KR920702033A - 전도성 금속 산화물을 함유하는 전도성 부품들 - Google Patents

전도성 금속 산화물을 함유하는 전도성 부품들

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KR920702033A
KR920702033A KR1019910701496A KR910701496A KR920702033A KR 920702033 A KR920702033 A KR 920702033A KR 1019910701496 A KR1019910701496 A KR 1019910701496A KR 910701496 A KR910701496 A KR 910701496A KR 920702033 A KR920702033 A KR 920702033A
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conductive
metal oxide
sulfuric acid
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케이 블룩 노오마
카오우 웬-홍
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원본미기재
글로브 유니온 인코포레이팃드
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Abstract

내용 없음

Description

전도성 금속 산화물을 함유하는 전도성 부품들
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 따른 납-산 전지판의 부분적, 단면도이다, 제2도는 본 발명에 따른 관상 납-산 전지 전극의 단면도이다, 제3도는 본 발명에 따른 언더코우팅된 전극의 단면도이다.

Claims (20)

  1. 부품이 전도성, 황산 내성 금속 산화물 피로브스카이트의 얇은 층으로 코우팅되는 것을 특징으로 하는 전도성 부품.
  2. 제1항에 있어서, 부품이 전극이고, 금속 산화물이 A가 Sr, Ba, Zn, Cd, 또는 Ra이고, B가 Zr, Sn, 또는 pb이고, 0.5≤c≤3인 일반식 AaBbOc의 화합물로 근본적으로 구성된 부품.
  3. 제1항 또는 제2항에 있어서, 화합물이 바륨메타플룸바이트인 부품.
  4. 납 물질이 전기 전도성, 황산-내성 금속 산화물 피로브스카이트를 함유하는 것을 특징으로 하는, 전도성 집전장치 및 집전장치와 접촉해 있는 활성 납 물질을 포함하는 전극.
  5. 제4항에 있어서, 전도성 금속 산화물이, 납-황산 전지의 양 전극으로 같은 조건하에 사용될때 PbO2와 거의 같거나 이보다 큰 산소 과전위, 납-황산 전지의 DMA 전극으로 같은 조건하에 사용될때 Pb와 거의 같거나 이 보다 큰 수소 과전위를 갖고, A가 Sr, Ba, Zn, Cd, 또는 Ra이고, B가 Zr, Sn, 또는 pb이고, 0.5≤a≤1, 0.5≤b≤1, 및 2≤c≤3인 일반식 AaBbOc의 화합물로 근본적으로 구성된 전극.
  6. 제4항 또는 제5항에 있어서, 전도성 금속 산화물이 ZnSnO3, CdSnO3, ZnPbO3, CdPb0.5O2, Cd0.5PbO2.5, 및 이들의 조합물로부터 선택되는 전극.
  7. 제4항, 제5항 또는 제6항중 어느 한 항에 있어서, 집전장치가 일반적으로 편평한 그리드를 포함하고, 활성납 물질이 그리드상에 층을 형성하는 전극.
  8. 제4항, 제5항 또는 제6항중 어느 한 항에 있어서, 집전장치가 연장된 로드를 포함하고, 전극이 또한 황산-내성 섬유 메쉬로 구성된 외장을 포함하고, 활성납 물질이 집전장치와 외장사이에 배치되는 전극.
  9. 제4항 내지 제8항중 어느 한 항에 있어서, 금속 산화물이 바륨메타플롬바이트인 전극.
  10. 케이싱, 케이싱내 배치된 양 및 음전극들, 전극들사이에 끼워진 분리기, 및 전극들 및 분리기와 접촉해 있는 황산 전해질을 포함하는, 전극들중 하나가 집전장치 및 집전장치와 접촉해 있는 활성 납 물질로 구성되고, 활성 납 물질은 전기전도성, 황산-내성 금속 산화물 피로브스카이트를 함유함을 특징으로 하는, 납-산 전지.
  11. 제10항에 있어서, 금속 산화물이, A가 Sr, Ba, Zn, Cd, 또는 Ra이고, B는 Zr, Sn, 또는 Pb이고, 0.5≤a≤1, 0.5≤b≤1, 및 2≤c≤3인 일반식 AaBbOc의 화합물로 근본적으로 구성된 전지.
