KR930008001A - 자유-유동성 폴리우레탄 분말 및 이의 제조방법 - Google Patents

자유-유동성 폴리우레탄 분말 및 이의 제조방법 Download PDF

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KR930008001A
KR930008001A KR1019920019797A KR920019797A KR930008001A KR 930008001 A KR930008001 A KR 930008001A KR 1019920019797 A KR1019920019797 A KR 1019920019797A KR 920019797 A KR920019797 A KR 920019797A KR 930008001 A KR930008001 A KR 930008001A
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powder
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nco
emulsion
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베르너 요아힘
멕켈 발터
리만 울리히
베게너 디르크
라쓰호퍼 베르너
더블유. 로스타우저 제임스
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게르하르트 뮐러. 로타르 슈타일링
바이엘 아크티엔게젤샤프트
로타르 슈타일링
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Priority claimed from DE19914135475 external-priority patent/DE4135475A1/de
Priority claimed from DE19924209709 external-priority patent/DE4209709A1/de
Application filed by 게르하르트 뮐러. 로타르 슈타일링, 바이엘 아크티엔게젤샤프트, 로타르 슈타일링 filed Critical 게르하르트 뮐러. 로타르 슈타일링
Publication of KR930008001A publication Critical patent/KR930008001A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
    • C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
    • C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
    • C08G18/0871—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/8064—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2140/00—Compositions for moulding powders
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2350/00—Acoustic or vibration damping material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2410/00—Soles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

본 발명은 적어도 부분적으로 차단된 이소시아네이트 및 유기 담체의 존재하에 유액을 만드는데 사용된 성분의 특성에 따라, 이소시아네이트 또는 이소시아네이트 반응성 물질의 유액을 이소시아네이트 반응성 물질 또는 이소시아네이트와 반응시켜 슬러시 성형법에 유용한 신규한 분말을 제조하는 방법에 관한 것이다. 후속적으로, 최종 반응 생성물을 담체로부터 분리한다.

