4219421A DE4219421A1 (de) 1992-06-13 1992-06-13 Verfahren zur Herstellung von faserreaktiven Formazanfarbstoffen sowie Aminophenole

Publications (1)

Publication Number Publication Date
KR940000528A true KR940000528A (ko) 1994-01-03

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019930010606A KR940000528A (ko) 1992-06-13 1993-06-11 섬유-반응성 포르마잔 염료의 제조방법 및 아미노페놀

Country Status (6)

Country Link
US (2) US5410027A (ko)
EP (1) EP0574799B1 (ko)
JP (1) JPH0693197A (ko)
KR (1) KR940000528A (ko)
DE (2) DE4219421A1 (ko)
TW (1) TW260696B (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4219421A1 (de) * 1992-06-13 1993-12-16 Basf Ag Verfahren zur Herstellung von faserreaktiven Formazanfarbstoffen sowie Aminophenole
DE4221543C1 (ko) * 1992-07-01 1993-08-26 Basf Ag, 6700 Ludwigshafen, De
JP3809974B2 (ja) * 1997-02-28 2006-08-16 日本化薬株式会社 ホルマザン化合物及びこれを用いるセルロース系繊維の染色方法
KR100510236B1 (ko) * 2002-06-11 2005-08-26 (주)경인양행 금속착염 포르마잔의 청색 염료 혼합물

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3202650A (en) * 1962-05-03 1965-08-24 Sandoz Ltd Metal-containing reactive azo dyes
US648580A (en) * 1899-11-29 1900-05-01 Auguste Behal Process of making ethereal salts of formic acid.
US2647815A (en) * 1951-05-03 1953-08-04 Gen Aniline & Film Corp Alkyl diformyl phenylenediamines
US2953423A (en) * 1957-01-29 1960-09-20 Gen Aniline & Film Corp Solubilization of dissociable ionic structures
US3627749A (en) * 1963-07-10 1971-12-14 Geigy Ag J R Mono-and disazo dyestuffs containing triazinylureylene groups
GB1398601A (en) * 1972-08-31 1975-06-25 Ici Ltd Reactive formazan dyestuffs
JPS6018357B2 (ja) * 1979-06-20 1985-05-09 住友化学工業株式会社 セルロ−ズ系繊維の染色法
JPS5915451A (ja) * 1982-07-19 1984-01-26 Sumitomo Chem Co Ltd 金属ホルマザン化合物、その製造法およびそれを用いる繊維材料の染色方法
US5155269A (en) * 1984-01-30 1992-10-13 Mallinckrodt Purification of p-aminophenol compositions and direct conversion to N-acetyl-p-aminophenol
DE3607825A1 (de) * 1985-03-16 1986-09-18 Sandoz-Patent-GmbH, 7850 Lörrach Reaktive formazanverbindungen
DE3705789A1 (de) * 1987-02-24 1988-09-01 Hoechst Ag Kupferkomplex-formazan-verbindungen, verfahren zu ihrer herstellung und ihre verwendung als farbstoffe
DE3737536A1 (de) * 1987-11-05 1989-05-18 Basf Ag Kupfer-formazanreaktivfarbstoffe und ihre verwendung
FR2638453B1 (fr) * 1988-10-28 1991-06-07 Oreal Ortho-aminophenols 5-substitues, procede pour les preparer et leur utilisation pour la teinture d'oxydation des fibres keratiniques
DE3903455A1 (de) * 1989-02-06 1990-08-09 Hoechst Ag Kupferkomplex-formazanverbindungen, verfahren zu ihrer herstellung und ihre verwendung als farbstoffe
EP0415884A1 (de) * 1989-08-28 1991-03-06 Ciba-Geigy Ag Verfahren zur Herstellung von aromatischen Aminen
DE4142132C1 (ko) * 1991-12-20 1993-05-27 Cassella Ag, 6000 Frankfurt, De
DE4219421A1 (de) * 1992-06-13 1993-12-16 Basf Ag Verfahren zur Herstellung von faserreaktiven Formazanfarbstoffen sowie Aminophenole

Also Published As

Publication number Publication date
EP0574799A2 (de) 1993-12-22
US5410027A (en) 1995-04-25
TW260696B (ko) 1995-10-21
US5536876A (en) 1996-07-16
DE59307367D1 (de) 1997-10-23
EP0574799B1 (de) 1997-09-17
EP0574799A3 (en) 1994-05-11
DE4219421A1 (de) 1993-12-16
JPH0693197A (ja) 1994-04-05

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