KR920008074A - 안정화된 복분해 촉매용 혼합 활성제 - Google Patents
안정화된 복분해 촉매용 혼합 활성제 Download PDFInfo
- Publication number
- KR920008074A KR920008074A KR1019910017837A KR910017837A KR920008074A KR 920008074 A KR920008074 A KR 920008074A KR 1019910017837 A KR1019910017837 A KR 1019910017837A KR 910017837 A KR910017837 A KR 910017837A KR 920008074 A KR920008074 A KR 920008074A
- Authority
- KR
- South Korea
- Prior art keywords
- tin
- hydride
- tin compound
- halide
- composition
- Prior art date
Links
- 239000012190 activator Substances 0.000 title claims 4
- 238000005649 metathesis reaction Methods 0.000 title claims 4
- 239000003054 catalyst Substances 0.000 title claims 3
- -1 alkyl tin hydride Chemical compound 0.000 claims 11
- 150000003606 tin compounds Chemical class 0.000 claims 9
- 239000000203 mixture Substances 0.000 claims 6
- 229910052782 aluminium Inorganic materials 0.000 claims 5
- 150000004820 halides Chemical class 0.000 claims 3
- 239000007788 liquid Substances 0.000 claims 3
- KXCAEQNNTZANTK-UHFFFAOYSA-N stannane Chemical class [SnH4] KXCAEQNNTZANTK-UHFFFAOYSA-N 0.000 claims 3
- 229910000083 tin tetrahydride Inorganic materials 0.000 claims 3
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims 2
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims 2
- OZDCXCTXEUFFEV-UHFFFAOYSA-M ethyl(propoxy)alumanylium;chloride Chemical group [Cl-].CCCO[Al+]CC OZDCXCTXEUFFEV-UHFFFAOYSA-M 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 238000000465 moulding Methods 0.000 claims 2
- 239000002685 polymerization catalyst Substances 0.000 claims 2
- 238000006116 polymerization reaction Methods 0.000 claims 2
- DBGVGMSCBYYSLD-UHFFFAOYSA-N tributylstannane Chemical compound CCCC[SnH](CCCC)CCCC DBGVGMSCBYYSLD-UHFFFAOYSA-N 0.000 claims 2
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 150000004678 hydrides Chemical class 0.000 claims 1
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 238000012690 ionic polymerization Methods 0.000 claims 1
- 150000002751 molybdenum Chemical class 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical group [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/121—Metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Paper (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (7)
- 알킬 주석 히드라이드, 아릴주석 히드라이드, 테트라알킬 주석 화합물, 헥사 알킬 및 헥사아릴 디-주석 화합물, 그리고 알킬 주석 할라이드 중에서 선택된 주석 화합물과 알콕시알킬알루미늄 할라이드로 구성되며, 이때 상기 주석 화합물 1몰당 상기 알콕시알킬알루미늄 할라이드가 0.15내지 2몰의 비율로 존재하는 것을 특징으로 하는 안정화된 복분해 촉매 시스템용 활성제 조성물.
- 제1항에 있어서, 상기 알콕시알킬 알루미늄 할라이드가 에틸 프로폭시알루미늄 클로라이드인 것을 특징으로 하는 조성물.
- 제1항 또는 제2항에 있어서, 상기 주석 화합물이 트리부틸 주석 히드라이드인 것을 특징으로 하는 조성물.
- 각 성분의 몰비가 디시클로 펜타디엔 1000부/주석화합물 1부/알콕시알킬 알루미늄 할라이드 0.15내지 2부의 농도가 되도록 제1항 내지 제3항중 어느 한항의 조성물을 디시클로펜타디엔중에 용해시킴을 특징으로 하는 디시클 타디엔의 성형 반응을 위해 상기 조성물을 사용하는 방법.
