KR920019942A - 폴리-β-하이드록시 알카노에이트 (PHA) 공중합체 및 그 제조방법, 이를 생산하는 미생물과 PHA 공중합체의고분자 블렌드 - Google Patents
폴리-β-하이드록시 알카노에이트 (PHA) 공중합체 및 그 제조방법, 이를 생산하는 미생물과 PHA 공중합체의고분자 블렌드 Download PDFInfo
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- KR920019942A KR920019942A KR1019910005607A KR910005607A KR920019942A KR 920019942 A KR920019942 A KR 920019942A KR 1019910005607 A KR1019910005607 A KR 1019910005607A KR 910005607 A KR910005607 A KR 910005607A KR 920019942 A KR920019942 A KR 920019942A
- Authority
- KR
- South Korea
- Prior art keywords
- hydroxy
- pha
- copolymer
- pha copolymer
- polymer blend
- Prior art date
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- 229920001577 copolymer Polymers 0.000 title claims description 12
- 229920002959 polymer blend Polymers 0.000 title claims 3
- 244000005700 microbiome Species 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 3
- 229910052757 nitrogen Inorganic materials 0.000 claims 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 2
- 241000589516 Pseudomonas Species 0.000 claims 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 2
- 235000015097 nutrients Nutrition 0.000 claims 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 2
- 241000894007 species Species 0.000 claims 2
- FYSSBMZUBSBFJL-VIFPVBQESA-N (S)-3-hydroxydecanoic acid Chemical compound CCCCCCC[C@H](O)CC(O)=O FYSSBMZUBSBFJL-VIFPVBQESA-N 0.000 claims 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims 1
- WHBMMWSBFZVSSR-UHFFFAOYSA-M 3-hydroxybutyrate Chemical compound CC(O)CC([O-])=O WHBMMWSBFZVSSR-UHFFFAOYSA-M 0.000 claims 1
- OFCNGPVEUCUWSR-UHFFFAOYSA-N 3-hydroxyhex-4-enoic acid Chemical compound CC=CC(O)CC(O)=O OFCNGPVEUCUWSR-UHFFFAOYSA-N 0.000 claims 1
- UYHGBTRCKCDOGE-UHFFFAOYSA-N 3-hydroxyoct-6-enoic acid Chemical compound CC=CCCC(O)CC(O)=O UYHGBTRCKCDOGE-UHFFFAOYSA-N 0.000 claims 1
- NDPLAKGOSZHTPH-UHFFFAOYSA-N 3-hydroxyoctanoic acid Chemical compound CCCCCC(O)CC(O)=O NDPLAKGOSZHTPH-UHFFFAOYSA-N 0.000 claims 1
- VATLWWDLSNGELA-UHFFFAOYSA-N 3-hydroxyundec-10-enoic acid Chemical compound OC(=O)CC(O)CCCCCCC=C VATLWWDLSNGELA-UHFFFAOYSA-N 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 claims 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims 1
- 229930091371 Fructose Natural products 0.000 claims 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims 1
- 239000005715 Fructose Substances 0.000 claims 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 claims 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims 1
- WHBMMWSBFZVSSR-UHFFFAOYSA-N R3HBA Natural products CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 claims 1
- FARPMBPKLYEDIL-UHFFFAOYSA-N S-3-Hydroxyundecanoic acid Natural products CCCCCCCCC(O)CC(O)=O FARPMBPKLYEDIL-UHFFFAOYSA-N 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- -1 ammonium ions Chemical class 0.000 claims 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims 1
- 239000004202 carbamide Substances 0.000 claims 1
- 238000012258 culturing Methods 0.000 claims 1
- 235000021323 fish oil Nutrition 0.000 claims 1
- 239000008103 glucose Substances 0.000 claims 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims 1
- 235000019341 magnesium sulphate Nutrition 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 235000013379 molasses Nutrition 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- 230000001902 propagating effect Effects 0.000 claims 1
- 235000013619 trace mineral Nutrition 0.000 claims 1
- 239000011573 trace mineral Substances 0.000 claims 1
- 229940070710 valerate Drugs 0.000 claims 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims 1
- 238000001228 spectrum Methods 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/24—Preparation of oxygen-containing organic compounds containing a carbonyl group
- C12P7/26—Ketones
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/62—Carboxylic acid esters
- C12P7/625—Polyesters of hydroxy carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S435/00—Chemistry: molecular biology and microbiology
- Y10S435/8215—Microorganisms
- Y10S435/822—Microorganisms using bacteria or actinomycetales
- Y10S435/874—Pseudomonas
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제 1도는 PHA 공중합체의 정량을 위한 PHB 표준정량 직선이다. PHA의 정량을 위해 PHB를 표준 시료로 하여, CC 스펙트럼을 분석, 면적을 비교, 계산함으로서 PHA의 양을 계산한다.
