KR930023388A - 2종의 플루오르화 고리 단량체의 무정형 공중합체 - Google Patents

2종의 플루오르화 고리 단량체의 무정형 공중합체 Download PDF

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KR930023388A
KR930023388A KR1019930007627A KR930007627A KR930023388A KR 930023388 A KR930023388 A KR 930023388A KR 1019930007627 A KR1019930007627 A KR 1019930007627A KR 930007627 A KR930007627 A KR 930007627A KR 930023388 A KR930023388 A KR 930023388A
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South Korea
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perfluoro
copolymer
dimethyl
vinyl ether
dioxole
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KR1019930007627A
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KR960000855B1 (ko
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레이피얼 레스닉 폴
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미리암 디. 메코너헤이
이. 아이. 듀폰 디 네모아 앤드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F234/00—Copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring
    • C08F234/02—Copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring in a ring containing oxygen
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/922—Static electricity metal bleed-off metallic stock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y10T428/24868—Translucent outer layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
    • Y10T428/31544—Addition polymer is perhalogenated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)

Abstract

본 발명은 모든 단량체 비율에 있어서 무정형하고, 퍼플루오로(2－부틸테트라히드로푸란) 중에서 용해될 수 있는 퍼플루오로 (1,3－디메틸－2,2－디옥솔)의 퍼플루오로(부테닐 비닐 에테르) 및 제3의 공단량체와 공중합체에 관한 것이다. 이들 공중합체는 각종 첨단 기술, 특히 용해도가 중요한, 예를 들면 기계적, 화학적 또는 환경적 위험으로부터 보호하기 위해 기판 또는 성형품을 코팅하는 경우에 적당하다. 본 발명의 이원공중합체는 동일한 단량체 비율을 갖는 퍼플루오로(1,3－디메틸－2,2－디옥솔)의 테트라플루오로에틸렌과의 이원공중합체보다 더 낮은 유리 전이 온도를 갖는다.

Description

2종의 플루오르화 고리 단량체의 무정형 공중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 중합체에 있어서 PBVE의 몰 분율에 대한 7종의 PDD/PBVE 이원공중합체(dipolymer)의 Tg값을 나타낸 도면, 제2도는 83.9몰%의 PDD 및 16.1몰%의 PBVE 로 이루어진 PDD/PBVE 이원공중합체의19F－핵 자기공명 스펙트럼, 제3도는 플루오르화 처리를 안정화시키기 전과 후에 있어서 96.5%몰 의 PDD 와 3.5몰%의 PBVE로 이루어진 PDD/PBVE 이원공중합체의 적외선 흡수 스펙트럼

Claims (5)

1 내지 99.5몰%의 퍼플루오로(2,2－디메틸－1,3－디옥솔)과, 이와 상보적인 양인 99 내지 0.5몰%의 1종 이상의 다른 공단량체와의 무정형 공중합체로서, 이 공중합체는 퍼플루오로(부테닐 비닐 에테르)와의 이원공중합체 및 퍼플루오로(부페닐 비닐 에테르) 및 제3의 공단량체와의 삼원공중합체로 이루어진 군에서 선택되고, 여기서 제3의 공단량체는 (a) 할로겐이 불소 또는 염소이고 할로겐 원자의 반이상이 불소인 퍼할로올레핀, 또는 (b) 퍼플루오로(알킬 비닐 에테르) 일 수 있고, 제3의 공단량체가 존재하는 경우 그 양은 총 조성물의 40몰% 이하인 것을 특징으로 하는 공중합체.
제1항에 있어서, 공중합체가 퍼플루오로(2,2－디메틸－1,3－디옥솔)과 이와 상보적인 양의 퍼플루오로(부테닐 비닐 에테르) 와의 이원공중합체이고, 퍼플루오로(2,2－디메틸－1,3－디옥솔) 함량이 80몰%이상인 것을 특징으로 하는 공중합체.
코어 및 제1항의 공중합체인 피복층으로 이루어진 광섬유
제1항의 공중합체로 봉인된 전자 부품.
적어도 한 표면상에 제1항의 공중합체가 코팅된, 렌즈, 윈도우, 광필터 및 프리즘으로 이루어진 군에서 선택되는 광 투과 장치.
※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930007627A 1992-05-05 1993-05-04 2종의 플루오르화 고리 단량체의 무정형 공중합체 KR960000855B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/878,481 1992-05-05
US07/878,481 US5276121A (en) 1992-05-05 1992-05-05 Amorphous copolymers of two fluorinated ring monomers
US7/878,481 1992-05-05

