KR920016482A - 가요성이 개선된 도료용 라텍스 - Google Patents

가요성이 개선된 도료용 라텍스 Download PDF

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Publication number
KR920016482A
KR920016482A KR1019920003108A KR920003108A KR920016482A KR 920016482 A KR920016482 A KR 920016482A KR 1019920003108 A KR1019920003108 A KR 1019920003108A KR 920003108 A KR920003108 A KR 920003108A KR 920016482 A KR920016482 A KR 920016482A
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South Korea
Prior art keywords
weight percent
range
nonionic surfactant
phm
monomer
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KR1019920003108A
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English (en)
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KR100232313B1 (ko
Inventor
에드먼드 스레일 리챠드
리 부로웨이 게리
Original Assignee
카알 에이취. 크루코우
더 굿이어 타이어 앤드 러버 캄파니
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Publication of KR920016482A publication Critical patent/KR920016482A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02—Monomers containing only one unsaturated aliphatic radical
    • C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06—Hydrocarbons
    • C08F112/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

내용 없음

Description

가요성이 개선된 도료용 라텍스.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. (1)단량체 100중량%를 기준으로, (a)비닐 방향족 단량체 약 30내지 약 70중량% (b)적어도 하나의 알킬아크릴레이트 단량체 약 25내지 약 65중량% (c)아크릴산 약 1내지 5중량% 및 (d)메타크릴산 약 0.4 내지 약 3중량%를 포함하는 단량체 혼합물을, 적어도 하나의 설포네이트 계면 활성제 약 0.2 내지 0.4phm 및 약 12내지 약 20범위내의 친수성-친유성 평형가를 갖는 적어도 하나의 수불용성 비이온성 계면활성제 약 4내지 8phm의 존재하에 약 3.5 미만의 pH에서 유리 라디칼 수성 유화 중합시켜 라텍스를 수득하고; (2)암모니아에 의해 상기 라텍스를 중화시켜 약 7내지 약 10.5 범위의 pH가 되도록 하여 중화된 라텍스를 제조하는 것을 포함하는, 수희석가능한(water reducible) 도료의 제조에 유용한 중화된 라텍스의 제조방법.
  2. 제1항에 있어서, 단량체 혼합물이 (a)스티렌 약 47내지 약 57중량% (b)2-에틸헥실아크릴레이트 약 40 내지 약 50중량% (c)아크릴산 약 1.5내지 2.5중량% 및, (d)메타크릴산 약 0.8내지 약 1.5중량 %로 구성되고; 유리 라디칼 수성 유화 중합 반응을 약 52℃내지 약 88℃ 범위내의온도에서 수행하고; 수불용성 비이온성 계면활성제가 약 14내지 약 18범위내의 친수성-친유성 평형가를 가지며; 설포네이트 계면활성제가 나트륨 도데실벤젠 설포네이트인 방법.
  3. 제2항에 있어서, 비이온성 계면활성제가 약4.5내지 약 6.0phm범위내의 농도로 존재하고; 설포네이트 계면 활성제가 약 0.25내지 약 0.35phm범위내의 농도로 존재하고; 상기 중합 반응을 pH 약 3.0 미만에서 수행하는 방법.
  4. 제1항에 있어서, 상기 비이온성 계면활성제가 하기 일반식을 갖는 수불용성 비이온 계면활성제인 방법:
    상기식에서 n은 약 8내지 약 50의 정수이며,m은 약 6내지 약 12의 정수이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되 는 것임.
KR1019920003108A 1991-02-28 1992-02-27 가요성이 개선된 도료용 라텍스 KR100232313B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/662,091 US5194469A (en) 1991-02-28 1991-02-28 Latex for coatings having improved flexibility
US662,091 1991-02-28

Publications (2)

Publication Number Publication Date
KR920016482A true KR920016482A (ko) 1992-09-24
KR100232313B1 KR100232313B1 (ko) 1999-12-01

Family

ID=24656348

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920003108A KR100232313B1 (ko) 1991-02-28 1992-02-27 가요성이 개선된 도료용 라텍스

Country Status (14)

