KR930017928A - 경화성수지 조성물 - Google Patents

경화성수지 조성물 Download PDF

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KR930017928A
KR930017928A KR1019930002718A KR930002718A KR930017928A KR 930017928 A KR930017928 A KR 930017928A KR 1019930002718 A KR1019930002718 A KR 1019930002718A KR 930002718 A KR930002718 A KR 930002718A KR 930017928 A KR930017928 A KR 930017928A
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acrylate
meth
resin composition
compound
curable resin
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히로유끼 안도
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홍고오 무쓰비
이데미쓰 세끼유 가가꾸 가부시끼가이샤
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Publication of KR930017928A publication Critical patent/KR930017928A/ko

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    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/106—Esters of polycondensation macromers
    • C08F222/1065—Esters of polycondensation macromers of alcohol terminated (poly)urethanes, e.g. urethane(meth)acrylates
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    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F267/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00
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    • C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
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    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
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Abstract

(A) 경화성 포스파젠 화합물, (B) 디펜타에리쓰리툴 헥사아크릴 레이트등의 다관능성 아크릴레이트계 화합물 및 (C) 에폭시로 변성시킨 (메타) 아크릴레이트 변성폴리머등의 경화수축율이 6%이하인 가교성 화합물로된 경화성수지조성물이 개시되어 있다.
이 수지조성물에 따르면 경화속도가 빠르고 두꺼운 도포가 가능하며, 표면강도, 두명성 및 내후성이 우수한 경화수지막을 얻을 수 있다.