Publications (2)

Publication Number Publication Date
KR930023388A true KR930023388A (ko) 1993-12-18
KR960000855B1 KR960000855B1 (ko) 1996-01-13

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Country Link
US (5) US5276121A (ko)
EP (1) EP0568869B1 (ko)
KR (1) KR960000855B1 (ko)
DE (1) DE69302041T2 (ko)
HK (1) HK146896A (ko)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5276121A (en) * 1992-05-05 1994-01-04 E. I. Du Pont De Nemours And Company Amorphous copolymers of two fluorinated ring monomers
US5502132A (en) * 1992-07-27 1996-03-26 Asahi Glass Company Ltd. Process for producing a perfluoro copolymer
WO1995028660A1 (fr) * 1994-04-18 1995-10-26 Yasuhiro Koike Resine a usage optique du type a repartition d'indice de refraction et son procede de production de cette resine
US5760139A (en) * 1994-04-18 1998-06-02 Yasuhiro Koike Graded-refractive-index optical plastic material and method for its production
US5408020A (en) * 1994-05-09 1995-04-18 E. I. Du Pont De Nemours And Company Copolymers of perhalo-2,2-di-loweralkyl-1,3-dioxole, and perfluoro-2-methylene-4-methyl-1,3-dioxolane
US7266725B2 (en) * 2001-09-03 2007-09-04 Pact Xpp Technologies Ag Method for debugging reconfigurable architectures
US5679444A (en) * 1996-07-15 1997-10-21 International Business Machines Corporation Method for producing multi-layer circuit board and resulting article of manufacture
DE29712042U1 (de) * 1997-07-10 1997-10-30 Fitterer Christian Bodenbelagentfernungsmaschine
DE69835649T2 (de) 1997-10-15 2007-09-13 E.I. Dupont De Nemours And Co., Wilmington Copolymere aus Maleinsäure oder dessen Anhydrid und fluorierten Olefinen
CA2276766A1 (en) 1998-07-03 2000-01-03 Asahi Glass Company Ltd. Optical waveguide
US6500547B1 (en) * 2000-03-06 2002-12-31 General Electric Company Coating materials for sensors and monitoring systems, methods for detecting using sensors and monitoring systems
DE60221066T2 (de) * 2001-05-07 2008-03-13 Solvay Solexis S.P.A. Amorphe perfluorierte Polymere
US7247313B2 (en) 2001-06-27 2007-07-24 Advanced Cardiovascular Systems, Inc. Polyacrylates coatings for implantable medical devices
US6566021B2 (en) 2001-07-26 2003-05-20 Micro Lithography, Inc. Fluoropolymer-coated photomasks for photolithography
US20030073961A1 (en) * 2001-09-28 2003-04-17 Happ Dorrie M. Medical device containing light-protected therapeutic agent and a method for fabricating thereof
FR2832412B1 (fr) * 2001-11-19 2003-12-19 Atofina Polymere fonctionnel reticulable permettant la fabrication de materiaux conducteurs de la lumiere
WO2003068718A2 (en) * 2002-02-12 2003-08-21 Photon-X, Inc. Halogenated monomers and polymers and process for making same
US7005137B1 (en) 2002-06-21 2006-02-28 Advanceed Cardiovascular Systems, Inc. Coating for implantable medical devices
US7396539B1 (en) * 2002-06-21 2008-07-08 Advanced Cardiovascular Systems, Inc. Stent coatings with engineered drug release rate
US7217426B1 (en) 2002-06-21 2007-05-15 Advanced Cardiovascular Systems, Inc. Coatings containing polycationic peptides for cardiovascular therapy
US7491233B1 (en) 2002-07-19 2009-02-17 Advanced Cardiovascular Systems Inc. Purified polymers for coatings of implantable medical devices
US20040063805A1 (en) * 2002-09-19 2004-04-01 Pacetti Stephen D. Coatings for implantable medical devices and methods for fabrication thereof
US8791171B2 (en) 2003-05-01 2014-07-29 Abbott Cardiovascular Systems Inc. Biodegradable coatings for implantable medical devices
US7563454B1 (en) 2003-05-01 2009-07-21 Advanced Cardiovascular Systems, Inc. Coatings for implantable medical devices
EP1836231B1 (en) * 2003-12-01 2009-04-22 Japan Science and Technology Agency Fluorinated polymers, method for producing the fluorinated compounds and polymers
US7244443B2 (en) * 2004-08-31 2007-07-17 Advanced Cardiovascular Systems, Inc. Polymers of fluorinated monomers and hydrophilic monomers
US20060171845A1 (en) * 2005-01-31 2006-08-03 Dakota Technologies, Inc. Sensors for measuring analytes
US9028859B2 (en) * 2006-07-07 2015-05-12 Advanced Cardiovascular Systems, Inc. Phase-separated block copolymer coatings for implantable medical devices
US8197578B2 (en) 2006-07-26 2012-06-12 Busek Company, Inc. Liquid degasser for a space device
CN101946295B (zh) * 2008-02-22 2012-11-28 旭硝子株式会社 驻极体及静电感应型转换元件
US8720794B2 (en) 2010-10-18 2014-05-13 Real Sensors, Inc. Gas permeation devices
DE102010062421A1 (de) 2010-12-03 2012-06-06 Bayer Materialscience Aktiengesellschaft Sauerstoffverzehrelektrode und Verfahren zu ihrer Herstellung
US11485814B1 (en) 2022-05-10 2022-11-01 Sparkling Tycoon Limited Perfluoro copolymers