제 2도는 PHA 공중합체의 GC 스펙트럼이다. PHA를 메틸 에스테르화 하여 GC를 분석한 결과 각 피이크는 PHA를 구성하는 모너머들의 메틸 에스테르 분자이다.
제 3도는 GC 스펙트럼 상에서 PHA 공중합 고분자의 각 모노머의 보지시간(Retention Time)의 Log 값과 탄소수와의 관계를 나타낸다. 탄소수에 비례하여 Log(RT)값이 증가함을 보여준다.
Claims (12)
- 하기 구조식(Ⅰ)의 모노머와 구조식(Ⅱ)의 모노머로 구성된 평균 분자량 10,000 이상의 폴리-β-하이드록시 알카노에이트(PHA)의 공중합체.(n=2, 4, 6, 8, 10 및 m=0, 2, 4, 6, 8)
- 제 1항에 있어서, 하기와 같은 모노머의 중량함량 범위의 조성을 가짐을 특징으로 하는 PHA 공중합체. 3-하이드록시 부티레이트 ; 0.0-0.5wt%, 3-하이드록시 헥사노에이트 ; 1.0-5.0wt%, 3-하이드록시-4-헥세노에이트 ; 0.0-1.0wt%, 3-하이드록시 옥타노에이트 ; 5.0-15.0wt%, 3-하이드록시-6-옥테노에이트 ; 0.0-5.0wt%, 3-하이드록시 데카노에이트 ; 40.0-60.0wt%, 3-하이드록시-8-데케노에이트 ; 0.0-10.0wt%, 3-하이드록시 운데카노에이트 ; 10.0-20.0wt%, 3-하이드록시-10-운데케노에이트 ; 0.0-20.0wt%, 3-하이드록시 테트라데카노에이트 ; 0.0-5.0wt%, 3-하이드록시-12-테트라데케노에이트 ; 0.0-5.0wt%.
- 제 1항의 PHA 공중합체를 생산하는 슈도모나스 속의 세파시아종(KCCM 10004) 및 그 변종.
- 탄소원, 질소원, 기타 영양원으로 포함하는 배양액에서 슈도모나스속 세파시아종(KCCM 10004) 및 그 변종을 배양한 후 질소원 및 기타 영양원을 제한하여 균체에서 PHA 공중합체를 생산하는 방법.
- 제 4항에 있어서, 탄소원은 포도당, 과당, 말토스, 당밀, 어유임을 특징으로 하는 방법.
- 제 4항에 있어서, 탄소원은 아세테이트, 프로피오네이트, 부티레이트, 발레레이트, 락테이트, 시트레이트 등의 유기산을 사용함을 특징으로 하는 방법.
- 제 4항에 있어서, 탄소원은 에탄올, 글리세롤, n-프로판올, n-부탄올, 프로필렌글리콜 등의 알콜을 사용함을 특징으로 하는 방법.
- 제 4항에 있어서, 질소원은 암모늄 이온염 또는 요소를 사용하여 균체를 증식한 후 배양액 중의 암모늄 이온 농도를 0.03g/L 이하로 제한하여 PHA 공중합체를 생산함을 특징으로 하는 방법.
- 제 4항에 있어서, 황산 마그네슘의 농도는 0.2-0.4g/L 임을 특징으로 하는 방법.
- 제 4항에 있어서, 미량 원소용액의 농도는 0.5-1㎖/L 임을 특징으로 하는 방법.
- 제 1항의 PHA 공중합체 0.5-99.5wt%와 PHB 99.5-0.5wt%로 구성된 분자량 1만 이상의 고분자 블렌드.