Description

자유-유동성 폴리우레탄 분말 및 이의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. a) 표면-활성 화합물로 안정화시킨, (ⅠA) 유리 NCO 그룹을 갖는 성분 및 (ⅠB) NCO 그룹에 대해 반응성인 그룹을 갖는 성분으로 이루어진 그룹으로부터 선택된 제1성분의 미세 소적의 유액을 제조하고, b) 유액을 제1성분과 반응성인, (ⅡA) 분자 1개당 NCO 그룹에 대해 반응성인 평균 2개의 수소원자를 갖는 성분 및 (ⅡB) 분자 1개당 평균 2개의 NCO 그룹을 갖는 성분으로 이루어진 그룹으로부터 선택된 제2성분과 반응시킨 다음(단, 단계 a)의 유액이 성분 (ⅠA)을 기본으로 하는 경우에는, 제2성분은 (ⅡA)이고, 단계 a)의 유액이 성분 (ⅠB)를 기본으로 하는 경우에는, 제2성분은 (ⅡB)이며, 단계 b)는 적어도 부분적으로 차단된 이소시아네이트 그룹을 함유하며 독립적으로 제조된 성분(Ⅲ)의 존재하에 및 성분(ⅠA) 또는 (ⅠB)와 성분(Ⅱ) 및 (Ⅲ)과의 개개의 반응 생성물이 용해되지 않는 불활성 유기 액체 담체 상의 존재하에 수행한다), c) 불활성 유기 담체로부터 반응 생성물을 분리함을 특징으로 하는 방법에 의해 제조된 자유-유동성 폴리우레탄 분말.
  2. 제1항에 있어서, 성분(Ⅲ)이 a) 1,6-헥사메틸렌 디이소시아네이트의 이소시아누레이트, 하이드록시벤조산 에스테르 및 평균 분자량이 400 내지 6,000인 폴리올의 반응 생성물, b) 우레트디온 그룹을 함유하는 폴리이소시아네이트 또는 우레트디온 그룹을 함유하는 폴리이소시아네이트와 1 또는 수개의 NCO-반응성 화합물의 반응 생성물 및 c) a)와 b)의 혼합물로 이루어진 그룹으로부터 선택됨을 특징으로 하는 분말.
  3. 제2항에 있어서, 우레트디온 그룹을 함유하는 폴리이소시아네이트가 1,6-헥사메틸렌 디이소시아네이트를 이량체화시킴으로써 수득되는 분말.
  4. 제1항에 있어서, 성분(ⅠA)가 1,6-헥사메틸렌 디이소시아네이트와 평균 분자량이 400 내지 6,000인 폴리에스테르 디올의 반응에 의해 수득된 우레탄-NCO 예비중합체인 분말.
  5. 제1항에 있어서, 성분(ⅠA)가 4,4′-메틸렌비스(사이클로헥실 이소시아네이트)와 평균 분자량이 400 내지 6,000인 폴리에스테르 디올의 반응에 의해 수득된 우레탄-NCO 예비중합체인 분말.
  6. 제1항에 있어서, 성분(ⅡA)가 분자량이 400 미만인 디올 또는 하나 이상의 디올의 혼합물인 분말.
  7. 제1항에 있어서, 비점 범위가 65 내지 200℃인 지방족 탄화수소가 불활성 유기 담체 상으로 사용된 분말.
  8. 제1항에 따른 분말 및 주위온도(25℃)에서 고체인 분쇄된 발포제 하나 이상을 포함하는 발포성 폴리우레탄 분말 제제.
  9. 제8항에 있어서, 발포제가 아조디카본아미드인 분말 제제.
  10. a) 표면-활성 화합물로 안정화시킨, (ⅠA) 유리 NCO 그룹을 갖는 성분 및 (ⅠB) NCO 그룹에 대해 반응성인 그룹을 갖는 성분으로 이루어진 그룹으로부터 선택된 제1성분의 미세 소적의 유액을 제조하고, b) 유액을 제1성분과 반응성인, (ⅡA) 분자 1개당 NCO 그룹에 대해 반응성인 평균 2개의 수소원자를 갖는 성분 및 (ⅡB) 분자 1개당 평균 2개의 NCO 그룹을 갖는 성분으로 이루어진 그룹으로부터 선택된 제2성분과 반응시킨 다음(단, 단계 a)의 유액이 성분 (ⅠA)을 기본으로 하는 경우에는, 제2성분은 (ⅡA)이고, 단계 a)의 유액이 성분 (ⅠB)를 기본으로 하는 경우에는, 제2성분은 (ⅡB)이며, 단계 b)는 적어도 부분적으로 차단된 이소시아네이트 그룹을 함유하며 독립적으로 제조된 성분(Ⅲ)의 존재하에 및 성분(ⅠA) 또는 (ⅠB)와 개개의 반응 생성물이 용해되지 않는 불활성 유기 액체 담체 상의 존재하에 수행한다), c) 불활성 유기 담체로부터 반응 생성물을 분리함을 특징으로 하여, 자유-유동성 폴리우레탄 분말을 제조하는 방법.
  11. 제10항에 있어서, 담체 상에 용해되지 않는 발포제를 사용하고, 이를 불활성 유기 액체 담체 상에 가하는 방법.
  12. 제11항에 있어서, 성분(ⅠA), (ⅡA), (ⅠB) 또는 (ⅡB)를 반응시키기 전에 발포제를 이들 성분에 가하는 방법.
  13. 분말을 가열된 금형 내부에서 슬러싱하는 분말 슬러시 성형법으로 성형 시이트를 제조하는 방법에 있어서, 분말이 제1항에 따른 분말임을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920019797A 1991-10-28 1992-10-27 자유-유동성 폴리우레탄 분말 및 이의 제조방법 KR930008001A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE19914135475 DE4135475A1 (de) 1991-10-28 1991-10-28 Freifliessende, thermoplastisch verarbeitbare und dabei nachvernetzende polyurethan-pulver fuer die anwendung im powder-slush-moulding-prozess
DEP4135475.3 1991-10-28
DE19924209709 DE4209709A1 (de) 1992-03-25 1992-03-25 Freifließende, thermoplastisch verarbeitbare und dabei nachvernetzende, gegebenenfalls expandierbare Polyurethan-Pulver (-Zubereitungen)
DEP4209709.6 1992-03-25

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KR930008001A true KR930008001A (ko) 1993-05-20

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US (1) US5210127A (ko)
EP (1) EP0539802A1 (ko)
JP (1) JPH05230163A (ko)
KR (1) KR930008001A (ko)
CA (1) CA2081542A1 (ko)
MX (1) MX9205999A (ko)

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JPH05230163A (ja) 1993-09-07
CA2081542A1 (en) 1993-04-29
EP0539802A1 (de) 1993-05-05
US5210127A (en) 1993-05-11

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