Country Link
US (1) US5194469A (ko)
EP (1) EP0501272B1 (ko)
JP (1) JP3251044B2 (ko)
KR (1) KR100232313B1 (ko)
AU (1) AU639658B2 (ko)
BG (1) BG63397B2 (ko)
BR (1) BR9200583A (ko)
CA (1) CA2054116C (ko)
CZ (1) CZ288951B6 (ko)
DE (1) DE69205189T2 (ko)
MX (1) MX9200787A (ko)
PL (2) PL169686B1 (ko)
SK (1) SK280784B6 (ko)
YU (1) YU12792A (ko)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5775850A (en) * 1993-08-12 1998-07-07 The Broken Hill Proprietary Company Limited Rock bolt
US5691033A (en) * 1995-06-07 1997-11-25 Reynolds Metals Company Coating compositions containing aluminum pigment and methods of coating
CA2182155A1 (en) * 1995-09-21 1997-03-22 Gary Lee Burroway Latex for coatings
JPH0995642A (ja) * 1995-09-29 1997-04-08 Sumitomo Chem Co Ltd フロアーポリッシュ用水性エマルジョン組成物
DE19617633A1 (de) * 1996-05-02 1997-11-06 Basf Ag Verfahren zur Herstellung von im alkalischen löslichen Copolymerisaten auf (Meth)acrylatbasis
AUPO216396A0 (en) * 1996-09-06 1996-10-03 Ici Australia Operations Proprietary Limited Stain resistant water-borne paint
US9259598B2 (en) * 1996-12-12 2016-02-16 Landec, Inc. Aqueous dispersions of crystalline polymers and uses
US6199318B1 (en) 1996-12-12 2001-03-13 Landec Corporation Aqueous emulsions of crystalline polymers for coating seeds
US6540984B2 (en) 1996-12-12 2003-04-01 Landec Corporation Aqueous dispersions of crystalline polymers and uses
USH2041H1 (en) 1997-04-24 2002-08-06 The Goodyear Tire & Rubber Company Water impervious carpet backing
US5962579A (en) * 1997-09-26 1999-10-05 The Goodyear Tire & Rubber Company Coating for concrete structures
US6528581B1 (en) * 1998-05-14 2003-03-04 Rohm And Haas Company Coating bituminous substrates
US7812079B2 (en) 2001-02-22 2010-10-12 Valspar Sourcing, Inc. Coating compositions containing low VOC compounds
CA2545584C (en) * 2003-11-17 2012-10-23 Biomarin Pharmaceutical Inc. Methods and compositions for the treatment of metabolic disorders
ATE527326T1 (de) * 2006-02-03 2011-10-15 Basf Se Verfahren zum behandeln von substraten
US20100204352A1 (en) * 2007-01-31 2010-08-12 Bergman Roger W Carpet backing composition
CN101328232B (zh) * 2007-06-22 2011-11-30 东莞市佳景印刷材料有限公司 一种半成膜乳液及其制备方法
JP5737776B2 (ja) * 2010-02-10 2015-06-17 関西ペイント株式会社 エマルション樹脂系塗料
CN105038443A (zh) * 2015-07-14 2015-11-11 桂林市和鑫防水装饰材料有限公司 一种金属屋面隔热防水涂料及其制备方法
CN108948250B (zh) * 2018-06-14 2021-08-31 广州大学 一种抗菌聚合物乳液及其制备方法与应用
CN110885393B (zh) * 2019-12-02 2022-06-28 上海保立佳新材料有限公司 一种低气味苯丙烯酸乳液
KR102332552B1 (ko) * 2021-05-25 2021-12-02 (주)그린에어존 라돈 저감용 친환경 무기질 도료 조성물

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US3242121A (en) * 1961-05-17 1966-03-22 Union Carbide Corp Method of preparing latex binder of styrene, an alkyl acrylate, and an ethylenically unsaturated carboxylic acid
US4474926A (en) * 1983-01-31 1984-10-02 The Goodyear Tire & Rubber Company Process for producing stable large particle size latices
GB8317855D0 (en) * 1983-06-30 1983-08-03 Iq Bio Ltd Biochemical detection method
US4571415A (en) * 1984-10-01 1986-02-18 Rohm And Haas Company Washout resistant coatings
US4968741A (en) * 1989-10-06 1990-11-06 The Goodyear Tire & Rubber Company Latex for coatings having reduced blushing characteristics

Also Published As

Publication number Publication date
SK280784B6 (sk) 2000-07-11
AU1129692A (en) 1992-09-03
PL169686B1 (pl) 1996-08-30
CZ288951B6 (cs) 2001-10-17
CA2054116C (en) 2002-01-01
EP0501272A1 (en) 1992-09-02
BR9200583A (pt) 1992-10-27
BG63397B2 (bg) 2001-12-31
PL170301B1 (pl) 1996-11-29
CA2054116A1 (en) 1992-08-29
YU12792A (sh) 1994-06-24
KR100232313B1 (ko) 1999-12-01
DE69205189D1 (de) 1995-11-09
SK60192A3 (en) 1994-09-07
MX9200787A (es) 1992-08-31
EP0501272B1 (en) 1995-10-04
PL293645A1 (en) 1992-11-16
US5194469A (en) 1993-03-16
JPH0565303A (ja) 1993-03-19
DE69205189T2 (de) 1996-05-09
CZ60192A3 (en) 1993-11-17
JP3251044B2 (ja) 2002-01-28
AU639658B2 (en) 1993-07-29

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