- 제 2항의 PHA 공중합체 0.5-99.5wt%와 PHB 99.5-0.5wt%로 구성된 분자량 1만 이상의 고분자 블렌드.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019910005607A KR100189468B1 (ko) | 1991-04-09 | 1991-04-09 | 폴리-베타-하이드록시알카노에이트(pha)공중합체및그제조방법,이를생산하는미생물과pha공중합체의고분자블렌드 |
DE69126444T DE69126444T2 (de) | 1991-04-09 | 1991-09-16 | Poly-g(b)-hydroxyalkanoat (pha) copolymer, verfahren zu seiner herstellung, die es produzierende mikrobe, und pha-copolymermischung |
AT91916731T ATE154048T1 (de) | 1991-04-09 | 1991-09-16 | Poly-g(b)-hydroxyalkanoat (pha) copolymer, verfahren zu seiner herstellung, die es produzierende mikrobe, und pha-copolymermischung |
JP3515824A JPH07500615A (ja) | 1991-04-09 | 1991-09-16 | ポリ−β−ヒドロキシアルカノエート(PHA)共重合体およびその製造方法、これを生産する微生物とPHA共重合体の高分子ブレンド |
PCT/KR1991/000019 WO1992018553A1 (en) | 1991-04-09 | 1991-09-16 | POLY-β-HYDROXY ALKANOATE (PHA) COPOLYMER, METHOD OF ITS PRODUCTION, THE MICROBE WHICH PRODUCES IT, AND PHA COPOLYMER BLEND |
EP91916731A EP0582567B1 (en) | 1991-04-09 | 1991-09-16 | POLY-$g(b)-HYDROXY ALKANOATE (PHA) COPOLYMER, METHOD OF ITS PRODUCTION, THE MICROBE WHICH PRODUCES IT, AND PHA COPOLYMER BLEND |
US08/122,590 US5395919A (en) | 1991-04-09 | 1991-09-16 | Poly-β-hydroxy alkanoate (PHA) copolymer, method of its production, the microbe which produces it, and PHA copolymer blend |
AU86121/91A AU8612191A (en) | 1991-04-09 | 1991-09-16 | Poly-beta-hydroxy alkanoate (pha) copolymer, method of its production, the microbe which produces it, and pha copolymer blend |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019910005607A KR100189468B1 (ko) | 1991-04-09 | 1991-04-09 | 폴리-베타-하이드록시알카노에이트(pha)공중합체및그제조방법,이를생산하는미생물과pha공중합체의고분자블렌드 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR920019942A true KR920019942A (ko) | 1992-11-20 |
KR100189468B1 KR100189468B1 (ko) | 1999-06-01 |
Family
ID=19313032
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019910005607A KR100189468B1 (ko) | 1991-04-09 | 1991-04-09 | 폴리-베타-하이드록시알카노에이트(pha)공중합체및그제조방법,이를생산하는미생물과pha공중합체의고분자블렌드 |
Country Status (8)
Country | Link |
---|---|
US (1) | US5395919A (ko) |
EP (1) | EP0582567B1 (ko) |
JP (1) | JPH07500615A (ko) |
KR (1) | KR100189468B1 (ko) |
AT (1) | ATE154048T1 (ko) |
AU (1) | AU8612191A (ko) |
DE (1) | DE69126444T2 (ko) |
WO (1) | WO1992018553A1 (ko) |
Families Citing this family (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2816777B2 (ja) * | 1991-08-03 | 1998-10-27 | 鐘淵化学工業株式会社 | 共重合体及びその製造方法 |
ZA95627B (en) * | 1994-01-28 | 1995-10-05 | Procter & Gamble | Biodegradable copolymers and plastic articles comprising biodegradable copolymers |
ID23491A (id) * | 1994-01-28 | 1995-09-07 | Procter & Gamble | Kopolimer-kopolimer yang dapat dibiodegradasi dan baha-bahan plastik yang terdiri dari kopolimer-kopolimer yang dapat dibiodegradasi |
SG49096A1 (en) * | 1994-01-28 | 1998-05-18 | Procter & Gamble | Biodegradable 3-polyhydtoxybuyrate/3- polyhydroxyhexanoate copolymer films |
ATE314410T1 (de) * | 1994-01-28 | 2006-01-15 | Procter & Gamble | Biologisch abbaubare copolymere und kunststoffgegenstände aus biologisch abbaubaren 3-hydroxyhexanoat copolymeren |
DE4420223C1 (de) * | 1994-06-06 | 1995-05-04 | Inst Genbiologische Forschung | Verfahren zur Kombination der intrazellulären Polyhydroxyalkanoat-Synthese in Mikroorganismen mit einer extrazellulären Polysaccharid-Synthese |
NL9401037A (nl) * | 1994-06-23 | 1996-02-01 | Soonn Stichting Onderzoek En O | Werkwijze voor het bereiden van een biologisch afbreekbare polyhydroxyalkanoaat coating met behulp van een waterige dispersie van polyhydroxyalkanoaat. |
GB9416690D0 (en) * | 1994-08-18 | 1994-10-12 | Zeneca Ltd | Process for the recovery of polyhydroxyalkanoic acid |
CA2226864C (en) | 1995-07-20 | 2003-05-20 | The Procter & Gamble Company | Nonwoven materials comprising biodegradable copolymers |
AU3406495A (en) * | 1995-08-14 | 1997-03-12 | University Of Massachusetts Medical Center | Methods of controlling microbial polyester structure |
US5942597A (en) * | 1995-08-21 | 1999-08-24 | The Procter & Gamble Company | Solvent extraction of polyhydroxyalkanoates from biomass |
US6143947A (en) * | 1996-01-29 | 2000-11-07 | The Procter & Gamble Company | Fibers, nonwoven fabrics and absorbent articles comprising a biodegradable polyhydroxyalkanoate comprising 3-hydroxybutyrate and 3-hydroxyhexanoate |
US5821299A (en) * | 1996-02-16 | 1998-10-13 | The Proctor & Gamble Company | Solvent extraction of polyhydroxy-alkanoates from biomass facilitated by the use of marginal nonsolvent |
DE19632504A1 (de) * | 1996-08-12 | 1998-02-19 | Gt Gmbh Elektrotechnische Prod | Kunstharzmuffe für Kabelgarnituren |
US5750848A (en) * | 1996-08-13 | 1998-05-12 | Monsanto Company | DNA sequence useful for the production of polyhydroxyalkanoates |
EP0977882B1 (en) * | 1997-04-21 | 2007-06-13 | Metabolix, Inc. | Hydroxy-terminated polyhydroxyalkanoates |
WO1999035278A1 (en) * | 1998-01-05 | 1999-07-15 | Monsanto Company | Biosynthesis of medium chain length polyhydroxyalkanoates |
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Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL8603073A (nl) * | 1986-12-02 | 1988-07-01 | Rijksuniversiteit | Werkwijze voor het bereiden van polyesters door fermentatie; werkwijze voor het bereiden van optisch actieve carbonzuren en esters; polyester omvattende voortbrengselen. |
-
1991
- 1991-04-09 KR KR1019910005607A patent/KR100189468B1/ko not_active IP Right Cessation
- 1991-09-16 EP EP91916731A patent/EP0582567B1/en not_active Expired - Lifetime
- 1991-09-16 US US08/122,590 patent/US5395919A/en not_active Expired - Fee Related
- 1991-09-16 JP JP3515824A patent/JPH07500615A/ja active Pending
- 1991-09-16 WO PCT/KR1991/000019 patent/WO1992018553A1/en active IP Right Grant
- 1991-09-16 AT AT91916731T patent/ATE154048T1/de not_active IP Right Cessation
- 1991-09-16 DE DE69126444T patent/DE69126444T2/de not_active Expired - Fee Related
- 1991-09-16 AU AU86121/91A patent/AU8612191A/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
KR100189468B1 (ko) | 1999-06-01 |
DE69126444D1 (de) | 1997-07-10 |
EP0582567A1 (en) | 1994-02-16 |
ATE154048T1 (de) | 1997-06-15 |
WO1992018553A1 (en) | 1992-10-29 |
US5395919A (en) | 1995-03-07 |
EP0582567B1 (en) | 1997-06-04 |
AU8612191A (en) | 1992-11-17 |
JPH07500615A (ja) | 1995-01-19 |
DE69126444T2 (de) | 1997-09-25 |
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