  12. 제11항에 있어서, 금속 산화물이 바륨 메타플룸바이트인 전지.
  13. 화합물을 형성하기 위해 그안에 첨지된 양극 및 음극을 포함하는 전극들에 의해 용액에 전류를 적용시키는 단계를 포함하는, 전극들중 적어도 하나가 전해 합성중에 비반응성으로 남아있는 전도성, 황산-내성 금속 산화물 퍼로브스카이트를 함유하는 것을 개선점으로 하는, 수성 반응 매체내 반응물로부터 화합물의 전기 합성 방법.
  14. 제13항에 있어서, 금속 산화물이, A가 Sr, Ba, Zn, Cd, 또는 Ra이고, B가 Zr, Sn, 또는 Pb이고, 0.5≤a≤1, 0.5≤b≤1, 및 2≤c≤3인 일반식 AaBbOc의 화합물로 근본적으로 구성된 방법.
  15. 제13항에 있어서, 금속 산화물이 바륨 메타플룸바이트이고, 매체가 수성 황산인 방법.
  16. 그의 반대면에 배치된 양성 및 음성 활성 물질의 한쌍의 층을 갖는 전도성 지지체를 포함하는, 지지체가 수성 황산내에서 실질적으로 안정하고, A가 Sr, Ba, Zn, Cd, 또는 Ra이고, B가 Zr, Sn, 또는 Pb이고, 0.5≤a≤1, 0.5≤b≤1, 및 2≤c≤3인 일반식 AaBbOc의 화합물로 근본적으로 구성된 전도성 금속 산화물의 입자들; 및 전도성 입자들이 분산되는 실질적으로 황산-내성 결합제로 구성됨을 특징으로 하는, 납-산 쌍극전지에 사용하기 위한 쌍극 전극.
  17. 제16항에 있어서, 전도성 금속 산화물이 바륨 메타플룸바이트인 쌍극 전극.
  18. 케이싱, 각각 그의 반대 면상에 배치된 양성 및 음성 활성 물질의 한쌍의 층을 갖는 전도성 지지체를 포함하는 케이싱내 배치된 다수의 쌍극 전극, 쌍극 전극사이에 끼워진 적어도 하나의 분리기, 및 전극들 및 분리기가 접촉해 있는 전해질을 포함하는, 지지체가, 수성 황산내에서 실질적으로 안정하고, A가 Sr, Ba, Zn, Cd, 또는 Ra이고, B가 Zr, Sn, 또는 Pb이고, 0.5≤a≤1, 0.5≤b≤1, 및 2≤c≤3인 일반식 AaBbOc의 화합물로 근본적으로 구성된 전도성, 황산-내성 금속 산화물의 입자들; 및 전도성 입자들이 분산되는 실질적으로 황산-내성 결합제로 구성된 것을 특징으로 하는 쌍극 전지.
  19. 제18항에 있어서, 화합물이 바륨 메타플룸바이트인 쌍극 전지.
  20. 용액을 위한 용기, 용액내 배치가능한 양극 및 음극을 포함하는 한쌍의 전극, 및 화합물을 형성하기 위해 전극들을 통해 용액에 전류를 적용시키기 위한 수단을 포함하는, 전극들중 하나는 전해 합성중 실질적으로 비반응성으로 남는 전도성 황산 내성 금속 산화물 퍼로브스카이트를 함유하는 것을 특징으로 하는, 수성 황산 반응 매체내 반응물로부터 화합물의 전해 합성 장치.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910701496A 1989-05-02 1990-04-25 전도성 금속 산화물을 함유하는 전도성 부품들 KR920702033A (ko)

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US345993 1989-05-02
US07/345,993 US5045170A (en) 1989-05-02 1989-05-02 Electrodies containing a conductive metal oxide
PCT/US1990/002264 WO1990013923A1 (en) 1989-05-02 1990-04-25 Conductive components containing conductive metal oxide

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US (1) US5045170A (ko)
EP (1) EP0471021A1 (ko)
JP (1) JPH04505072A (ko)
KR (1) KR920702033A (ko)
AU (1) AU5568790A (ko)
BR (1) BR9007337A (ko)
CA (1) CA2051441A1 (ko)
MX (1) MX171903B (ko)
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CA2051441A1 (en) 1990-11-03
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