Description

경화성수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. (A) 경화성 포스파젠 화합물, (B) 다관능성 (메탈) 아크릴레이트제 화합물 및 (C) 경화수축율이 6%이하인 가교성 화합물로 된 것을 특징으로 하는 경화성 수지조성물.
  2. 제1항에 있어서, (A) 경화성 포스파젠 화합물이 5-90중량% 및, (B) 다관능성 (메타)아크릴레이트제 화합물이 95-10중량%임과 동시에, (C) 경화수축률이 6%이하인 가교성 화합물이 상기(A) 및 (B)의 합계량에 대하여 5-70중량%인 경화성 수지조성물.
  3. 제1항에 있어서, (A) 경화성 포스파젠 화합물이 일반식(Ⅰ)
    (식중, A는 중합경화성기를 나타내고, B는 비중합경화성기를 나타낸다. 또한 a, b 는 0 〈 a, 0 ≤b이며, a + b=2를 만족하는 실수를 나타냄)으로 표시되는 반복단위를 갖는 포스파젠화합물인 경화성 수지조성물.
  4. 제1항에 있어서, (A) 경화성 포스파젠 화합물이, 식으로 표시되는 고리형 또는 사슬형 포스파젠 화합물인 경화성 수지조성물.
  5. 제1항에 있어서, (B)다관능성(메타)아크릴레이트계 화합물이, 다관능성(메타)아크릴레이트 모노머, 다관능성(메타)아크릴 레이트 올리고머 또는 다관능성 우레탄 (메타) 아크릴레이트인 경화성수지 조성물.
  6. 제5항에 있어서, 다관능성 (메타)아크릴레이트 모노머가 1,3-부탄디올디(메타)아크릴레이트, 1,4-부탄디올디(메타)아크릴레이트, 1.6-헥산디올(메타)아크릴레이트, 에틸렌글리콜리(메타)아크릴레이트, 디에틸렌글콜디(메타)아크릴레이트, 트리에틸렌글리콜리(메타)아크릴레이트, 테트라에틸렌글리콜리(메타)아크릴레이트, 네오펜틸글리콜디(메타)아크릴레이트, 폴리 에틸렌글리콜리(메타)아크릴레이트 및 히드록시피발린산 에스테르네오펜틸글리콜디(메타)아크릴레이트로딘 군에서 선택된 2관능성 화합물인 경화성수지조성물.
  7. 제5항에 있어서, 다관능성(메타)아크릴레이트모노머가, 트리메틸롤 프로판트리(메타)아크릴레이트 또는 펜타에리쓰리롤트리(메타)아크릴레이트인 경화성 수지조성물.
  8. 제5항에 있어서, 다관능성(메타)아크릴레이트 올리고머가, 폴리펜타 에리쓰리롤폴리(메타)아크릴레이트, ε-카그로락톤 변성디 펜타에리쓰리롤헥사(메타)아크릴레이트, 폴리에스테르(메타)아크릴레이트, 폴리우레탄(메타)아크릴레이트, 에폭시(메타)아크릴레이트, 폴리에테르(메타)아크릴레이트, 멜라민(메타)아크릴레이트, 올리고(메타)아크릴레이트, 알키드(메타)아크릴레이트, 폴리올(메타)아크릴레이트 또는 실리콘(메타)아크릴레이트인 경화성 수지 조성물.
  9. 제5항에 있어서, 다관능성 우레탄(메타)아크릴레이트가 히드록시기 함유(메타)아크릴레이트와 폴리이소시아네이트를 반응시켜 얻어지는 것인 경화성 수지조성물.
  10. 제1항에 있어서, (C)가교성화합물이 경화수축율이 4.5%이하의 것인 경화성 수지조성물.
  11. 제1항에 있어서, (C)가교성화합물이, (메타)아크릴레이트 변성 폴리머, 경화성 (메타)아크릴레이트모노머 또는 할로겐화 폴리에스테르인 겨와성수지 조성물.
  12. 제11항에 있어서, (메타)아크릴레이트 변성폴리머가, (메타)아크릴레이트 변성 폴리에스테르, (메타)아크릴레이트 변성에폭시, (메타)아크릴레이트 변성우레탄, (메타)아크릴레이트 변성 알키드 우레탄, (메타)아크릴레이트 변성 폴리카프로락톤 또는 (메타)아크릴레이트 불포화산 변성건성유인 경화성 수지 조성물.
  13. 제11항에 있어서, 경화성(메타)아크릴레이트 모노머가 스피로 아세탈계 화합물, (이소)시아누레이트계 화합물, 멜라민제 화합물 또는 지방족 고리형 골격을 갖는 화합물인 경화성 수지조성물.
  14. 제11항에 있어서, 할로겐화 폴리에스테르가 폴리에스테르플리머를 할로겐원소로 할로겐화 한 것인 경화성 수지조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930002718A 1992-02-25 1993-02-25 경화성수지 조성물 KR930017928A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP4037693A JPH05230156A (ja) 1992-02-25 1992-02-25 硬化性樹脂組成物
JP92-37693 1992-02-25

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
KR20160144742A (ko) 2015-06-09 2016-12-19 동우 화인켐 주식회사 하드코팅 조성물 및 이를 이용한 하드코팅 필름

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19616968A1 (de) * 1996-04-27 1997-11-06 Daimler Benz Ag Polymerisierbares Phosphazenderivat, Verfahren zu dessen Herstellung und dessen Verwendung
DE19645340C1 (de) * 1996-11-04 1998-02-12 Daimler Benz Ag Aushärtbare Zusammensetzungen mit Phosphazenderivat und Vernetzer
DE10255664B4 (de) * 2002-11-28 2006-05-04 Kodak Polychrome Graphics Gmbh Für lithographische Druckplatten geeignete Photopolymerzusammensetzung
KR101469912B1 (ko) * 2013-06-28 2014-12-08 (주)아이씨비 경화형 난연 수지 조성물 및 이를 이용한 난연 고광택 데코시트

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JPH0796664B2 (ja) * 1988-11-08 1995-10-18 出光石油化学株式会社 硬化性樹脂組成物
JPH02284926A (ja) * 1989-04-26 1990-11-22 Idemitsu Petrochem Co Ltd 硬化性ホスファゼン組成物および被覆部材

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160144742A (ko) 2015-06-09 2016-12-19 동우 화인켐 주식회사 하드코팅 조성물 및 이를 이용한 하드코팅 필름

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CA2090304A1 (en) 1993-08-26
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JPH05230156A (ja) 1993-09-07

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