KR920018095A - 이타콘산의 중합방법 - Google Patents

이타콘산의 중합방법 Download PDF

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Publication number
KR920018095A
KR920018095A KR1019920004900A KR920004900A KR920018095A KR 920018095 A KR920018095 A KR 920018095A KR 1019920004900 A KR1019920004900 A KR 1019920004900A KR 920004900 A KR920004900 A KR 920004900A KR 920018095 A KR920018095 A KR 920018095A
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South Korea
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weight
initiator
homopolymer
itaconic acid
monomers
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KR1019920004900A
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English (en)
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안네 휴즈 캐덜린
스위프트 그래헴
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윌리엄 이. 램버트 3세
롬 앤드 하스 캄파니
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Publication of KR920018095A publication Critical patent/KR920018095A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/02—Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F122/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F122/02—Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/52—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
    • C09K8/528—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning inorganic depositions, e.g. sulfates or carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • D21C5/02—Working-up waste paper
    • D21C5/025—De-inking
    • D21C5/027—Chemicals therefor
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06—Paper forming aids
    • D21H21/08—Dispersing agents for fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/02—Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/12—Sulfonates of aromatic or alkylated aromatic compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/64—Paper recycling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Detergent Compositions (AREA)
  • Polymerisation Methods In General (AREA)
  • Biological Depolymerization Polymers (AREA)

Abstract

내용 없음

Description

이타콘산의 중합방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. a) 처음에 물을 투입한 반응기에 수-가용성 염기로 미리 중화한 모노머 용액을 첨가하고, b) 이 용액에 모노머 활성 개시제 0.5 내지 20중량%로 이루어진 개시용액을 균일한 천가속도하에 첨가하고 그리고 c) 반응기를 약 80 내지 120℃의 온도에서 유지시키는 것으로 이루어지는 이타콘산의 폴리머 제조방법.
  2. 제1항에 있어서, 이타콘산의 중화도가 약 80 내지 100당량%인 폴리머 제조방법.
  3. 제1항에 있어서, 모노머 용액이 개시 투입물에 함유하는 폴리머 제조방법.
  4. 제1항에 있어서, 모노머 용액이 개시제의 첨가동안 선형적으로 그리고 분리용액으로서 개시투입물에 도입하는 폴리머 제조방법.
  5. 제1항에 있어서, 개시제 농도는 모노머 전체량 기준으로 약 1.0 내지 10중량% 범위이고, 개시제는 과황산 나트륨 과황산 칼륨, 과황산암모늄, 과인산 나트륨, 과인산칼륨, 과인산암모늄, 3차부틸 히드로퍼옥사이드 및 과산화수소로 이루어진 그룹으로부터 선택하는 폴리머 제조방법.
  6. 제1항에 있어서, 개시제가 과황산나트륨인 폴리머 제조방법.
  7. 제1항에 있어서, 중합을 모노머 전체량 기준으로 고체수준 30 내지 80중량%범위에서 실시하는 폴리머 제조방법.
  8. 제1항에 있어서, 중합을 모노머 전체량 기준으로 고체수준 30 내지 60중량% 범위에서 실시하는 폴리머 제조방법.
  9. 제1항의 단일 중합체 약 30중량%까지의 세제로 이루어지는, 제1항의 생분해가능한 단일 중합체를 함유하는 세제 조성물.
  10. 제9항에 있어서, 단일중합체의 함량이 0.1 내지 20중량%인 세제조성물.
  11. 제9항에 있어서, 단일중합체의 함량이 0.5 내지 5.0중량%인 세제조성물.
  12. 제1항의 단일중합체의 유효량으로 이루어진 수처리 조성물.
  13. 제1항의 폴리머의 유효량으로 이루어진 분산제 조성물.
    ※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920004900A 1991-03-27 1992-03-26 이타콘산의 중합방법 KR920018095A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US676,056 1991-03-27
US07/676,056 US5223592A (en) 1991-03-27 1991-03-27 Process for polymerization of itaconic acid

Publications (1)

Publication Number Publication Date
KR920018095A true KR920018095A (ko) 1992-10-21

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KR1019920004900A KR920018095A (ko) 1991-03-27 1992-03-26 이타콘산의 중합방법

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US (1) US5223592A (ko)
EP (1) EP0506246A1 (ko)
JP (1) JPH0586129A (ko)
KR (1) KR920018095A (ko)
CN (1) CN1065276A (ko)
AU (1) AU1138192A (ko)
BR (1) BR9201061A (ko)
CA (1) CA2063197A1 (ko)
MX (1) MX174542B (ko)
NZ (1) NZ242068A (ko)

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EP0506246A1 (en) 1992-09-30
CN1065276A (zh) 1992-10-14
US5223592A (en) 1993-06-29
NZ242068A (en) 1994-08-26
BR9201061A (pt) 1992-11-24
AU1138192A (en) 1992-10-01
MX9201228A (es) 1992-10-01
MX174542B (es) 1994-05-23
CA2063197A1 (en) 1992-09-28
JPH0586129A (ja) 1993-04-06

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