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3978030A (en) * 1973-08-01 1976-08-31 E. I. Du Pont De Nemours And Company Polymers of fluorinated dioxoles
JPS5838707A (ja) * 1981-08-20 1983-03-07 イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− パ−フルオロ−２，２−ジメチル−１，３−ジオキソ−ルの無定形共重合体
US4935477A (en) * 1981-08-20 1990-06-19 E. I. Du Pont De Nemours And Company Amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole
US4754009A (en) * 1981-08-20 1988-06-28 E. I. Du Pont De Nemours And Company Amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole
US4431786A (en) * 1982-05-06 1984-02-14 E. I. Du Pont De Nemours And Company Novel fluorodioxoles and fluorodioxole polymers
US4897457A (en) * 1987-08-14 1990-01-30 Asahi Glass Company Ltd. Novel fluorine-containing cyclic polymer
JPH03192312A (ja) * 1989-12-22 1991-08-22 Mitsubishi Rayon Co Ltd プラスチック製マルチ光ファイバ
JP3053657B2 (ja) * 1991-02-06 2000-06-19 旭硝子株式会社 パーフルオロ共重合体、その製造法、その組成物およびその膜
US5276121A (en) * 1992-05-05 1994-01-04 E. I. Du Pont De Nemours And Company Amorphous copolymers of two fluorinated ring monomers

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Publication number Publication date
DE69302041T2 (de) 1996-10-24
KR960000855B1 (ko) 1996-01-13
US5324889A (en) 1994-06-28
US5326839A (en) 1994-07-05
HK146896A (en) 1996-08-09
US5338608A (en) 1994-08-16
US5353368A (en) 1994-10-04
EP0568869A2 (en) 1993-11-10
DE69302041D1 (de) 1996-05-09
US5276121A (en) 1994-01-04
EP0568869A3 (en) 1994-06-22
EP0568869B1 (en) 1996-04-03

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