- 디환식 시클로올레핀 및 복분해 중합반응 촉매를 포함하는 하나 이상의 액체 스트림과 복분해 중합 반응 촉매 활성제를 함유하는 하나이상의 액체스트림으로 구성된 여러개의 액체스트림을 함께 합하고, 이들을 중합과 성형이 동시에 발생하는 성형기내로 즉시 사출하는 것을 포함하는 다환식 시클로올레핀의 중합반응에 있어서, 상기 촉매가 이온 중합반응에 대해 안정화된 텅스텐 또는 몰리브덴 염이고, 상기 활성제는 주석화합물 1몰당 알콕시 알킬 알루미늄 할라이드가 0.15:2몰의 비로 존재하는 알킬 주석 히드라이드, 아일 주석 히드라이드, 테트라알킬 주석 화합물, 헥사알킬 및 헥사아릴 디-주석 화합물, 그리고 알킬 주석 할라이드 중에서 선택된 주석 화합물과 알콕시알킬 알루미늄 할라이드의 혼합물인 것을 특징으로 하는 방법.
- 제5항에 있어서, 상기 알콕시 알킬 알루미늄 할라이드는 에틸 프로폭시 알루미늄 클로라이드이며, 상기 주석 화합물은 트리알킬 주석 히드라이드인 것을 특징으로 하는 방법.
- 제6항에 있어서, 상기 트리알킬 주석 히드라이드가 트리부틸 주석 히드라이드인 것을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/596,263 US5075272A (en) | 1990-10-12 | 1990-10-12 | Mixed activators for stabilized metathesis catalysts |
| US596,263 | 1990-10-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR920008074A true KR920008074A (ko) | 1992-05-27 |
Family
ID=24386633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019910017837A KR920008074A (ko) | 1990-10-12 | 1991-10-11 | 안정화된 복분해 촉매용 혼합 활성제 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5075272A (ko) |
| EP (1) | EP0480247A3 (ko) |
| JP (1) | JPH04283224A (ko) |
| KR (1) | KR920008074A (ko) |
| AU (1) | AU8579191A (ko) |
| CA (1) | CA2051207A1 (ko) |
| MX (1) | MX9101412A (ko) |
| TW (1) | TW201762B (ko) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE162957T1 (de) * | 1992-12-01 | 1998-02-15 | Merck Patent Gmbh | Koordinations-katalysatorsysteme |
| DE4309821A1 (de) * | 1993-03-26 | 1994-09-29 | Merck Patent Gmbh | Koordinations-Katalysatorsysteme enthaltend intramolekular stabilisierte metallorganische Verbindungen |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4568660A (en) * | 1982-01-25 | 1986-02-04 | Hercules Incorporated | Cycloolefin polymerization catalyst composition |
| US4426502A (en) * | 1982-06-14 | 1984-01-17 | The B. F. Goodrich Company | Bulk polymerization of cycloolefins |
| GB8526539D0 (en) * | 1985-10-28 | 1985-12-04 | Shell Int Research | Bulk polymerization of dicyclopentadiene |
| JPH0762064B2 (ja) * | 1987-03-23 | 1995-07-05 | 日本ゼオン株式会社 | 熱硬化性樹脂の製造法 |
| US5015705A (en) * | 1988-09-28 | 1991-05-14 | Hercules Incorporated | Polymerization feed composition comprising slow gel/cure systems based on dialkylzinc |
| US4835230A (en) * | 1988-10-17 | 1989-05-30 | Hercules Incorporated | Use of a cationic polymerization initiator in the preparation of thermoset polymer |
-
1990
- 1990-10-12 US US07/596,263 patent/US5075272A/en not_active Expired - Fee Related
-
1991
- 1991-09-11 CA CA002051207A patent/CA2051207A1/en not_active Abandoned
- 1991-09-25 TW TW080107514A patent/TW201762B/zh active
- 1991-09-25 EP EP19910116344 patent/EP0480247A3/en not_active Withdrawn
- 1991-10-02 MX MX9101412A patent/MX9101412A/es unknown
- 1991-10-11 AU AU85791/91A patent/AU8579191A/en not_active Abandoned
- 1991-10-11 JP JP3290374A patent/JPH04283224A/ja active Pending
- 1991-10-11 KR KR1019910017837A patent/KR920008074A/ko not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0480247A3 (en) | 1993-01-07 |
| EP0480247A2 (en) | 1992-04-15 |
| AU8579191A (en) | 1992-04-16 |
| CA2051207A1 (en) | 1992-04-13 |
| TW201762B (ko) | 1993-03-11 |
| US5075272A (en) | 1991-12-24 |
| MX9101412A (es) | 1992-06-05 |
| JPH04283224A (ja) | 1992-10-08 |
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| N231 | Notification of change of applicant | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |